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Field Ionization and Field Desorption

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References

  1. Müller EW (1953) Feldemission. Ergebn Exakt Naturw 27:290–360. doi:10.1007/BFb0110808

    Google Scholar 

  2. Gomer R, Inghram MG (1955) Applications of Field Ionization to Mass Spectrometry. J Am Chem Soc 77:500. doi:10.1021/ja01607a096

    Article  CAS  Google Scholar 

  3. Inghram MG, Gomer R (1954) Mass-Spectrometric Analysis of Ions from the Field Microscope. J Chem Phys 22:1279–1280. doi:10.1063/1.1740380

    Article  CAS  Google Scholar 

  4. Inghram MG, Gomer R (1955) Mass-Spectrometric Investigation of the Field Emission of Positive Ions. Z Naturforsch A 10:863–872. doi:10.1515/zna-1955-1113

    Article  Google Scholar 

  5. Beckey HD (1959) Mass Spectrographic Investigations, Using a Field Emission Ion Source. Z Naturforsch A 14:712–721. doi:10.1515/zna-1959-0805

    Article  Google Scholar 

  6. Beckey HD (1962) Field-Ionization Mass Spectra of Organic Molecules. Normal C1 to C9 Paraffins. Z Naturforsch A 17:1103–1111. doi:10.1515/zna-1962-1211

    Article  Google Scholar 

  7. Beckey HD, Wagner G (1963) Analytical Use of an Ion Field Mass Spectrometer. Fresenius Z Anal Chem 197:58–80. doi:10.1007/BF00468727

    Article  Google Scholar 

  8. Beckey HD (1963) Mass Spectrometric Analysis with a New Source for the Production of Ion Fields at Thin Wires or Metal Edges. Fresenius Z Anal Chem 197:80–90. doi:10.1007/BF00468728

    Article  CAS  Google Scholar 

  9. Beckey HD, Wagner G (1965) Field Ionization Mass Spectra of Organic Molecules. II. Amines. Z Naturforsch A 20:169–175. doi:10.1515/zna-1965-0201

    Google Scholar 

  10. Beckey HD, Schulze P (1965) Field Ionization Mass Spectra of Organic Molecules. III. N-Paraffins Up to C16 and Branched Paraffins. Z Naturforsch A 20:1329–1335. doi:10.1515/zna-1965-1017

    Google Scholar 

  11. Beckey HD (1965) Analysis of Solid Organic Natural Products by Field Ionization Mass Spectrometry. Fresenius Z Anal Chem 207:99–104. doi:10.1007/BF00573238

    Article  CAS  Google Scholar 

  12. Beckey HD (1966) Comparison of Field Ionization and Chemical Ionization Mass Spectra of Decane Isomers. J Am Chem Soc 88:5333–5335. doi:10.1021/ja00974a061

    Article  CAS  Google Scholar 

  13. Beckey HD (1969) Field Desorption Mass Spectrometry: A Technique for the Study of Thermally Unstable Substances of Low Volatility. Int J Mass Spectrom Ion Phys 2:500–503. doi:10.1016/0020-7381(69)80047-1

    Article  CAS  Google Scholar 

  14. Beckey HD, Heindrichs A, Winkler HU (1970) New Field Desorption Techniques. Int J Mass Spectrom Ion Phys 3:A9–A11. doi:10.1016/0020-7381(70)80009-2

    Article  CAS  Google Scholar 

  15. Beckey HD (1971) Field-Ionization Mass Spectrometry. Pergamon, Elmsford

    Google Scholar 

  16. Sammons MC, Bursey MM, White CK (1975) Field Desorption Mass Spectrometry of Onium Salts. Anal Chem 47:1165–1166. doi:10.1021/ac60357a051

    Article  CAS  Google Scholar 

  17. Beckey HD, Schulten HR (1975) Field Desorption Mass Spectrometry. Angew Chem Int Ed 14:403–415. doi:10.1002/anie.197504031

    Article  Google Scholar 

  18. Lehmann WD, Schulten HR (1976) Physikalische Methoden in der Chemie: Massenspektrometrie II CI-, FI- und FD-MS. Chem Unserer Zeit 10:163–174. doi:10.1002/ciuz.19760100602

    Article  CAS  Google Scholar 

  19. Beckey HD (1977) Principles of Field Desorption and Field Ionization Mass Spectrometry. Pergamon Press, Oxford

    Google Scholar 

  20. Larsen E, Egsgaard H, Holmen H (1978) Field Desorption Mass Spectrometry of 1-Methylpyridinium Salts. Org Mass Spectrom 13:417–424. doi:10.1002/oms.1210130710

    Article  CAS  Google Scholar 

  21. Wood GW (1982) Field Desorption Mass Spectrometry: Applications. Mass Spectrom Rev 1:63–102. doi:10.1002/mas.1280010106

