Abstract
Equilibrium is a central concept of statistical mechanics. In previous work we introduced the notions of a Boltzmannian α-ɛ-equilibrium and a Boltzmannian γ-ɛ-equilibrium (Werndl and Frigg, Stud Hist Philos Mod Phys 44:470–479, 2015a; Philos Sci 82:1224–1235, 2015b). This was done in a deterministic context. We now consider systems with a stochastic micro-dynamics and transfer these notions from the deterministic to the stochastic context. We then prove stochastic equivalents of the Dominance Theorem and the Prevalence Theorem. This establishes that also in stochastic systems equilibrium macro-regions are large in requisite sense.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
Notes
- 1.
We assume that ɛ is small enough so that \(\alpha (1-\varepsilon ) > \frac{1} {2}\).
- 2.
We assume that the dynamics is stationary, i.e. that ϕ t does not depend on time explicitly. This, however, is not a substantive assumption in the current context because standard systems in statistical mechanics such as gases and crystals are stationary.
- 3.
Here we can also illustrate the difference between an ω and a realisation r(ω). We could, for instance, also use ‘0’ and ‘1’ to encode the path of a stochastic process (where ‘0’ encodes the outcome Heads and ‘1’ encodes the outcome Tails). Then \(\Omega \) would consist of sequences such as ω = (…, 0, 1, 0, 1, …), but r(ω) = (… H, T, H, T, …). More radically, we could also use a real number ω ∈ [0, 1] to encode a sequence of 0s and 1s (via its binary development) and thus a sequence of outcomes of tossing a coin.
- 4.
We assume that ɛ is small enough so that \(\alpha (1-\varepsilon ) > \frac{1} {2}\).
- 5.
We assume that the dynamics is stationary, but, as in the deterministic case, this is not a substantive assumption because standard stochastic systems in statistical mechanics are stationary.
- 6.
- 7.
Note that it is also clear from Equation (20.10) that for sufficiently large μ c , M N LG corresponds to the largest macro-region.
- 8.
Again, this is clear from Equation (20.10).
- 9.
Mathematically speaking, the lattice gas is equivalent to the Ising model. The Ising model is one of the best developed and most widely studied models in physics and is discussed in nearly every modern textbook on statistical mechanics. In particular, the lattice gas on a square lattice with μ C = −ξ∕8 is equivalent to the two-dimensional Ising model with no external field, which is famous for being one of the very few exactly solved models that display phase transitions (Baxter 1982).
References
Baxter, Rodney. 1982. Exactly solved models in statistical mechanics. San Diego: Academic Press Limited.
Callender, Craig. 2001. Taking thermodynamics too seriously. Studies in History and Philosophy of Modern Physics 32: 539–553.
Cipra, Barry A. (1987). An introduction to the ising model. American Mathematical Monthly 94: 937–954.
Clarke, R., N. Caswell, and S.A. Solin. 1979. Melting and staging in graphite intercalated with cesium. Physical Review Letters 42: 61–64. doi:http://dx.doi.org/-10.1103/PhysRevLett.42.61.
de Ribaupierre, Y., and F.D. Manchester. 1974. Experimental study of the critical-point behaviour of the hydrogen in palladium system. I. Lattice gas aspects. Journal of Physics C: Solid State Physics 7: 2126–2139. doi: 10.1088/0022-3719/7/12/006.
Doob, Joseph L. 1953. Stochastic processes. New York: John Wiley & Sons.
Frigg, Roman. 2008. A field guide to recent work on the foundations of statistical mechanics. In The Ashgate companion to contemporary philosophy of physics, ed. Dean Rickles, 99–196. London: Ashgate.
Kierlik, E., P.A. Monson, M.L. Rosinberg, and G. Tarjus. 2002. Adsorption hysteresis and capillary condensation in disordered porous solids: a density functional study. Journal of Physics: Condensed Matter 14: 9295–9315. doi: 10.1088/0953-8984/14/40/319.
Kikuchi, Ryoichi, and John W. Cahn. 1980. Grain-boundary melting transition in a two-dimensional lattice-gas model. Physical Review B 21: 1893–1897.
Lavis, David. 2005. Boltzmann and Gibbs: An attempted reconciliation. Studies in History and Philosophy of Modern Physics 36: 245–273.
Lavis, David, and George M. Bell. 1999. Statistical Mechanics of Lattice Systems: Volume 1: Closed-Form and Exact Solutions. Berlin: Springer.
Jicai, Pan, Subal Das Gupta, and Martin Grant. 1998. First-Order Phase Transition in Intermediate-Energy Heavy Ion Collisions. Physical Review Letter 80: 1182–1885.
Reiss, Howard. 1996. Methods of Thermodynamics. Mineaola/NY: Dover.
Wang, Genmiao, Edith M. Sevinck, Emil Mittag, Debra J. Searles, and Denis J. Evans. 2002. Experimental demonstration of violations of the second law of thermodynamics for small systems and short time scales. Physical Review Letters 89: 050601.
Werndl, Charlotte. 2009. Are deterministic descriptions and indeterministic descriptions observationally equivalent? Studies in History and Philosophy of Modern Physics 40: 232–242.
Werndl, Charlotte. 2011. On the Observational Equivalence of Continuous-Time Deterministic and Indeterministic Descriptions. European Journal for the Philosophy of Science 1: 193–225.
