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Boltzmannian Equilibrium in Stochastic Systems

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EPSA15 Selected Papers

Part of the book series: European Studies in Philosophy of Science ((ESPS,volume 5))

Abstract

Equilibrium is a central concept of statistical mechanics. In previous work we introduced the notions of a Boltzmannian α-ɛ-equilibrium and a Boltzmannian γ-ɛ-equilibrium (Werndl and Frigg, Stud Hist Philos Mod Phys 44:470–479, 2015a; Philos Sci 82:1224–1235, 2015b). This was done in a deterministic context. We now consider systems with a stochastic micro-dynamics and transfer these notions from the deterministic to the stochastic context. We then prove stochastic equivalents of the Dominance Theorem and the Prevalence Theorem. This establishes that also in stochastic systems equilibrium macro-regions are large in requisite sense.

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Notes

  1. 1.

    We assume that ɛ is small enough so that \(\alpha (1-\varepsilon ) > \frac{1} {2}\).

  2. 2.

    We assume that the dynamics is stationary, i.e. that ϕ t does not depend on time explicitly. This, however, is not a substantive assumption in the current context because standard systems in statistical mechanics such as gases and crystals are stationary.

  3. 3.

    Here we can also illustrate the difference between an ω and a realisation r(ω). We could, for instance, also use ‘0’ and ‘1’ to encode the path of a stochastic process (where ‘0’ encodes the outcome Heads and ‘1’ encodes the outcome Tails). Then \(\Omega \) would consist of sequences such as ω = (, 0, 1, 0, 1, ), but r(ω) = (… H, T, H, T, ). More radically, we could also use a real number ω ∈ [0, 1] to encode a sequence of 0s and 1s (via its binary development) and thus a sequence of outcomes of tossing a coin.

  4. 4.

    We assume that ɛ is small enough so that \(\alpha (1-\varepsilon ) > \frac{1} {2}\).

  5. 5.

    We assume that the dynamics is stationary, but, as in the deterministic case, this is not a substantive assumption because standard stochastic systems in statistical mechanics are stationary.

  6. 6.

    See Baxter (1982) and Cipra (1987) for more details about the lattice gas.

  7. 7.

    Note that it is also clear from Equation (20.10) that for sufficiently large μ c , M N LG corresponds to the largest macro-region.

  8. 8.

    Again, this is clear from Equation (20.10).

  9. 9.

    Mathematically speaking, the lattice gas is equivalent to the Ising model. The Ising model is one of the best developed and most widely studied models in physics and is discussed in nearly every modern textbook on statistical mechanics. In particular, the lattice gas on a square lattice with μ C  = −ξ∕8 is equivalent to the two-dimensional Ising model with no external field, which is famous for being one of the very few exactly solved models that display phase transitions (Baxter 1982).

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Appendices

Appendix

A.1 Proof of the Stochastic Dominance Theorem

First of all, let us show that a stationary stochastic process {Z t } can be represented by a measure-preserving deterministic system \((X,\Sigma _{X},\mu _{X},T_{t})\). Let X be the set of all possible realisations, i.e., functions x(τ) from \(\mathbb{R}\) or \(\mathbb{Z}\) to \(\bar{X}\). Let \(\Sigma _{X}\) be the σ-algebra generated by the cylinder-sets

$$\displaystyle{ C_{i_{1}\ldots i_{n}}^{A_{1}\ldots A_{n} }\!\! =\!\!\{ x\! \in \! X\,\vert \,x(i_{1})\!\! \in \!\! A_{1},\ldots,x(i_{n})\!\! \in \!\! A_{n},A_{j}\! \in \! \Sigma _{\bar{X}},i_{j}\! \in \! \mathbb{R}\,\,\text{or}\,\,\mathbb{Z},\,i_{1}\!\! <\ldots <\!\! i_{n},1\! \leq j\! \leq n\}. }$$
(20.11)

Let μ X be the unique probability measure arising by assigning to each \(C_{i_{1}\ldots i_{n}}^{A_{1}\ldots A_{n}}\) the probability \(P\{Z_{i_{1}} \in A_{1},\ldots,Z_{i_{n}} \in A_{n}\}\). The evolution functions shift a realisation t times to the left, i.e., T t (x(τ)) = x(τ + t). The T t are invariant under the dynamics because {Z t } is stationary. \((X,\Sigma _{X},\mu _{X},T_{t})\) is a measure-preserving deterministic system called the deterministic representation (cf. Doob 1953, 621–622; Werndl 20092011).