    Article  CAS  Google Scholar 

  22. Schulten HR (1983) Analytical Applications of Field Desorption Mass Spectrometry. In: Benninghoven A (ed) Ion Formation from Organic Solids. Springer, Heidelberg

    Google Scholar 

  23. Lattimer RP, Schulten HR (1989) Field Ionization and Field Desorption Mass Spectrometry: Past, Present, and Future. Anal Chem 61:1201A–1215A. doi:10.1021/ac00196a721

    Article  CAS  Google Scholar 

  24. Olson KL, Rinehart KL (1993) Field Desorption, Field Ionization, and Chemical Ionization Mass Spectrometry. Methods Carbohyd Chem 9:143–164

    CAS  Google Scholar 

  25. Del Rio JC, Philp RP (1999) Field Ionization Mass Spectrometric Study of High Molecular Weight Hydrocarbons in a Crude Oil and a Solid Bitumen. Org Geochem 30:279–286. doi:10.1016/S0146-6380(99)00014-5

    Article  Google Scholar 

  26. Guo X, Fokkens RH, Peeters HJW, Nibbering NMM, de Koster CG (1999) Multiple Cationization of Polyethylene Glycols in Field Desorption Mass Spectrometry: A New Approach to Extend the Mass Scale on Sector Mass Spectrometers. Rapid Commun Mass Spectrom 13:2223–2226. doi:10.1002/(SICI)1097-0231(19991115)13:21<2223::AID-RCM756>3.0.CO;2-C

    Article  CAS  Google Scholar 

  27. Lattimer RP (2001) Field ionization (FI-MS) and field desorption (FD-MS). In: Montaudo G, Lattimer RP (eds) Mass Spectrometry of Polymers. CRC Press, Boca Raton

    Google Scholar 

  28. Linden HB (2002) Quick Soft Analysis of Sensitive Samples Under Inert Conditions by In-Source Liquid Injection FD. Proc 50th Ann Conf Mass Spectrom Allied Topics, MPL 373. 2002. Orlando, ASMS

    Google Scholar 

  29. Linden HB (2004) Liquid Injection Field Desorption Ionization: A New Tool for Soft Ionization of Samples Including Air-Sensitive Catalysts and Non-Polar Hydrocarbons. Eur J Mass Spectrom 10:459–468. doi:10.1255/ejms.655

    Article  CAS  Google Scholar 

  30. Hsu CS, Green M (2001) Fragment-Free Accurate Mass Measurement of Complex Mixture Components by Gas Chromatography/Field Ionization-Orthogonal Acceleration Time-of-Flight Mass Spectrometry: An Unprecedented Capability for Mixture Analysis. Rapid Commun Mass Spectrom 15:236–239. doi:10.1002/1097-0231(20010215)15:3<236::AID-RCM197>3.0.CO;2-B

    Article  CAS  Google Scholar 

  31. Qian K, Dechert GJ (2002) Recent Advances in Petroleum Characterization by GC Field Ionization Time-of-Flight High-Resolution Mass Spectrometry. Anal Chem 74:3977–3983. doi:10.1021/ac020166d

    Article  CAS  Google Scholar 

  32. Schaub TM, Hendrickson CL, Qian K, Quinn JP, Marshall AG (2003) High-Resolution Field Desorption/Ionization Fourier Transform Ion Cyclotron Resonance Mass Analysis of Nonpolar Molecules. Anal Chem 75:2172–2176. doi:10.1021/ac020627v

    Article  CAS  Google Scholar 

  33. Schaub TM, Linden HB, Hendrickson CL, Marshall AG (2004) Continuous-Flow Sample Introduction for Field Desorption/Ionization Mass Spectrometry. Rapid Commun Mass Spectrom 18:1641–1644. doi:10.1002/rcm.1523

    Article  CAS  Google Scholar 

  34. Linden HB, Gross JH (2011) A Liquid Injection Field Desorption/Ionization-Electrospray Ionization Combination Source for a Fourier Transform Ion Cyclotron Resonance Mass Spectrometer. J Am Soc Mass Spectrom 22:2137–2144. doi:10.1007/s13361-011-0259-9

    Article  CAS  Google Scholar 

  35. Linden HB, Gross JH (2012) Reduced Fragmentation in Liquid Injection Field Desorption/Ionization-Fourier Transform Ion Cyclotron Resonance Mass Spectrometry by Use of Helium for the Thermalization of Molecular Ions. Rapid Commun Mass Spectrom 26:336–344. doi:10.1002/rcm.5335

    Article  CAS  Google Scholar 

  36. Gomer R (1994) Field Emission, Field Ionization, and Field Desorption. Surf Sci 299(300):129–152. doi:10.1016/0039-6028(94)90651-3

    Article  Google Scholar 

  37. Prókai L (1990) Field Desorption Mass Spectrometry. Marcel Dekker, New York

    Google Scholar 

  38. Todd JFJ (1995) Recommendations for Nomenclature and Symbolism for Mass Spectroscopy Including an Appendix of Terms Used in Vacuum Technology. Int J Mass Spectrom Ion Proc 142:211–240. doi:10.1016/0168-1176(95)93811-F

    Article  CAS  Google Scholar 

  39. Ligon WV Jr (1979) Molecular Analysis by Mass Spectrometry. Science 205:151–159. doi:10.1126/science.205.4402.151

    Article  CAS  Google Scholar 

  40. Miyamoto K, Fujimaki S, Ueda Y (2009) Development of a New Electron Ionization/Field Ionization Ion Source for Gas Chromatography/Time-of-Flight Mass Spectrometry. Rapid Commun Mass Spectrom 23:3350–3354. doi:10.1002/rcm.4256

    Article  CAS  Google Scholar 

  41. Schröder E (1991) Massenspektrometrie – Begriffe und Definitionen. Springer, Heidelberg

    Google Scholar 

  42. Derrick PJ, Robertson AJB (1973) Field Ionization Mass Spectrometry with Conditioned Razor Blades. Int J Mass Spectrom Ion Phys 10:315–321. doi:10.1016/0020-7381(73)83009-8

    Article  Google Scholar 

  43. Giessmann U, Heinen HJ, Röllgen FW (1979) Field Desorption of Nonelectrolytes Using Simply Activated Wire Emitters. Org Mass Spectrom 14:177–179. doi:10.1002/oms.1210140314

    Article  CAS  Google Scholar 

  44. Heinen HJ, Giessmann U, Röllgen FW (1977) Field Desorption of Electrolytic Solutions Using Untreated Wire Emitters. Org Mass Spectrom 12:710–715. doi:10.1002/oms.1210121112

    Article  CAS  Google Scholar 

  45. Beckey HD, Krone H, Röllgen FW (1968) Comparison of Tips, Thin Wires, and Sharp Metal Edges as Emitters for Field Ionization Mass Spectrometry. J Sci Instrum 1:118–120. doi:10.1088/0022-3735/1/2/308

    Article  CAS  Google Scholar 

  46. Beckey HD, Hilt E, Schulten HR (1973) High Temperature Activation of Emitters for Field Ionization and Field Desorption Spectrometry. J Phys E:Sci Instrum 6:1043–1044. doi:10.1088/0022-3735/6/10/028

    Article  CAS  Google Scholar 

  47. Linden HB, Hilt E, Beckey HD (1978) High-Rate Growth of Dendrites on Thin Wire Anodes for Field Desorption Mass Spectrometry. J Phys E:Sci Instrum 11:1033–1036. doi:10.1088/0022-3735/11/10/019

    Article  CAS  Google Scholar 

  48. Rabrenovic M, Ast T, Kramer V (1981) Alternative Organic Substances for Generation of Carbon Emitters for Field Desorption Mass Spectrometry. Int J Mass Spectrom Ion Phys 37:297–307. doi:10.1016/0020-7381(81)80051-4

    Article  CAS  Google Scholar 

  49. Linden HB, Beckey HD, Okuyama F (1980) On the Mechanism of Cathodic Growth of Tungsten Needles by Decomposition of Hexacarbonyltungsten Under High-Field Conditions. Appl Phys 22:83–87. doi:10.1007/BF00897937

    Article  CAS  Google Scholar 

  50. Bursey MM, Rechsteiner CE, Sammons MC, Hinton DM, Colpitts T, Tvaronas KM (1976) Electrochemically Deposited Cobalt Emitters for Field Ionization and Field Desorption Mass Spectrometry. J Phys E Sci Instrum 9:145–147. doi:10.1088/0022-3735/9/2/026

    Article  CAS  Google Scholar 

  51. Matsuo T, Matsuda H, Katakuse I (1979) Silicon Emitter for Field Desorption Mass Spectrometry. Anal Chem 51:69–72. doi:10.1021/ac50037a025

    Article  CAS  Google Scholar 

  52. Okuyama F, Shen GH (1981) Ion Formation Mechanisms in Field-Desorption Mass Spectrometry of Semirefractory Metal Elements. Int J Mass Spectrom Ion Phys 39:327–337. doi:10.1016/0020-7381(81)87006-4

    Article  CAS  Google Scholar 

  53. Kümmler D, Schulten HR (1975) Correlation Between Emitter Heating Current and Emitter Temperature in Field Desorption Mass Spectrometry. Org Mass Spectrom 10:813–816. doi:10.1002/oms.1210100918

