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The Coastal Sulfuric Acid Cave System of Santa Cesarea Terme (Southern Italy)

  • Ilenia M. D’Angeli
  • Marco Vattano
  • Mario Parise
  • Jo De WaeleEmail author
Chapter
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Part of the Cave and Karst Systems of the World book series (CAKASYWO)

Abstract

Santa Cesarea Terme in Salento is the only area in which hypogenic caves have been recognized in the Apulia region. In this spa area, the rising of sulfidic thermal waters that mix with both recent fresh infiltration waters and coastal salt water has formed four active sulfuric acid speleogenesis (SAS) caves. These caves are characterized by the typical set of sulfuric acid meso- and micromorphologies, and also by the presence of both gypsum and native sulfur. In all caves, biofilms are visible in the sulfidic thermal waters and on the cave walls.

Keywords

Thermal water Spa Speleogenesis Hypogenic cave 

Notes

Acknowledgements

We thank the staff at the Santa Cesarea Terme spa for their availability. The Apulian Speleological Federation is kindly acknowledged for the work carried out during the cave surveys. We thank all the collaborators that helped us during the monitoring and sampling stage and the reviewers who gave us several interesting suggestions to improve this chapter.

References

  1. Basso A, Bruno E, Parise M, Pepe M (2013) Morphometric analysis of sinkholes in a karst coastal area of southern Apulia (Italy). Environ Earth Sci 70(6):2545–2559CrossRefGoogle Scholar
  2. Bosellini A, Bosellini FR, Colalongo ML, Parente M, Russo A, Vescogni A (1999) Stratigraphic architecture of the Salento coast from Capo d’Otranto to Santa Maria di Leuca (Apulia, southern Italy). Riv Ital Paleont Strat 105(3):397–416Google Scholar
  3. Bossio A, Mazzei R, Monteforti B, Salvatorini G (2005) Stratigrafia del Neogene e Quaternario del Salento sud-orientale (con rilevamento geologico alla scala 1:25.000). Geol Romana 38:31–60Google Scholar
  4. Bruno E, Calcaterra D, Parise M (2008) Development and morphometry of sinkholes in coastal plains of Apulia, southern Italy. Preliminary sinkhole susceptibility assessment. Eng Geol 99:198–209CrossRefGoogle Scholar
  5. Calò GC, Tinelli R (1995) Systematic hydrogeological study of a hypothermal spring (S. Cesarea Terme, Apulia), Italy. J Hydrol 165:185–205CrossRefGoogle Scholar
  6. Calò GC, Spizzico M, Tinelli R, Zezza F (1983) Hydrogeological investigations on the area surrounding Santa Cesarea Terme springs (southern Apulia). Geol Appl e Idrogeol 18(2):129–144Google Scholar
  7. Corti E (1992) Relazione sul Convegno Nazionale di Speleologia di Castro, 14-15-16 settembre 1936. Itinerari Speleol 6:89–97Google Scholar
  8. D’Agostino D, Beccarisi L, Camassa M, Febbroriello P (2015) Microclimate and microbial characterization in the Zinzulusa show cave (South Italy) after switching to led lighting. J Cave Karst Stud 77(3):133–144CrossRefGoogle Scholar
  9. De Giorgi C (1882) I bagni solfurei di Santa Cesarea in Terra d’Otranto. Riv Idrol e Clim Med 4:8Google Scholar
  10. Dell’Oca S (1962) Note di speleologia economica. Rassegna Speleol Ital 1:76–109Google Scholar
  11. De Waele J, Lauritzen SE, Parise M (2011) On the formation of dissolution pipes in quaternary coastal calcareous arenites in Mediterranean settings. Earth Surf Proc Land 36(2):143–157CrossRefGoogle Scholar
  12. De Waele J, Galdenzi S, Madonia G, Menichetti M, Parise M, Piccini L, Sanna L, Sauro F, Tognini P, Vattano M, Vigna B (2014) A review on hypogene caves in Italy. In: Klimchouk A, Sasowski ID, Mylroie J, Engel SA, Summers Engel A (eds), Hypogene cave morphologies, vol 18. Karst Water Institute, special publication, pp 28–30Google Scholar
  13. Doglioni C, Mongelli F, Pieri P (1994) The Puglia uplift (SE-Italy): an anomaly in the foreland of the Apenninic subduction due to buckling of a thick continental lithosphere. Tectonics 13(5):1309–1321CrossRefGoogle Scholar
  14. Edmunds WM, Smedley PL (2000) Residence time indicators in groundwater: the East Midlands Triassic sandstone aquifer. Appl Geochem 15:737–752CrossRefGoogle Scholar
  15. Galdenzi S (2012) Corrosion of limestone tablets in sulfidic ground-water: measurements and speleogenetic implications. Int J Speleol 41(2):149–159CrossRefGoogle Scholar
  16. Inguscio S, Lorusso D, Pascali V, Ragone G, Savino G (eds) (2007) Grotte e carsismo in Puglia. Regione Puglia, p 200Google Scholar
  17. Jones AA (2011) Microbe-mineral affinity in sulfuric acid karst systems. University of Austin, ThesisGoogle Scholar
