Abstract
In view of the steady depletion of primary sources of copper and the increased global demand for refined copper, it becomes necessary to explore some secondary sources for possible extraction of copper. The waste copper smelter dust (CSD) is a rich secondary resource for copper as shown by the chemical composition of the South African Palabora coppers smelter plant CSD that assayed 18.02, 13.36, and 3.4 wt% copper, iron and sulphur; respectively. Studies on CSD have focused majorly on either dust characterization or treatment, while hydrometallurgical extraction without pretreatment and with pretreatment using techniques such as oxidative roasting are also considered quite attractive. The challenge of iron dissolution during the leaching stage in these processes necessitates adequate purification of the leach liquor before the extraction of the metal as nano-particles. Hence, this review examined the theories relating to the characterization and treatment of CSD for copper recovery as nanoparticles; with factors having a bearing on the treatment process such as kinetics considered with the aim of providing scientific basis for the research.
References
A.A. Baba, K.I. Ayinla, F.A. Adekola, M.K. Ghosh, O.S. Ayanda, R.B. Bale, A.R. Sheik, S.R. Pradhan, A review on novel techniques for chalcopyrite ore processing. Int. J. Min. Eng. Mineral Process. 1(1), 1–16 (2012)
USGS, Facts about Copper: copper uses, resources, supply, demand and production information 2009, http://eology.comusgsuses-of-copper/. Accessed 15/12/2010
R.T. Jones, P.J. Mackey, An overview of copper smelting in Southern Africa (2015)
J. Wood, S. Creedy, R. Matusewicz, M. Reuter, Secondary copper processing using Outotec Ausmelt TSL technology, in Proceedings of MetPlant (2011), pp. 460–467
M. Reuter, A. van Schaik, Thermodynamic metrics for measuring the “sustainability” of design for recycling. JOM 60(8), 39–46 (2008)
European Commission, European Dioxin Inventory—Secondary Copper Production [online] (2009). Available from http://ec.europa.eu/environment/dioxin/pdf/stage1/seccopper.pdf. Accessed 23 Feb 2011. A. Umer et al., Selection of a suitable method for the synthesis of copper nanoparticles. Nano 7(05), 1230005 (2012)
J.B. Wang, C.H. Hung, C.H. Hung, G.P. Chang-Chien, Polychlorinated dibenzo-p-dioxin and dibenzofuran emissions from an industrial park clustered with metallurgical industries. J. Hazard. Mater. 161(2), 800–807 (2009)
V. Montenegro, H. Sano, T. Fujisawa, Recirculation of Chilean copper smelting dust with high arsenic content to the smelting process. Mater. Trans. 49(9), 2112–2118 (2008)
Regulation EC, No 1907/2006 of the European Parliament and of the Council of 18 December 2006, concerning the Registration. Evaluation, Authorisation and Restriction of Chemicals (REACH), establishing a European Chemicals Agency, amending Directive, vol. 45 (1999), pp. 1–849
SANS, South African National Standard: Ambient Air Quality—Limits for Common Pollutants (2005)
U. Neveling, Palabora Mining Company Annual report on ambient air quality monitoring (2011)
L. Qiang, I.S. Pinto, Z. Youcai, Sequential stepwise recovery of selected metals from flue dusts of secondary copper smelting. J. Clean. Prod. 84, 663–670 (2014)
I.S. Pinto, H.M. Soares, Selective leaching of molybdenum from spent hydrodesulphurisation catalysts using ultrasound and microwave methods. Hydrometallurgy 129, 19–25 (2012)
I.S. Pinto, H.M. Soares, Recovery of molybdates from an alkaline leachate of spent hydrodesulphurisation catalyst–proposal of a nearly-closed process. J. Clean. Prod. 52, 481–487 (2013)
F. Bakhtiari, H. Atashi, M. Zivdar, S.S. Bagheri, Continuous copper recovery from a smelter’s dust in stirred tank reactors. Int. J. Miner. Process. 86(1), 50–57 (2008)
F. Bakhtiari, M. Zivdar, H. Atashi, S.S. Bagheri, Bioleaching of copper from smelter dust in a series of airlift bioreactors. Hydrometallurgy 90(1), 40–45 (2008)