    Article  Google Scholar 

  54. Winkler HU, Linden B (1976) On the Determination of Desorption Temperatures in Field Desorption Mass Spectrometry. Org Mass Spectrom 11:327–329. doi:10.1002/oms.1210110314

    Article  CAS  Google Scholar 

  55. Schulten HR, Lehmann WD (1977) High-Resolution Field Desorption Mass Spectrometry. Part VII. Explosives and Explosive Mixtures. Anal Chim Acta 93:19–31. doi:10.1016/0003-2670(77)80003-2

    Article  CAS  Google Scholar 

  56. Schulten HR, Nibbering NMM (1977) An Emission-Controlled Field Desorption and Electron Impact Spectrometry Study of Some N-Substituted Propane and Butane Sultams. Biomed Mass Spectrom 4:55–61. doi:10.1002/bms.1200040108

    Article  CAS  Google Scholar 

  57. Schulten HR (1978) Recent Advances in Field Desorption Mass Spectrometry. Adv Mass Spectrom 7A:83–97

    CAS  Google Scholar 

  58. Beckey HD (1964) Molecule Dissociation by High Electric Fields. Z Naturforsch A 19:71–83. doi:10.1515/zna-1964-0114

    Google Scholar 

  59. Severin D (1976) Molecular Ion Mass Spectrometry for the Analysis of High- and Nonboiling Hydrocarbon Mixtures. Erdöl und Kohle Erdgas Petrochemie Vereinigt mit Brennstoff-Chemie 29:13–18

    CAS  Google Scholar 

  60. Mead L (1968) Field Ionization Mass Spectrometry of Heavy Petroleum Fractions. Waxes. Anal Chem 40:743–747. doi:10.1021/ac60260a040

    Article  CAS  Google Scholar 

  61. Scheppele SE, Hsu CS, Marriott TD, Benson PA, Detwiler KN, Perreira NB (1978) Field-Ionization Relative Sensitivities for the Analysis of Saturated Hydrocarbons from Fossil-Energy-Related Materials. Int J Mass Spectrom Ion Phys 28:335–346. doi:10.1016/0020-7381(78)80077-1

    Article  CAS  Google Scholar 

  62. Gross JH (2008) Molecular Ions of Ionic Liquids in the Gas Phase. J Am Soc Mass Spectrom 19:1347–1352. doi:10.1016/j.jasms.2008.06.002

    Article  CAS  Google Scholar 

  63. Röllgen FW, Beckey HD (1970) Surface Reactions Induced by Field Ionization of Organic Molecules. Surf Sci 23:69–87. doi:10.1016/0039-6028(70)90006-3

    Article  Google Scholar 

  64. Schulten HR, Beckey HD (1974) Criteria for Distinguishing Between M+. and [M+H]+ Ions in Field Desorption Mass Spectra. Org Mass Spectrom 9:1154–1155. doi:10.1002/oms.1210091111

    Article  CAS  Google Scholar 

  65. Goldenfeld IV, Korostyshevsky IZ, Nazarenko VA (1973) Multiple Field Ionization. Int J Mass Spectrom Ion Phys 11:9–16. doi:10.1016/0020-7381(73)80050-6

    Article  CAS  Google Scholar 

  66. Helal AI, Zahran NF (1988) Field Ionization of Indene on Tungsten. Int J Mass Spectrom Ion Proc 85:187–193. doi:10.1016/0168-1176(88)83014-3

    Article  CAS  Google Scholar 

  67. Röllgen FW, Heinen HJ (1975) Formation of Multiply Charged Ions in a Field Ionization Mass Spectrometer. Int J Mass Spectrom Ion Phys 17:92–95. doi:10.1016/0020-7381(75)80010-6

    Article  Google Scholar 

  68. Röllgen FW, Heinen HJ (1975) Energetics of Formation of Doubly Charged Benzene Ions by Field Ionization. Z Naturforsch A 30:918–920. doi:10.1515/zna-1975-6-735

    Google Scholar 

  69. Röllgen FW, Heinen HJ, Levsen K (1976) Doubly-Charged Fragment Ions in the Field Ionization Mass Spectra of Alkylbenzenes. Org Mass Spectrom 11:780–782. doi:10.1002/oms.1210110712

    Article  Google Scholar 

  70. Neumann GM, Cullis PG, Derrick PJ (1980) Mass Spectrometry of Polymers: Polypropylene Glycol. Z Naturforsch A 35:1090–1097. doi:10.1515/zna-1980-1015

    Article  Google Scholar 

  71. McCrae CE, Derrick PJ (1983) The Role of the Field in Field Desorption Fragmentation of Polyethylene Glycol. Org Mass Spectrom 18:321–323. doi:10.1002/oms.1210180802