Werndl, Charlotte, and Roman Frigg. 2015a. Reconceptualising equilibrium in Boltzmannian statistical mechanics and characterising its existence. Studies in History and Philosophy of Modern Physics 44: 470–479.
Werndl, Charlotte, and Roman Frigg. 2015b. Rethinking Boltzmannian equilibrium. Philosophy of Science 82: 1224–1235.
Yang, Chen Ning, and Tsung-Dao Lee. 1952. Statistical theory of equations of state and phase transitions. I. Theory of condensation. Physical Review 87: 404–409.
Author information
Authors and Affiliations
Corresponding author
Editor information
Editors and Affiliations
Appendices
Appendix
A.1 Proof of the Stochastic Dominance Theorem
First of all, let us show that a stationary stochastic process {Z t } can be represented by a measure-preserving deterministic system \((X,\Sigma _{X},\mu _{X},T_{t})\). Let X be the set of all possible realisations, i.e., functions x(τ) from \(\mathbb{R}\) or \(\mathbb{Z}\) to \(\bar{X}\). Let \(\Sigma _{X}\) be the σ-algebra generated by the cylinder-sets
Let μ X be the unique probability measure arising by assigning to each \(C_{i_{1}\ldots i_{n}}^{A_{1}\ldots A_{n}}\) the probability \(P\{Z_{i_{1}} \in A_{1},\ldots,Z_{i_{n}} \in A_{n}\}\). The evolution functions shift a realisation t times to the left, i.e., T t (x(τ)) = x(τ + t). The T t are invariant under the dynamics because {Z t } is stationary. \((X,\Sigma _{X},\mu _{X},T_{t})\) is a measure-preserving deterministic system called the deterministic representation (cf. Doob 1953, 621–622; Werndl 2009, 2011).
Let W = { x(τ) ∈ X | x(τ) = Z τ (ω) for all τ for a \(\omega \in \Omega ^{{\ast}}\}\). Note that μ X (W) ≥ 1 −ɛ. Consider first the case of an α-ɛ-equilibrium M α-ɛ-eq. Then it follows that for all x ∈ W:
where \(Q_{M_{\alpha \text{-}\varepsilon \text{-eq}}} =\{ x \in X\,\,\vert \,\,x(0) \in \bar{ X}_{M_{\alpha \text{-}\varepsilon \text{-eq}}}\}\).
Hence \(Q_{M_{\alpha \text{-}\varepsilon \text{-eq}}}\) is an α-ɛ-equilibrium of \((X,\Sigma _{X},\mu _{X},T_{t})\). It follows from the (deterministic) Dominance Theorem (Frigg and Werndl 2015a) that \(\mu _{X}(Q_{M_{\alpha \text{-}\varepsilon \text{-eq}}}) >\alpha (1-\varepsilon )\), which immediately implies that P{M α-ɛ-eq} > α(1 −ɛ).
A.2 Proof of the Stochastic Prevalence Theorem
The proof proceeds in the same fashion as the previous one. That is, consider again the measure-preserving deterministic system \((X,\Sigma _{X},\mu _{X},T_{t})\) that represents the stationary stochastic process {Z t }. Suppose that M γ-ɛ-eq is an γ-ɛ-equilibrium.
As before, let W = { x(τ) ∈ X | x(τ) = Z τ (ω) for all τ for a \(\omega \in \Omega ^{{\ast}}\}\). Note that μ X (W) ≥ 1 −ɛ.
Then for all x ∈ W and all M ≠ M γ-ɛ-eq it holds that
where \(Q_{M_{\gamma \text{-}\varepsilon \text{-eq}}} =\{ x \in X\,\,\vert \,\,x(0) \in \bar{ X}_{M_{\gamma \text{-}\varepsilon \text{-eq}}}\}\) and \(Q_{M} =\{ x \in X\,\,\vert \,\,x(0) \in \bar{ X}_{M}\}\). Hence \(Q_{M_{\gamma \text{-}\varepsilon \text{-eq}}}\) is an γ-ɛ-equilibrium of \((X,\Sigma _{X},\mu _{X},T_{t})\).
It follows from the (deterministic) Prevalence Theorem (cf. Werndl and Frigg 2015a) that \(\mu _{X}(Q_{M_{\gamma \text{-}\varepsilon \text{-eq}}}) \geq \mu _{X}(Q_{M}) +\gamma -\varepsilon\) for all M ≠ M γ-ɛ-eq. This immediately implies that P{M γ-ɛ-eq} ≥ P{M} +γ −ɛ for all M ≠ M γ-ɛ-eq.
Rights and permissions
Copyright information
© 2017 Springer International Publishing AG
About this paper
Cite this paper
Werndl, C., Frigg, R. (2017). Boltzmannian Equilibrium in Stochastic Systems. In: Massimi, M., Romeijn, JW., Schurz, G. (eds) EPSA15 Selected Papers. European Studies in Philosophy of Science, vol 5. Springer, Cham. https://doi.org/10.1007/978-3-319-53730-6_20
Download citation
DOI: https://doi.org/10.1007/978-3-319-53730-6_20
Published:
Publisher Name: Springer, Cham
Print ISBN: 978-3-319-53729-0
Online ISBN: 978-3-319-53730-6
eBook Packages: Religion and PhilosophyPhilosophy and Religion (R0)