Abstract
Detailed low-temperature scanning tunneling microscope images of the Si(100)-2×1-H and the Ge(100)-2×1-H surfaces show a remarkable contrast inversion between filled- and empty-state images where the hydrogen dimer rows appear bright for filled-state images and dark for empty-state images. This contrast inversion originates from the change in the dominant surface states and their coupling to the tip apex and the bulk channels as a function of the bias voltage.
Sections 1, 3, and 5: Reprinted with minor editorial changes from Surface Science Letters, 632, Tiong Leh Yap, Hiroyo Kawai, Olga Neucheva, Andrew Thye Shen Wee, Cedric Troadec, Mark Saeys, and Christian Joachim, “Si(100)-2×1-H dimer rows contrast inversion in low-temperature scanning tunneling microscope images,” L13-L17, 2015, with permission from Elsevier.
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References
Joachim, C., Martrou, D., Rezeq, M., Troadec, C., Deng, J., Chandrasekhar, N., Gauthier, S.: Multiple atomic scale solid surface interconnects for atom circuits and molecule logic gates. J. Phys. Condens. Matter 22, 084025 (2010). doi:10.1088/0953-8984/22/8/084025
Fuechsle, M., Miwa, J.A., Mahapatra, S., Ryu, H., Lee, S., Warschkow, O., Hollenberg, L.C.L., Klimeck, G., Simmons, M.Y.: A single-atom transistor. Nat. Nanotechnol. 7, 242 (2012). doi:10.1038/nnano.2012.21
Piva, P.G., DiLabio, G.A., Pitters, J.L., Zikovsky, J., Rezeq, M., Dogel, S., Hofer, W.A., Wolkow, R.A.: Field regulation of single-molecule conductivity by a charged surface atom. Nature 435, 658 (2005). doi:10.1038/nature03563
Hersam, M.C., Guisinger, N.P., Lyding, J.W., Thompson, D.S., Moore, J.S.: Atomic-level study of the robustness of the Si(100)-2×1: H surface following exposure to ambient conditions. App. Phys. Lett. 78, 886 (2001). doi:10.1063/1.1348322
Boland, J.J.: Scanning tunneling microscopy of the interaction of hydrogen with silicon surfaces. Adv. Phys. 42, 129 (1993). doi:10.1080/00018739300101474
Bellec, A., Riedel, D., Dujardin, G., Boudrioua, O., Chaput, L., Stauffer, L., Sonnet, P.: Electronic properties of the n-doped hydrogenated silicon (100) surface and dehydrogenated structures at 5 K. Phys. Rev. B 80, 245434 (2009). doi:10.1103/PhysRevB.80.245434
Buehler, E.J., Boland, J.J.: Dimer preparation that mimics the transition state for the adsorption of H2 on the Si(100)-2×1 surface. Science 290, 506 (2000). doi:10.1126/science.290.5491.506
Bellec, A., Riedel, D., Dujardin, G., Rompotis, N., Kantorovich, L.N.: Dihydride dimer structures on the Si(100): H surface studied by low-temperature scanning tunneling microscopy. Phys. Rev. B 78, 165032 (2008). doi:10.1103/PhysRevB.78.165302
Labidi, H., Kantorovich, L., Riedel, D.: Atomic-scale control of hydrogen bonding on a bare Si(100)-2×1 surface. Phys. Rev. B 86, 165441 (2012). doi:10.1103/PhysRevB.86.165441
Kolmer, M., Godlewski, S., Kawai, H., Such, B., Krok, F., Saeys, M., Joachim, C., Szymonski, M.: Electronic properties of STM-constructed dangling-bond dimer lines on a Ge(001)-(2×1):H surface. Phys. Rev. B. 86, 215307 (2012). doi:10.1103/PhysRevB.86.125307
Haider, M.B., Pitters, J.L., DiLabio, G.A., Livadaru, L., Mutus, J.Y., Wolkow, R.A.: Controlled coupling and occupation of silicon atomic quantum dots at room temperature. Phys. Rev. Lett. 102, 046805 (2009). doi:10.1103/PhysRevLett.102.046805
Schofield, S.R., Studer, P., Hirjibehedin, C.F., Curson, N.J., Aeppli, G., Bowler, D.R.: Quantum engineering at the silicon surface using dangling bonds. Nat. Commun. 4, 1649 (2013). doi:10.1038/ncomms2679
Kawai, H., Ample, F., Wang, Q., Yeo, Y.K., Saeys, M., Joachim, C.: Dangling-bond logic gates on a Si(100)-(2×1)-H surface. J. Phys. Condens. Matter 24, 095011 (2012). doi:10.1088/0953-8984/24/9/095011
Ample, F., Duchemin, I., Hliwa, M., Joachim, C.: Single OR molecule and OR atomic circuit logic gates interconnected on a Si(100)H surface. J. Phys. Condens. Matter 23, 125303 (2011). doi:10.1088/0953-8984/23/12/125303
Neucheva, O.A., Thamankar, R.M., Yap, T.L., Troadec, C., Deng, J., Joachim, C.: Atomic scale interconnection machine. In: Joachim, C., (ed.) Atomic Scale Interconnection Machines, Advances in Atom and Single Molecule Machines, pp. 23–33. Springer, Heidelberg. doi:10.1007/978-3-642-28172-3_3 (2012)
Cerda, J., Hove, M.A.V., Sautet, P., Salmeron, M.: Efficient method for the simulation of STM images. I. Generalized green-function formalism. Phys. Rev. B 56, 15885 (1997). doi:10.1103/PhysRevB.56.15885
Kienle, D., Bevan, K.H., Liang, G.-C., Siddiqui, L., Cerda, J.I., Ghosh, A.W.: Extended Hückel Theory for band structure, chemistry, and transport II. Silicon. J. Appl. Phys. 100, 043715 (2006). doi:10.1063/1.2259820
Moussa, J.E., Schultz, P.A., Chelikowsky, J.R.: Analysis of the Heyd-Scuseria-Ernzerhof density functional parameter space. J. Chem. Phys. 136, 204117 (2012). doi:10.1063/1.4722993
Kolmer, M., Godlewski, S., Zuzak, R., Wojtaszek, M., Rauer, C., Thuaire, A., Hartmann, J.-M., Moriceau, H., Joachim, C., Szymonski, M.: Atomic scale fabrication of dangling bond structures on hydrogen passivated Si(001) wafers processed and nanopackaged in a clean room environment. Appl. Surf. Sci. 288, 83 (2014). doi:10.1016/j.apsusc.2013.09.124
Acknowledgements
We acknowledge the Agency of Science, Technology, and Research (A*STAR) for funding provided through the Visiting Investigatorship Programme Atom Technology project 1021100972, and through the AtMol integrated project contract number 270028 from the European Commission. We also acknowledge the A*STAR Computational Resource Centre (A*CRC) for computational resources and support. MK acknowledges financial support received from the Foundation for Polish Science (FNP).
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Kawai, H. et al. (2017). Si(100):H and Ge(100):H Dimer Rows Contrast Inversion in Low-temperature Scanning Tunneling Microscope Images. In: Kolmer, M., Joachim, C. (eds) On-Surface Atomic Wires and Logic Gates . Advances in Atom and Single Molecule Machines. Springer, Cham. https://doi.org/10.1007/978-3-319-51847-3_4
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