F.J. Alguacil, I. Garcia-Diaz, F. Lopez, O. Rodriguez, Recycling of copper flue dust via leaching-solvent extraction processing. Desalin. Water Treat. 56(5), 1202–1207 (2015)
G.A. Kordosky, Copper recovery using leach/solvent extraction/electrowinning technology: forty years of innovation, 2.2 million tonnes of copper annually. J. S. Afr. Inst. Min. Metall. 102(8), 445–450 (2002)
N.N. Hoover, B.J. Auten, B.D. Chandler, Tuning supported catalyst reactivity with dendrimer-templated Pt-Cu nanoparticles. J. Phys. Chem. B 110(17), 8606–8612 (2006)
Y. Niu, R.M. Crooks, Preparation of dendrimer-encapsulated metal nanoparticles using organic solvents. Chem. Mater. 15(18), 3463–3467 (2003)
E. Darezereshki, F. Bakhtiari, Synthesis and characterization of tenorite (CuO) nanoparticles from smelting furnace dust (SFD). J. Min. Metall. B: Metall. 49(1), 21–26 (2013)
C. Samuelsson, G. Carlsson, Characterization of copper smelter dusts. CIM Bull. 94(1051), 111–115 (2001)
Y. Chen, T. Liao, G. Li, B. Chen, X. Shi, Recovery of bismuth and arsenic from copper smelter flue dusts after copper and zinc extraction. Miner. Eng. 39, 23–28 (2012)
D.K. Steele, K.S. Gritton, S.B. Odedirk, Treatment of Copper Smelting and Refining Wastes (US Department of the Interior, Bureau of Mines, 1994)
A.K. Biswas, W.G. Davenport, Extractive Metallurgy of Copper: International Series on Materials Science and Technology, vol. 20. Elsevier (2013)
D.R. Swinbourne, E. Simak, A. Yazawa, V. Melbourne, Accretion and dust formation in copper smelting-thermodynamic considerations, in Sulfide Smelting (2002), pp. 247–259
E. Miettinen, Thermal conductivity and characteristics of copper flash smelting flue dust accretions. Teknillinen korkeakoulu (2008)
J.A. Eastman, S.U.S. Choi, S. Li, W. Yu, L.J. Thompson, Anomalously increased effective thermal conductivities of ethylene glycol-based nanofluids containing copper nanoparticles. Appl. Phys. Lett. 78(6), 718–720 (2001)
R.K. Guduru, K.L. Murty, K.M. Youssef, R.O. Scattergood, C.C. Koch, Mechanical behavior of nanocrystalline copper. Mater. Sci. Eng., A 463(1), 14–21 (2007)
Y. Wang, M. Chen, F. Zhou, E. Ma, High tensile ductility in a nanostructured metal. Nature 419(6910), 912–915 (2002)
X. Kang, Z. Mai, X. Zou, P. Cai, J. Mo, A sensitive nonenzymatic glucose sensor in alkaline media with a copper nanocluster/multiwall carbon nanotube-modified glassy carbon electrode. Anal. Biochem. 363(1), 143–150 (2007)
K.B. Male, S. Hrapovic, Y. Liu, D. Wang, J.H. Luong, Electrochemical detection of carbohydrates using copper nanoparticles and carbon nanotubes. Anal. Chim. Acta 516(1), 35–41 (2004)
Y. Guo, W. Meyer-Zaika, M. Muhler, S. Vukojević, M. Epple, Cu/Zn/Al xerogels and aerogels prepared by a sol–gel reaction as catalysts for methanol synthesis. Eur. J. Inorg. Chem. 2006(23), 4774–4781 (2006)
M.L. Kantam, V.S. Jaya, M.J. Lakshmi, B.R. Reddy, B.M. Choudary, S.K. Bhargava, Alumina supported copper nanoparticles for aziridination and cyclopropanation reactions. Catal. Commun. 8(12), 1963–1968 (2007)
J.A. Rodriguez, P. Liu, J. Hrbek, J. Evans, M. Perez, Water gas shift reaction on Cu and Au nanoparticles supported on CeO2 (111) and ZnO (000$ bar 1$): intrinsic activity and importance of support interactions. Angew. Chem. 119(8), 1351–1354 (2007)
C. Pecharromán, A. Esteban-Cubillo, I. Montero, J.S. Moya, E. Aguilar, J. Santarén, A. Alvarez, Monodisperse and corrosion-resistant metallic nanoparticles embedded into sepiolite particles for optical and magnetic applications. J. Am. Ceram. Soc. 89(10), 3043–3049 (2006)
E. Balladares, U. Kelm, S. Helle, R. Parra, E. Araneda, Chemical-mineralogical characterization of copper smelting flue dust. Dyna 81(186), 11–18 (2014)
M. Vítková, V. Ettler, J. Hyks, T. Astrup, B. Kříbek, Leaching of metals from copper smelter flue dust (Mufulira, Zambian Copperbelt). Appl. Geochem. 26, S263–S266 (2011)
A. Morales, M. Cruells, A. Roca, R. Bergó, Treatment of copper flash smelter flue dusts for copper and zinc extraction and arsenic stabilization. Hydrometallurgy 105(1), 148–154 (2010)
A.B. Vakylabad, A comparison of bioleaching ability of mesophilic and moderately thermophilic culture on copper bioleaching from flotation concentrate and smelter dust. Int. J. Miner. Process. 101(1), 94–99 (2011)
A.B. Vakylabad, M. Schaffie, M. Ranjbar, Z. Manafi, E. Darezereshki, Bio-processing of copper from combined smelter dust and flotation concentrate: A comparative study on the stirred tank and airlift reactors. J. Hazard. Mater. 241, 197–206 (2012)
J.Y. Wu, F.C. Chang, H.P. Wang, M.J. Tsai, C.H. Ko, C.C. Chen, Selective leaching process for the recovery of copper and zinc oxide from copper-containing dust. Environ. Technol. 36(23), 2952–2958 (2015)
T.K. Ha, B.H. Kwon, K.S. Park, D. Mohapatra, Selective leaching and recovery of bismuth as Bi2O3 from copper smelter converter dust. Sep. Purif. Technol. 142, 116–122 (2015)
L.G. Austin, I. Shah, A method for inter-conversion of Microtrac and sieve size distributions. Powder Technol. 35(2), 271–278 (1983)
B.A. Wills, T. Napier-Munn, Wills’ mineral processing technology: an introduction to the practical aspects of ore treatment and mineral recovery. Butterworth-Heinemann (2015)
Z.F. Xu, L.I. Qiang, H.P. Nie, Pressure leaching technique of smelter dust with high-copper and high-arsenic. Trans. Nonferrous Met. Soc. China 20, s176–s181 (2010)
V. Ettler, M. Vítková, M. Mihaljevič, O. Šebek, M. Klementová, F. Veselovský, P. Vybíral, B. Kříbek, Dust from Zambian smelters: mineralogy and contaminant bioaccessibility. Environ. Geochem. Health 36(5), 919–933 (2014)
T. Rosenqvist, Principles of Extractive Metallurgy. Tapir Academic Press (2004)
The encyclopedia of earth, 2015: https://en.wikipedia.org/wiki/Encyclopedia_of_Earth
S.K. Kawatra, T.C. Eisele, Depression of Pyrite Flotation by Yeast and Bacteria. Mineral Biotechnology: Microbial Aspects of Mineral Beneficiation, Metal Extraction, and Environmental Control (2001), p. 3
S. Prasad, B.D. Pandey, Alternative processes for treatment of chalcopyrite—a review. Miner. Eng. 11(8), 763–781 (1998)
F. Magagula, High temperature roasting of sulphide concentrate and its effect on the type of precipitate formed. Doctoral dissertation, 2012
Z.B. Yin, E. Caba, L. Barron, D. Belin, W. Morris, M. Vosika, R. Bartlett, Copper extraction from smelter flue dust by lime-roast/ammoniacal heap leaching. Residues and Effluents: Processing and Environmental Considerations (1992), pp. 255–267
B. Gorai, R.K. Jana, Z.H. Khan, Electrorefining electrolyte from copper plant dust. Mater. Trans. 43(3), 532–536 (2002)
M.P. Smirnov, V.T. Khvan, G.A. Bibenina, R.P. Kefilyan, N.I. Il’yasov, Complex treatment of lead and rhenium containing sulfate dusts from copper plants. Tsvetn. Met. 6, 3–6 (1984)
Z.W. Zhang, W. Lu, F. Zheng, Separation and recovery of copper and zinc from flue dust. Huanjing Kexue 11(6), 1012–1016 (1992)
M. Carter, E.R. Vance, L.P. Aldridge, M. Zaw, G. Khoe, Immobilization of arsenic trioxide in cementitious materials, in Australasian Institute of Mining and Metallurgy (1994), pp. 275–280
Y. Fu, L. Jiang, D. Wang, Removal of arsenic from copper smelter flue dust by calcinations. Yelian Bufen 6, 14–16 (2000)
Z. Yu, Process for bismuth recovery from the flue dust of copper smelting. Huaxue Shijie 28(10), 465–468 (1987)
H. Mochida, O. Iida, Copper smelter flue dust treatment (Kokai Tokkyo Koho, Jap, 1988), p. 3
H.H. Law, M.P. Bohrer, P. O’Hara, Recovery of metals from copper smelter furnace flue dust. Residues and Effluents: Processing and Environmental Considerations (1992), pp. 295–310
R.S. Kunter, W.E. Bedal, Chloride-process treatment of smelter flue dusts. JOM 44(12), 35–38 (1992)
G.J. Roman-Moguel, G. Plascencia, J. Pérez, A. García, Copper recycling from waste pickling solutions. JOM 47(10), 18–19 (1995)
P.J. Gabb, J.P. Evans, Kennecott Utah Copper Corporation, Hydrometallurgical processing of impurity streams generated during the pyrometallurgy of copper. U.S. Patent 5,616,168, 1997