    Article  CAS  Google Scholar 

  72. Heine CE, Geddes MM (1994) Field-Dependent [M-2H]+. Formation in the Field Desorption Mass Spectrometric Analysis of Hydrocarbon Samples. Org Mass Spectrom 29:277–284. doi:10.1002/oms.1210290603

    Article  CAS  Google Scholar 

  73. Klesper G, Röllgen FW (1996) Field-Induced Ion Chemistry Leading to the Formation of [M-2nH]+. and [2M-2mH]+. Ions in Field Desorption Mass Spectrometry of Saturated Hydrocarbons. J Mass Spectrom 31:383–388. doi:10.1002/(SICI)1096-9888(199604)31:4<383::AID-JMS311>3.0.CO;2-1

    Article  CAS  Google Scholar 

  74. Evans WJ, DeCoster DM, Greaves J (1995) Field Desorption Mass Spectrometry Studies of the Samarium-Catalyzed Polymerization of Ethylene Under Hydrogen. Macromolecules 28:7929–7936. doi:10.1021/ma00127a046

    Article  CAS  Google Scholar 

  75. Evans WJ, DeCoster DM, Greaves J (1996) Evaluation of Field Desorption Mass Spectrometry for the Analysis of Polyethylene. J Am Soc Mass Spectrom 7:1070–1074. doi:10.1016/1044-0305(96)00043-8

    Article  CAS  Google Scholar 

  76. Gross JH, Vékey K, Dallos A (2001) Field Desorption Mass Spectrometry of Large Multiply Branched Saturated Hydrocarbons. J Mass Spectrom 36:522–528. doi:10.1002/jms.151

    Article  CAS  Google Scholar 

  77. Gross JH, Weidner SM (2000) Influence of Electric Field Strength and Emitter Temperature on Dehydrogenation and C-C Cleavage in Field Desorption Mass Spectrometry of Polyethylene Oligomers. Eur J Mass Spectrom 6:11–17. doi:10.1255/ejms.300

    Article  CAS  Google Scholar 

  78. Chait EM, Shannon TW, Perry WO, Van Lear GE, McLafferty FW (1969) High-Resolution Field-Ionization Mass Spectrometry. Int J Mass Spectrom Ion Phys 2:141–155. doi:10.1016/0020-7381(69)80014-8

    Article  CAS  Google Scholar 

  79. Forehand JB, Kuhn WF (1970) High Resolution Field Ionization Mass Spectrometry of the Condensable Phase of Cigaret Smoke. Anal Chem 42:1839–1841. doi:10.1021/ac50160a073

    Article  CAS  Google Scholar 

  80. Schulten HR, Beckey HD, Meuzelaar HLC, Boerboom AJH (1973) High-Resolution Field Ionization Mass Spectrometry of Bacterial Pyrolysis Products. Anal Chem 45:191–195. doi:10.1021/ac60323a039

    Article  CAS  Google Scholar 

  81. Schulten HR, Marzec A, Simmleit N, Dyla P, Mueller R (1989) Thermal Behavior and Degradation Products of Differently Ranked Coals Studied by Thermogravimetry and High-Resolution Field-Ionization Mass Spectrometry. Energy Fuel 3:481–487. doi:10.1021/ef00016a010

    Article  CAS  Google Scholar 

  82. Games DE, Jackson AH, Millington DS (1973) Applications of Field Ionization Mass Spectrometry in the Analysis of Organic Mixtures. Tetrahedron Lett 14:3063–3066. doi:10.1016/S0040-4039(01)96320-8

    Article  Google Scholar 

  83. Damico JN, Barron RP (1971) Application of Field Ionization to Gas-Liquid Chromatography-Mass Spectrometry (GLC-MS) Studies. Anal Chem 43:17–21. doi:10.1021/ac60296a032

    Article  CAS  Google Scholar 

  84. Briker Y, Ring Z, Iacchelli A, McLean N, Rahimi PM, Fairbridge C, Malhotra R, Coggiola MA, Young SE (2001) Diesel Fuel Analysis by GC-FIMS: Aromatics, n-Paraffins, and Isoparaffins. Energy Fuel 15:23–37. doi:10.1021/ef000106f

    Article  CAS  Google Scholar 

  85. Qian K, Dechert GJ, Edwards KE (2007) Deducing Molecular Compositions of Petroleum Products Using GC-Field Ionization High Resolution Time of Flight Mass Spectrometry. Int J Mass Spectrom 265:230–236. doi:10.1016/j.ijms.2007.02.012

    Article  CAS  Google Scholar 

  86. Hejazi L, Ebrahimi D, Hibbert DB, Guilhaus M (2009) Compatibility of Electron Ionization and Soft Ionization Methods in Gas Chromatography/Orthogonal Time-of-Flight Mass Spectrometry. Rapid Commun Mass Spectrom 23:2181–2189. doi:10.1002/rcm.4131

