Abstract
This chapter reviews the technique of magnetic microrheology for the characterization of the viscosity of coatings. In magnetic microrheology, a liquid containing a dilute solution of micron-sized magnetic probe particles is placed in a magnetic field gradient and the motion of the probe particles is tracked with a microscope. The probe particle velocity found from image analysis is then used, along with the particle and system parameters, to find the local viscosity of the liquid. The application to coatings requires an apparatus designed for tracking particles in thin liquid coating layers. In the chapter, an overview of magnetic microrheology is provided, including the design of an apparatus for monitoring coating viscosity. Examples are provided for the use of the method to track viscosity as a function of time during drying and curing, and position through the thickness of the coatings. The chapter explores the application of the method to understand the effects of process variables on the viscosity development of a coating used in the manufacture of tissue paper.
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References
Bangert, C., Detiveaux, S.: The state of the global coatings industry. http://www.pfon-line.com/articles/the-state-of-the-global-coatings-industry (2014). Accessed 9 June 2016
Overdiep, W.S.: The levelling of paints. Prog. Org. Coat. 14(2), 159–175 (1986)
Wu, S.: Rheology of high solid coatings. I. Analysis of sagging and slumping. J. Appl. Polym. Sci. 22, 2769–2782 (1978)
Lade Jr., R.K., Song, J.-O., Musliner, A.D., Williams, B.A., Kumar, S., Macosko, C.W., Francis, L.F.: Sag in drying coatings: prediction and real time measurement with particle tracking. Prog. Org. Coat. 86, 49–58 (2015)
Waigh, T.A.: Microrheology of complex fluids. Rep. Prog. Phys. 68(3), 685–742 (2005)
Gardel, M.L., Valentine, M.T., Weitz, D.A.: Microrheology. In: Breuer (ed.) Microscale Diagnostic Techniques, pp. 1–49. Springer, Berlin (2005)
Cicuta, P., Donald, A.M.: Microrheology: a review of the method and applications. Soft Matter. 3(12), 1449–1455 (2007)
Squires, T.M., Mason, T.G.: Fluid mechanics of microrheology. Annu. Rev. Fluid Mech. 42, 413–438 (2010)
Komoda, Y., Leal, L.G., Squires, T.M.: Local, real-time measurement of drying films of aqueous polymer solutions using active microrheology. Langmuir. 30(18), 5230–5237 (2014)
Gu, Y., Kornev, K.G.: Ferromagnetic nanorods in applications to control of the in-plane anisotropy of composite films and for in situ characterization of the film rheology. Adv. Funct. Mater. 26(22), 3796–3808 (2016)
Bausch, A.R., Möller, W., Sackmann, E.: Measurement of local viscoelasticity and forces in living cells by magnetic tweezers. Biophys. J. 76(1), 573–579 (1999)
Yagi, K.: The mechanical and colloidal properties of amoeba protoplasm and their relations to the mechanism of amoeboid movement. Comp. Biochem. Physiol. 3(2), 73–91 (1961)
Ortega, F., Ritacco, H., Rubio, R.G.: Interfacial microrheology: particle tracking and related techniques. Curr. Opin. Colloid Interface Sci. 15(4), 237–245 (2010)
Shahin, G.T.: The stress deformation interfacial rheometer. Dissertation, University of Pennsylvania (1986)
Brooks, C.F., Fuller, G.G., Frank, C.W., Robertson, C.R.: An interfacial stress rheometer to study rheological transitions in monolayers at the air-water interface. Langmuir. 15(7), 2450–2459 (1999)
Ding, J., Warriner, H.E., Zasadzinski, J.A.: Magnetic needle viscometer for Langmuir monolayers. Langmuir. 18(7), 2800–2806 (2002)
Anguelouch, A., Leheny, R.L., Reich, D.H.: Application of ferromagnetic nanowires to interfacial microrheology. Appl. Phys. Lett. 89(11), 111914 (2006)
Lee, M.H., Lapointe, C.P., Reich, D.H., Stebe, K.J., Leheny, R.L.: Interfacial hydrodynamic drag on nanowires embedded in thin oil films and protein layers. Langmuir. 25(14), 7976–7982 (2009)
Dhar, P., Cao, Y., Fischer, T.M., Zasadzinski, J.A.: Active interfacial shear microrheology of aging protein films. Phys. Rev. Lett. 104(1), 016001 (2010)
Edwards, D.E., Brenner, H., Wasan, D.T.: Interfacial Transport Processes and Rheology, p. 134. Butterworth-Heinemann, Boston (1991)
Moschakis, T.: Microrheology and particle tracking in food gels and emulsions. Curr. Opin. