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Carbon Based Coatings Deposited on Nitrided Stainless Steel: Study of Thermal Degradation

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Proceedings of the 3rd Pan American Materials Congress

Abstract

Amorphous hydrogenated carbon (DLC) coatings have a high hardness depending on the relative amount of sp3/sp2 bondings. They also exhibit an extremely low friction coefficient and are chemically inert. However, these coatings have some disadvantages which limit their applications. For instance, adhesion is poor when they are deposited on metallic substrates and they are also unstable at high temperatures, degrading into graphite and loosing hardness. In this work, DLC coatings were deposited on precipitation hardening stainless steel (PH Corrax) which was plasma nitrided before the coating deposition. The samples were submitted to annealing treatments for an hour at different temperatures from 200 to 600 °C, together with a control group, which was only coated but not nitrided. After each annealing cycle, Raman Spectroscopy, nanoindentation and microscopy were used to check film properties. It was demonstrated that the nitriding pre treatment improved not only adhesion but also the thermal stability of the DLC, slowing degradation and preventing delamination.

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References

  1. Li, H., Xu, T., Wang, C., Chen, J., Zhou, H., & Liu, H. (2006). Annealing effect on the structure, mechanical and tribological properties of hydrogenated diamond-like carbon films. Thin Solid Films, 515, 2153–2160.

    Article  Google Scholar 

  2. Zou, Y. S., Wu, Y. F., Huang, R. F., Sun, C., & Wen, L. S. (2009). Mechanical properties and thermal stability of nitrogen incorporated diamond-like carbon films. Vacuum, 83, 1406–1410.

    Article  Google Scholar 

  3. Zhang, S., Bui, X. L., & Li, X. (2006). Thermal stability and oxidation properties of magnetron sputtered diamond-like carbon and its nanocomposite coatings. Diamond and Related Materials, 15, 972–976.

    Article  Google Scholar 

  4. Choi, H. W., Gage, D. M., Dauskardt, R. H., Lee, K.-R., & Oh, K. H. (2009). Effects of thermal annealing and Si incorporation on bonding structure and fracture properties of diamond-like carbon films. Diamond and Related Materials, 18, 615–619.

    Article  Google Scholar 

  5. Er, K., & So, M. (2010). Thermal annealing behavior of Si-doped diamond like-carbon films deposited by reactive sputtering. Journal of Ceramic Processing Research, 11, 760–764.

    Google Scholar 

  6. Borges, C. F. M., Pfender, E., & Heberlein, J. (2001). Influence of nitrided and carbonitrided interlayers on enhanced nucleation of diamond on stainless steel 304. Diamond and Related Materials, 10, 1983–1990.

    Article  Google Scholar 

  7. Trava-Airoldi, V. J., Bonetti, L. F., Fernandes, J. A., Blando, E., Hübler, R., Radia, P. A., et al. (2007). DLC film properties obtained by a low cost and modified pulsed-DC discharge. Thin Solid Films, 516, 272–276.

    Article  Google Scholar 

  8. Choi, J., Soejima, K., Kato, T., Kawaguchi, M., & Lee, W. (2012). Nitriding of high speed steel by bipolar PBII for improvement in adhesion strength of DLC films. Nuclear Instruments and Methods in Physics Research, Section B: Beam Interactions with Materials and Atoms, 272, 357–360.

    Article  Google Scholar 

  9. Casiraghi, C., Ferrari, A. C., & Robertson, J. (2005). Raman spectroscopy of hydrogenated amorphous carbons. Physical Review B, 72, 1–13.

    Article  Google Scholar 

  10. Ferrari, A. C., & Robertson, J. (2000). Interpretation of Raman spectra of disordered and amorphous carbon. Physical Review B, 61, 14095–14107.

    Article  Google Scholar 

  11. Dalibon, E. L., Trava-Airoldi, V., Pereira, L. A., Cabo, A., & Brühl, S. P. (2014). Evaluation of the mechanical behaviour of a DLC film on plasma nitrided AISI 420 with different surface finishing. Surface and Coatings Technology, 255, 22–27.

    Article  Google Scholar 

  12. Li, X.-Y., Sun, Y., & Bell, T. (1999). Stability of nitrogen S-phase in austenitic stainless steel. Materials Research Advance, 90, 901–990.

    Google Scholar 

  13. Wei, Ch., & Yen, J.-Y. (2007). Effect of film thickness and interlayer on the adhesion strength of diamond like carbon films on different substrate. Diamond and Related Materials, 16, 1325–1330.

    Article  Google Scholar 

  14. Azzi, M., Amirault, P., Paquette, M., Klemberg-Sapieha, J. E., & Martinu, L. (2010). Corrosion performance and mechanical stability of 316L/DLC coating system: Role of interlayers. Surface and Coatings Technology, 204, 3986–3994.

    Article  Google Scholar 

  15. Chen, C. W., Huanga, C. C., Lina, Y. Y., Chen, L. C., & Chen, K. H. (2005). The affinity of Si–N and Si–C bonding in amorphous silicon carbon nitride (a-SiCN) thin film. Diamond and Related Materials, 14, 1126–1130.

    Article  Google Scholar 

  16. Tien, C. L., & Lin, T. W. (2012). Thermal expansion coefficient and thermomechanical properties of SiN(x) thin films prepared by plasma-enhanced chemical vapor deposition. Applied Optics, 51, 7229–7235.

    Article  Google Scholar 

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Acknowledgements

The authors would like to thank to research scholars of GIS group (UTN) for their help in preparing of samples and tests.

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Correspondence to Sonia P. Brühl .

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© 2017 The Minerals, Metals & Materials Society

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Dalibón, E.L., Ghafoor, N., Rogström, L., Trava-Airoldi, V.J., Odén, M., Brühl, S.P. (2017). Carbon Based Coatings Deposited on Nitrided Stainless Steel: Study of Thermal Degradation. In: Meyers, M., et al. Proceedings of the 3rd Pan American Materials Congress. The Minerals, Metals & Materials Series. Springer, Cham. https://doi.org/10.1007/978-3-319-52132-9_6

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