    Article  CAS  Google Scholar 

  87. Kane-Maguire LAP, Kanitz R, Sheil MM (1995) Comparison of Electrospray Mass Spectrometry with Other Soft Ionization Techniques for the Characterization of Cationic Π-Hydrocarbon Organometallic Complexes. J Organomet Chem 486:243–248. doi:10.1016/0022-328X(94)05041-9

    Article  CAS  Google Scholar 

  88. Rogers DE, Derrick PJ (1984) Mechanisms of Ion Formation in Field Desorption of Oligosaccharides. Org Mass Spectrom 19:490–495. doi:10.1002/oms.1210191006

    Article  CAS  Google Scholar 

  89. Derrick PJ, Nguyen T-T, Rogers DEC (1985) Concerning the Mechanism of Ion Formation in Field Desorption. Org Mass Spectrom 11:690. doi:10.1002/oms.1210201108

    Google Scholar 

  90. Veith HJ, Röllgen FW (1985) On the Ionization of Oligosaccharides. Org Mass Spectrom 11:689–690. doi:10.1002/oms.1210201108

    Google Scholar 

  91. Schulten HR, Beckey HD (1972) Field Desorption Mass Spectrometry with High-Temperature Activated Emitters. Org Mass Spectrom 6:885–895. doi:10.1002/oms.1210060808

    Article  CAS  Google Scholar 

  92. Davis SC, Neumann GM, Derrick PJ (1987) Field Desorption Mass Spectrometry with Suppression of the High Field. Anal Chem 59:1360–1362. doi:10.1021/ac00136a021

    Article  CAS  Google Scholar 

  93. Veith HJ (1977) Alkali Ion Addition in FD Mass Spectrometry. Cationization and Protonation-Ionization Methods in the Application of Nonactivated Emitters. Tetrahedron 33:2825–2828. doi:10.1016/0040-4020(77)80275-5

    Article  CAS  Google Scholar 

  94. Giessmann U, Röllgen FW (1981) Electrodynamic Effects in Field Desorption Mass Spectrometry. Int J Mass Spectrom Ion Phys 38:267–279. doi:10.1016/0020-7381(81)80072-1

    Article  CAS  Google Scholar 

  95. Röllgen FW (1983) Principles of field desorption mass spectrometry. In: Benninghoven A (ed) Ion Formation from Organic Solids. Springer, Heidelberg

    Google Scholar 

  96. Wong SS, Giessmann U, Karas M, Röllgen FW (1984) Field Desorption of Sucrose Studied by Combined Optical Microscopy and Mass Spectrometry. Int J Mass Spectrom Ion Proc 56:139–150. doi:10.1016/0168-1176(84)85038-7

    Article  CAS  Google Scholar 

  97. Derrick PJ (1986) Mass Spectroscopy at High Mass. Fresenius Z Anal Chem 324:486–491. doi:10.1007/BF00474121

    Article  CAS  Google Scholar 

  98. Davis SC, Natoli V, Neumann GM, Derrick PJ (1987) A Model of Ion Evaporation Tested Through Field Desorption Experiments on Glucose Mixed with Alkali Metal Salts. Int J Mass Spectrom Ion Proc 78:17–35. doi:10.1016/0168-1176(87)87039-8

    Article  CAS  Google Scholar 

  99. Reichert H (1997) Monodesoxygenierte Glucosid-Synthese und Kinetikstudien der enzymatischen Spaltung. PhD Thesis. Organisch-Chemisches Institut, Heidelberg University

    Google Scholar 

  100. Veith HJ (1976) Field Desorption Mass Spectrometry of Quaternary Ammonium Salts: Cluster Ion Formation. Org Mass Spectrom 11:629–633. doi:10.1002/oms.1210110609

    Article  CAS  Google Scholar 

  101. Veith HJ (1983) Mass Spectrometry of Ammonium and Iminium Salts. Mass Spectrom Rev 2:419–446. doi:10.1002/mas.1280020402

    Article  CAS  Google Scholar 

  102. Veith HJ (1980) Collision-Induced Fragmentations of Field-Desorbed Cations. 4. Collision-Induced Fragmentations of Alkylideneammonium Ions. Angew Chem Int Ed 19:541–542. doi:10.1002/anie.198005411

    Article  Google Scholar 

  103. Fischer M, Veith HJ (1981) Collision-Induced Fragmentations of Field-Desorbed Cations. 5. Reactions of 2- and 3-Phenyl Substituted Alkylalkylidene Iminium Ions in the Gas Phase. Helv Chim Acta 64:1083–1091. doi:10.1002/hlca.19810640413