Let W = { x(τ) ∈ X  |  x(τ) = Z τ (ω) for all τ for a \(\omega \in \Omega ^{{\ast}}\}\). Note that μ X (W) ≥ 1 −ɛ. Consider first the case of an α-ɛ-equilibrium M α-ɛ-eq. Then it follows that for all x ∈ W:

$$\displaystyle{ LF_{X_{Q_{ M_{\alpha \text{-}\varepsilon \text{-eq}}}}}(x) \geq \alpha, }$$
(20.12)

where \(Q_{M_{\alpha \text{-}\varepsilon \text{-eq}}} =\{ x \in X\,\,\vert \,\,x(0) \in \bar{ X}_{M_{\alpha \text{-}\varepsilon \text{-eq}}}\}\).

Hence \(Q_{M_{\alpha \text{-}\varepsilon \text{-eq}}}\) is an α-ɛ-equilibrium of \((X,\Sigma _{X},\mu _{X},T_{t})\). It follows from the (deterministic) Dominance Theorem (Frigg and Werndl 2015a) that \(\mu _{X}(Q_{M_{\alpha \text{-}\varepsilon \text{-eq}}}) >\alpha (1-\varepsilon )\), which immediately implies that P{M α-ɛ-eq} > α(1 −ɛ).

A.2 Proof of the Stochastic Prevalence Theorem

The proof proceeds in the same fashion as the previous one. That is, consider again the measure-preserving deterministic system \((X,\Sigma _{X},\mu _{X},T_{t})\) that represents the stationary stochastic process {Z t }. Suppose that M γ-ɛ-eq is an γ-ɛ-equilibrium.

As before, let W = { x(τ) ∈ X  |  x(τ) = Z τ (ω) for all τ for a \(\omega \in \Omega ^{{\ast}}\}\). Note that μ X (W) ≥ 1 −ɛ.

Then for all x ∈ W and all MM γ-ɛ-eq it holds that

$$\displaystyle{ LF_{X_{Q_{ M_{\gamma \text{-}\varepsilon \text{-eq}}}}}(x) \geq LF_{X_{Q_{M}}} +\gamma -\varepsilon, }$$
(20.13)

where \(Q_{M_{\gamma \text{-}\varepsilon \text{-eq}}} =\{ x \in X\,\,\vert \,\,x(0) \in \bar{ X}_{M_{\gamma \text{-}\varepsilon \text{-eq}}}\}\) and \(Q_{M} =\{ x \in X\,\,\vert \,\,x(0) \in \bar{ X}_{M}\}\). Hence \(Q_{M_{\gamma \text{-}\varepsilon \text{-eq}}}\) is an γ-ɛ-equilibrium of \((X,\Sigma _{X},\mu _{X},T_{t})\).

It follows from the (deterministic) Prevalence Theorem (cf. Werndl and Frigg 2015a) that \(\mu _{X}(Q_{M_{\gamma \text{-}\varepsilon \text{-eq}}}) \geq \mu _{X}(Q_{M}) +\gamma -\varepsilon\) for all MM γ-ɛ-eq. This immediately implies that P{M γ-ɛ-eq} ≥ P{M} +γɛ for all MM γ-ɛ-eq.

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Werndl, C., Frigg, R. (2017). Boltzmannian Equilibrium in Stochastic Systems. In: Massimi, M., Romeijn, JW., Schurz, G. (eds) EPSA15 Selected Papers. European Studies in Philosophy of Science, vol 5. Springer, Cham. https://doi.org/10.1007/978-3-319-53730-6_20

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