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Phase Analysis of the Si-O2 System

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Part of the book series: The Minerals, Metals & Materials Series ((MMMS))

Abstract

In this work the equilibrium temperature-composition phase diagrams of the Si-O2 system were calculated using Thermo-Calc software in the temperature range 500–3000 K. Constituents of stable phases were obtained, and the amounts of certain phases where investigated with the variations in the composition of oxygen and temperature. It is found that quartz with silicon represent a stable phase in the temperature range 500–1150 K, while tridymite with silicon represent a stable phase in the temperature range 1150–1700 K. A liquid phase is found besides tridymite in the temperature range 1700–1750 K, and a stable phase of cristobalite with liquid appears in the temperature range 1750–2000. The maximum amounts of quartz, tridymite, and cristobalite are found at oxygen mole percent of 67.7%. These results are important to better understand the process steps in the production of silicon for different applications including silicon solar cells .

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Correspondence to Shadia J. Ikhmayies .

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© 2017 The Minerals, Metals & Materials Society

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Ikhmayies, S.J. (2017). Phase Analysis of the Si-O2 System. In: Zhang, L., et al. Energy Technology 2017. The Minerals, Metals & Materials Series. Springer, Cham. https://doi.org/10.1007/978-3-319-52192-3_33

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