    Article  CAS  Google Scholar 

  104. Miermans CJH, Fokkens RH, Nibbering NMM (1997) A Study of the Applicability of Various Ionization Methods and Tandem Mass Spectrometry in the Analyses of Triphenyltin Compounds. Anal Chim Acta 340:5–20. doi:10.1016/S0003-2670(96)00541-7

    Article  CAS  Google Scholar 

  105. Röllgen FW, Giessmann U, Heinen HJ (1976) Ion Formation in Field Desorption of Salts. Z Naturforsch A 31:1729–1730. doi:10.1515/zna-1976-1245

    Article  Google Scholar 

  106. Röllgen FW, Ott KH (1980) On the Formation of Cluster Ions and Molecular Ions in Field Desorption of Salts. Int J Mass Spectrom Ion Phys 32:363–367. doi:10.1016/0020-7381(80)80019-2

    Article  Google Scholar 

  107. Lehmann WD, Schulten HR (1977) Determination of Alkali Elements by Field Desorption Mass Spectrometry. Anal Chem 49:1744–1746. doi:10.1021/ac50020a028

    Article  CAS  Google Scholar 

  108. Schulten HR, Bohl B, Bahr U, Mueller R, Palavinskas R (1981) Qualitative and Quantitative Trace-Metal Analysis in Physiological Fluids of Multiple Sclerosis Patients by Field Desorption Mass Spectrometer. Int J Mass Spectrom Ion Phys 38:281–295. doi:10.1016/0020-7381(81)80073-3

    Article  CAS  Google Scholar 

  109. Keough T, DeStefano AJ (1981) Acid-Enhanced Field Desorption Mass Spectrometry of Zwitterions. Anal Chem 53:25–29. doi:10.1021/ac00224a009

    Article  CAS  Google Scholar 

  110. Gross JH (2007) Liquid Injection Field Desorption/Ionization Mass Spectrometry of Ionic Liquids. J Am Soc Mass Spectrom 18:2254–2262. doi:10.1016/j.jasms.2007.09.019

    Article  CAS  Google Scholar 

  111. Frauenkron M, Berkessel A, Gross JH (1997) Analysis of Ruthenium Carbonyl-Porphyrin Complexes: A Comparison of Matrix-Assisted Laser Desorption/Ionization Time-of-Flight, Fast-Atom Bombardment and Field Desorption Mass Spectrometry. Eur Mass Spectrom 3:427–438. doi:10.1255/ejms.177

    Article  CAS  Google Scholar 

  112. Lattimer RP, Harmon DJ, Welch KR (1979) Characterization of Low Molecular Weight Polymers by Liquid Chromatography and Field Desorption Mass Spectroscopy. Anal Chem 51:293–296. doi:10.1021/ac50044a040

    Article  Google Scholar 

  113. Craig AC, Cullis PG, Derrick PJ (1981) Field Desorption of Polymers: Polybutadiene. Int J Mass Spectrom Ion Phys 38:297–304. doi:10.1016/0020-7381(81)80074-5

    Article  CAS  Google Scholar 

  114. Lattimer RP, Schulten HR (1983) Field Desorption of Hydrocarbon Polymers. Int J Mass Spectrom Ion Phys 52:105–116. doi:10.1016/0020-7381(83)85094-3

    Article  CAS  Google Scholar 

  115. Matsuo T, Matsuda H, Katakuse I (1979) Use of Field Desorption Mass Spectra of Polystyrene and Polypropylene Glycol as Mass References Up to Mass 10000. Anal Chem 51:1329–1331. doi:10.1021/ac50044a050

    Article  CAS  Google Scholar 

  116. Ott KH, Röllgen FW, Zwinselmann JJ, Fokkens RH, Nibbering NMM (1980) Negative Ion Field Desorption Mass Spectra of Some Inorganic and Organic Compounds. Org Mass Spectrom 15:419–422. doi:10.1002/oms.1210150805

    Article  CAS  Google Scholar 

  117. Daehling P, Röllgen FW, Zwinselmann JJ, Fokkens RH, Nibbering NMM (1982) Negative Ion Field Desorption Mass Spectrometry of Anionic Surfactants. Fresenius Z Anal Chem 312:335–337. doi:10.1007/BF00470387

    Article  CAS  Google Scholar 

  118. Mes GF, Van der Greef J, Nibbering NMM, Ott KH, Röllgen FW (1980) The Formation of Negative Ions by Field Ionization. Int J Mass Spectrom Ion Phys 34:295–301. doi:10.1016/0020-7381(80)85043-1

    Article  CAS  Google Scholar 

  119. Dähling P, Ott KH, Röllgen FW, Zwinselmann JJ, Fokkens RH, Nibbering NMM (1983) Ionization by Proton Abstraction in Negative Ion Field Desorption Mass Spectrometry. Int J Mass Spectrom Ion Phys 46:301–304. doi:10.1016/0020-7381(83)80112-0

