Abstract
A novel process of magnesium production has been developed by changing the preparation method of pellets of silicothermic process. For the method, the pellets consist of dolomite, ferrosilicon, fluorite and binder, which need to be roasted before reduction. After calcinations, porous pellets were obtained due to the decomposition of dolomite in the pellets. Heat transfer of the porous pellets is different from that of pellets used in Pidgeon process. In the present paper, a comparative study on heat transfer of the novel process and Pidgeon process was carried out by numerical method. The results indicated that heat transfer in Pidgeon pellets is slightly better than that in the porous pellets. For the novel process, the center temperature in a retort of 300 mm-diameter reaches 1473 K after heating the retort at 1523 K for 2.3 h (without considering reaction heat), which needs 4.8 h for the Pidgeon process.
References
M.A.O. Ping-li, L.I.U. Zheng, W.A.N.G. Chang-yi, G.U.O. Quan-ying, S.U.N. Jin, W.A.N.G. Feng, L.I.N. Li, Fatigue behavior of magnesium alloy and application in auto steering wheel frame. Trans. Nonferrous Metals Soc. China 18(1), s218–s222 (2008)
L.I.U. Bin, T.A.N.G. Ai-tao, P.A.N. Fu-sheng, Z.H.A.N.G. Jing, P.E.N.G. Jian, W.A.N.G. Jing-feng, Improvement and application of neural network models in development of wrought magnesium alloys. Trans. Nonferrous Metals Soc. China 21(4), 885–891 (2011)
O.A. Lebedev, Y. Brusakov, N.P. Shkuryakov, Express monitoring of MgCl2 concentration in the electrolyte of magnesium electrolyzers. Russ. J. Appl. Chem. 78(8), 1276–1279 (2005)
A. Krishnan, U.B. Pal, X.G. Lu, Solid oxide membrane process for magnesium production directly from magnesium oxide. Metall. Mater. Trans. B 36(4), 463–473 (2005)
Winny Wulandari, Geoffrey A. Brooks, Muhammad A. Rhamdhani, Magnesium: current and alternative production routes. Chemeca Eng. Edge 2010, 347–357 (2010)
R. Winand, M.V. Gysel, A. Fontana, L. Segers, J.C. Carlier, Production of magnesium by vacuum carbothermic reduction of calcined dolomite. Trans. Inst. Min. Metall., Sect. C 99, C105–C112 (1990)
Li Rong-ti, Pan Wei, M. Sano, Kinetics and mechanism of carbothermic reduction of magnesia. Metall. Mater. Trans. B 34B, 433–437 (2003)
G. Brooks, S. Trang, P. Witt, M.N.H. Khan, M. Nagle, The carbothermic route to magnesium. JOM 58(5), 51–55 (2006)
S. Tassios, T.R.D. Barton, K.K. Constanti-Carey, M.W. Nagle, L.H. Prentice, Manufacture of metal E.G. magnesium, involves performing carbothermal reduction of metal oxide, preventing reformation of metal oxide, and cooling stream using Nozzle heated with unit other than gas under specific condition. WO2010012042-A1 (2010)
A. Donaldson, R.A. Cordes, Rapid plasma quenching for the production of ultrafine metal and ceramic powders. JOM 57(4), 58–63 (2005)
M. Abdellatif, Review of the development work on the Mintek thermal magnesium process(MTMP). J. S. Afr. Instit Min. Metall 111, 393–399 (2011)
D.J. Zuliani, D. Reeson, Making magnesium a more cost and environmentally competitive option, in Conference of Magnesium Alloy in Vancouver (2012). http://www.gossan.ca/pdfs/Conference9MagALLOY-Paper-Vancouver-July2012.pdf