  18. Jones DS, Polerecky L, Galdenzi S, Dempsey BA, Macalady JL (2015) Fate of sulfide in the Frasassi cave system and implications for sulfuric acid speleogenesis. Chem Geol 410:21–27CrossRefGoogle Scholar
  19. Klimchouk AB (2007) Hypogene speleogenesis: hydrogeological and morphogenetic perspective. Natl. Cave Karst Res. Inst, CarlsbadGoogle Scholar
  20. Margiotta S, Sansò P (2014) The geological heritage of Otranto-Leuca Coast (Salento, Italy). Geoheritage 6(4):305–316CrossRefGoogle Scholar
  21. Margiotta S, Negri S, Parise M, Valloni R (2012) Mapping the susceptibility to sinkholes in coastal areas, based on stratigraphy, geomorphology and geophysics. Nat Hazards 62(2):657–676CrossRefGoogle Scholar
  22. Mauget A (1875) Note geologiche sulla Provincia di Lecce. LecceGoogle Scholar
  23. Mostardini F, Merlini S (1986) Appennino centro meridionale. Sezioni geologiche e proposta di modello strutturale. Mem della Soc Geol Ital 35:177–202Google Scholar
  24. Palmentola G (2002) Il paesaggio carsico della Puglia. Grotte e dintorni 4:203–220Google Scholar
  25. Parise M (2008) Elementi di geomorfologia carsica della Puglia. In: Parise M, Inguscio S, Marangella A (eds), Atti del 45° Corso CNSS-SSI di III livello di Geomorfologia Carsica, Grottaglie, 2–3 febbraio 2008, p 93–118Google Scholar
  26. Parise M (2011) Some considerations on show cave management issues in Southern Italy. In: Van Beynen PE (ed) Karst management. Springer, Dordrecht, pp 159–167CrossRefGoogle Scholar
  27. Parise M, Federico A, Delle Rose M, Sammarco M (2003) Karst terminology in Apulia (southern Italy). Acta Carsol 32(2):65–82Google Scholar
  28. Parise M, De Pasquale P, Martimucci V, Meuli V, Pentimone N, Pepe P (2013) Grotta della Rondinella a Polignano a Mare: un progetto di ricerca della Federazione Speleologica Pugliese. In: Cucchi F, Guidi P (eds) Proceedings of the XXI National Congress Speleologia “Diffusione delle conoscenze”, Trieste, 2–5 giugno 2011, Ed. Università di Trieste, pp 437–448Google Scholar
  29. Plan L, Tschegg C, De Waele J, Spötl C (2012) Corrosion morphology and cave wall alteration in an Alpine sulfuric acid cave (Kraushöhle, Austria). Geomorphology 169:45–54CrossRefGoogle Scholar
  30. Polemio M, Limoni PP, Zuffianò LE, Santaloia F (2012) Santa Cesarea thermal springs (Southern Italy). In: Thangarajan M, Mayilswami C, Kulkarni PS, Singh VP (eds) 5th international groundwater conference (IGWC) assessment and management of groundwater resources in hard rock systems with special reference to basaltic terrain vol 15, 737–752Google Scholar
  31. Ricchetti G, Ciaranfi N, Luperto Sinni E, Mongelli F, Pieri P (1988) Geodinamica ed evoluzione sedimentaria e tettonica dell’Avampaese Apulo. Mem della Soc Geol Ital 41:57–82Google Scholar
  32. Santaloia F, Zuffianò LE, Palladino G, Limoni PP, Liotta D, Minissale A (2016) Coastal thermal springs in a foreland setting: the Santa Cesarea Terme system (Italy). Geothermics 64:344–361CrossRefGoogle Scholar
  33. Tadolini T, Bruno G (1993) The influence of geostructural setting upon water thermo-mineralization in certain areas of Apulia (Southern Italy). In: Proceedings of the Antalya symposium and field seminar, vol 207, Oct 1990, IAHS, pp 75–83Google Scholar
  34. Taviani M, Angeletti L, Campiani E, Ceregato A, Foglini F, Maselli V, Morsilli M, Parise M, Trincardi F (2012) Drowned karst landscapes offshore the Apulian Margin (Southern Adriatic Sea, Italy). J Cave Karst Stud 74(2):197–212CrossRefGoogle Scholar
  35. Visintin B (1945) Studio sull’acqua della Grotta Gattulla delle Terme demaniali di S. Cesarea Ann Chim Appl 35(6–7):97–111Google Scholar
  36. Zezza F (1980) Le sorgenti ipotermali solfuree di Santa Cesarea Terme. Azienda di cura e soggiorno e turismo Santa Cesarea Terme. Salentum, pp 1–2Google Scholar
  37. Zuffianò LE, Palladino G, Santaloia F, Polemio M, Liotta D, Limoni PP, Parise M, Pepe M, Casarano D, Rizzo E, Minissale A, De Franco R (2013) Geothermal resource in a foreland environment: the Santa Cesarea Terme thermal springs (Southern Italy). European Geothermal Congress 2013, Pisa, 3–7 June 2013, p 6Google Scholar

Copyright information

© Springer International Publishing AG 2017

Authors and Affiliations

  • Ilenia M. D’Angeli
    • 1
  • Marco Vattano
    • 2
  • Mario Parise
    • 3
  • Jo De Waele
    • 1
    Email author
  1. 1.Italian Institute of Speleology, Department of Biological Geological and Environmental SciencesUniversity of BolognaBolognaItaly
  2. 2.Department of Earth and Marine SciencesUniversity of PalermoPalermoItaly
  3. 3.Department of Earth and Geo-Environmental SciencesUniversity of Bari Aldo MoroBariItaly

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