    Article  Google Scholar 

  120. Linden HB (2001) Electric field-induced ionization of analytes in mass spectrometer by desorption from microdendrite substrates, German Patent No. DE 99-19963317

    Google Scholar 

  121. Gross JH, Nieth N, Linden HB, Blumbach U, Richter FJ, Tauchert ME, Tompers R, Hofmann P (2006) Liquid Injection Field Desorption/Ionization of Reactive Transition Metal Complexes. Anal Bioanal Chem 386:52–58. doi:10.1007/s00216-006-0524-0

    Article  CAS  Google Scholar 

  122. Monillas WH, Yap GPH, Theopold KH (2007) A Tale of Two Isomers: A Stable Phenyl Hydride and a High-Spin (S = 3) Benzene Complex of Chromium. Angew Chem Int Ed 46:6692–6694. doi:10.1002/anie.200701933

    Article  CAS  Google Scholar 

  123. Schaub TM, Hendrickson CL, Quinn JP, Rodgers RP, Marshall AG (2005) Instrumentation and Method for Ultrahigh Resolution Field Desorption Ionization Fourier Transform Ion Cyclotron Resonance Mass Spectrometry of Nonpolar Species. Anal Chem 77:1317–1324. doi:10.1021/ac048766v

    Article  CAS  Google Scholar 

  124. Fu J, Klein GC, Smith DF, Kim S, Rodgers RP, Hendrickson CL, Marshall AG (2006) Comprehensive Compositional Analysis of Hydrotreated and Untreated Nitrogen-Concentrated Fractions from Syncrude Oil by Electron Ionization, Field Desorption Ionization, and Electrospray Ionization Ultrahigh-Resolution FT-ICR Mass Spectrometry. Energy Fuel 20:1235–1241. doi:10.1021/ef060012r

    Article  CAS  Google Scholar 

  125. Stanford LA, Rodgers RP, Marshall AG, Czarnecki J, Wu XA (2007) Compositional Characterization of Bitumen/Water Emulsion Films by Negative- and Positive-Ion Electrospray Ionization and Field Desorption/Ionization Fourier Transform Ion Cyclotron Resonance Mass Spectrometry. Energy Fuel 21:963–972. doi:10.1021/ef060291i

    Article  CAS  Google Scholar 

  126. Schaub TM, Rodgers RP, Marshall AG, Qian K, Green LA, Olmstead WN (2005) Speciation of Aromatic Compounds in Petroleum Refinery Streams by Continuous Flow Field Desorption Ionization FT-ICR Mass Spectrometry. Energy Fuel 19:1566–1573. doi:10.1021/ef049734d

    Article  CAS  Google Scholar 

  127. Smith DF, Schaub TM, Rodgers RP, Hendrickson CL, Marshall AG (2008) Automated Liquid Injection Field Desorption/Ionization for Fourier Transform Ion Cyclotron Resonance Mass Spectrometry. Anal Chem 80:7379–7382. doi:10.1021/ac801085r

    Article  CAS  Google Scholar 

  128. Heinen HJ, Hötzel C, Beckey HD (1974) Combination of a Field Desorption Ion Source with a Quadrupole Mass Analyzer. Int J Mass Spectrom Ion Phys 13:55–62. doi:10.1016/0020-7381(74)83005-6

    Article  CAS  Google Scholar 

  129. Gierlich HH, Heinen HJ, Beckey HD (1975) The Application of Quadrupole Mass Filters in Field Desorption Mass Spectrometry. Biomed Mass Spectrom 2:31–35. doi:10.1002/bms.1200020107

    Article  CAS  Google Scholar 

  130. Smith DF, Rahimi P, Teclemariam A, Rodgers RP, Marshall AG (2008) Characterization of Athabasca Bitumen Heavy Vacuum Gas Oil Distillation Cuts by Negative/Positive Electrospray Ionization and Automated Liquid Injection Field Desorption Ionization Fourier Transform Ion Cyclotron Resonance Mass Spectrometry. Energy Fuel 22:3118–3125. doi:10.1021/ef8000357

    Article  CAS  Google Scholar 

  131. Miyabayashi K, Naito Y, Miyake M (2009) Characterization of Heavy Oil by FT-ICR MS Coupled with Various Ionization Techniques. J Jpn Pet Inst 52:159–171. doi:10.1627/jpi.52.159

    Article  CAS  Google Scholar 

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Gross, J.H. (2017). Field Ionization and Field Desorption. In: Mass Spectrometry. Springer, Cham. https://doi.org/10.1007/978-3-319-54398-7_8

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