A. Robles, A.E. Serna, M. Sandez, Alkaline arsenic leaching from smelter flue dust and leaching solution regeneration, in Copper99-Cobre99, International Conference on TMS-AIME, Warrendale, PA (1999), pp. 261–272
E. Vircikova, M. Havlik, Removing as from converter dust by a hydrometallurgical method. JOM 51(9), 20–23 (1999)
J.J. Ke, R.Y. Qin, Arsenic removal and bismuth recovery from copper smelter flue dust (2000)
M.I. Martín, A. López-Delgado, F.A. López, A.G. Coedo, M.T. Dorado, F.J. Alguacil, Treatment of copper converter flue dust for the separation of metallic/non-metallic copper by hydrometallurgical processing. J. Chem. Eng. Jpn. 36(12), 1498–1502 (2003)
N.T. Beukes, J. Badenhorst, Copper electrowinning: theoretical and practical design. J. South Afr. Inst. Min. Metall. 109(6), 343–356 (2009)
O. Kubaschewski, C.B. Alcock, P.J. Spencer, Materials Thermodynamics (1993)
F. Bakhtiari, E. Darezereshki, One-step synthesis of tenorite (CuO) nano-particles from Cu4(SO4)(OH)6 by direct thermal-decomposition method. Mater. Lett. 65(2), 171–174 (2011)
X. Song, S. Sun, W. Zhang, Z. Yin, A method for the synthesis of spherical copper nanoparticles in the organic phase. J. Colloid Interface Sci. 273(2), 463–469 (2004)
S. Kapoor, T. Mukherjee, Photochemical formation of copper nanoparticles in poly (N-vinylpyrrolidone). Chem. Phys. Lett. 370(1), 83–87 (2003)
M. Aslam, G. Gopakumar, T.L. Shoba, I.S. Mulla, K. Vijayamohanan, S.K. Kulkarni, J. Urban, W. Vogel, Formation of Cu and Cu2O nanoparticles by variation of the surface ligand: preparation, structure, and insulating-to-metallic transition. J. Colloid Interface Sci. 255(1), 79–90 (2002)
H. Zhu, C. Zhang, Y. Yin, Novel synthesis of copper nanoparticles: influence of the synthesis conditions on the particle size. Nanotechnology 16(12), 3079 (2005)
Y. Wang, P. Chen, M. Liu, Synthesis of well-defined copper nanocubes by a one-pot solution process. Nanotechnology 17(24), 6000 (2006)
S. Panigrahi, S. Kundu, S.K. Ghosh, S. Nath, S. Praharaj, S. Basu, T. Pal, Selective one-pot synthesis of copper nanorods under surfactantless condition. Polyhedron 25(5), 1263–1269 (2006)
B.K. Park, S. Jeong, D. Kim, J. Moon, S. Lim, J.S. Kim, Synthesis and size control of monodisperse copper nanoparticles by polyol method. J. Colloid Interface Sci. 311(2), 417–424 (2007)
A.A. Athawale, P.P. Katre, M. Kumar, M.B. Majumdar, Synthesis of CTAB–IPA reduced copper nanoparticles. Mater. Chem. Phys. 91(2), 507–512 (2005)
X. Zhang, D. Zhang, X. Ni, J. Song, H. Zheng, Synthesis and electrochemical properties of different sizes of the CuO particles. J. Nanopart. Res. 10(5), 839–844 (2008)
E. Darezereshki, F. Bakhtiari, A novel technique to synthesis of tenorite (CuO) nanoparticles from low concentration CuSO4 solution. J. Min. Metall. B 47(1), 73–78 (2011)
K. Byrappa, Hydrothermal processing, in Kirk-Othmer Encyclopedia of Chemical Technology (2005)
C.W. Bale, P. Chartrand, S.A. Degterov, G. Eriksson, K. Hack, R.B. Mahfoud, J. Melançon, A.D. Pelton, S. Petersen, FactSage thermochemical software and databases. Calphad 26(2), 189–228 (2002)
Wikipedia 2014 https://en.wikipedia.org/wiki
S. Rosenblum, I.K. Brownfield, Magnetic Susceptibilities of Minerals. US Department of the Interior, US Geological Survey (2000)
Z.A. Zanetell, Penalty element separation from copper concentrates utilizing froth flotation (2007)
O. Font, N. Moreno, G. Aixa, X. Querol, R. Navia, Copper Smelting Flue Dust: A Potential Source of Germanium
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Okanigbe, D.O., Popoola, A.P.I., Adeleke, A.A. (2017). Hydrometallurgical Processing of Copper Smelter Dust for Copper Recovery as Nano-particles: A Review. In: Zhang, L., et al. Energy Technology 2017. The Minerals, Metals & Materials Series. Springer, Cham. https://doi.org/10.1007/978-3-319-52192-3_21
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