Abstract
The discovery, 30 years ago, of superconductivity at 35 K in the Ba-La-Cu-O system has stimulated a huge number of studies. From the analysis of the numerous data, it is shown that the ability of barium to generate the highest Tc’s originates, besides its size, from its particular “oxygenation capacity” which influences dramatically the copper mixed valence.
Dedicated to Professor K.A. Müller on the Occasion of his 90th Birthday.
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Raveau, B. (2017). Essential Role of Barium for Reaching the Highest Tc’s in Superconducting Cuprates. In: Bussmann-Holder, A., Keller, H., Bianconi, A. (eds) High-Tc Copper Oxide Superconductors and Related Novel Materials. Springer Series in Materials Science, vol 255. Springer, Cham. https://doi.org/10.1007/978-3-319-52675-1_21
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