L.M. Pidgeon, W.A. Alexander, Trans. Am. Inst. Min. Met. Eng. 159, 315–352 (1944)
J.M. Toguri, L.M. Pidgeon, Can. J. Chem. 39(3), 540–547 (1961)
J.M. Toguri, L.M. Pidgeon, Can. J. Chem. 40(9), 1769–1776 (1962)
H.U. Wen-xin, Liu Jian, Feng Nai-xiang, P.E.N.G. Jian-ping, Vacuum thermal reduction kinetics of calcined dolomite with Al-Si-Fe alloy. Chin. J. Process Eng. 10(1), 127–132 (2010). (in Chinese)
X.I.E. Wei-dong, D.A.N.G. Chun-mei, L.I. Zhao-nan, P.E.N.G. Xiao-dong, W.A.N.G. Hao, Preparation of Mg using Si-Cu reduction and its thermodynamics. Chin. J. Rare Metals 36(2), 213–217 (2012). (in Chinese)
I.M. Morsi, K.A.E. Barawy, M.B. Morsi, S.R. Abdel-Gawad, Silicothermic reduction of dolomite ore under inert atmosphere. Can. Metall. Q. 41, 15–28 (2002)
G.C. Holywell, Magnesium: the first quarter millennium. JOM 57, 26–33 (2005)
U.S. Geological Survey, Mineral Commodity Summaries, Jan 2015, p. 99
R.B. Li, J.J. Wei, L.J. Guo, S.J. Zhang, in 7th International Conference on CFD in the Minerals and Processing Industries, ed. by P.J. Witt, M.P. Schwarz (CSIRO, Canberra, ACT, Australia, 2009). http://www.cfd.com.au/cfd_conf09/PDFs/088LI.pdf
R.B. Li, S.J. Zhang, L.J. Guo, J.J. Wei, Numerical study of magnesium (Mg) production by the Pidgeon process: impact of heat transfer on Mg reduction process. Int. J. Heat Mass Transf. 59, 328–337 (2013)
T.A. Zhang, Z.H. Dou, Z.M. Zhang, M. Wen, Y. Liu, G.Z. Lv, CN Patent CN102965524-B (2014)
M. Wen, T.A. Zhang Z.H. Dou, X.D. Ren, R. Zhang, L. Zhou, Magnesium Technology (The Minerals, Metals & Materials Society, Warrendale, PA; Wiley, Hoboken, NJ, 2013), pp. 75–79
M. Wen, T.A. Zhang, Z.H. Dou, Y. Guan, R. Zhang, Chin. J. Vac. Sci. Technol. 34, 1242 (2014)
D.X. Fu, L.K. Guan, M. Wen, Z.H. Dou, R. Zhang, T.A. Zhang, Magnesium Technology (The Minerals, Metals & Materials Society, Wiley, Warrendale, PA, Hoboken, NJ, 2015), pp. 49–53
R. Zhang, Study on Pellet Preparation of Novel Silicothermic Process, Master Thesis, Northeastern University, Shenyang (2014)
Acknowledgements
This research was supported by the Fundamental Research Funds for the Central Universities of China (N130302006, N140204013, N130102002, N130702001), National Natural Science Foundation of China under Grant (51504058; U1508217; 51404054; 51374064) and Education Department of Liaoning Province (LZ2014021).
Author information
Authors and Affiliations
Corresponding author
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 2017 The Minerals, Metals & Materials Society
About this paper
Cite this paper
Fu, D., Zhang, Ta., Dou, Zh., Guan, L., Wen, M. (2017). Numerical Study of Magnesium Production by Pidgeon Process and Pre-prepared Pellets Silicothermic Process: Comparison of Heat Transfer. In: Solanki, K., Orlov, D., Singh, A., Neelameggham, N. (eds) Magnesium Technology 2017. The Minerals, Metals & Materials Series. Springer, Cham. https://doi.org/10.1007/978-3-319-52392-7_18
Download citation
DOI: https://doi.org/10.1007/978-3-319-52392-7_18
Published:
Publisher Name: Springer, Cham
Print ISBN: 978-3-319-52391-0
Online ISBN: 978-3-319-52392-7
eBook Packages: Chemistry and Materials ScienceChemistry and Material Science (R0)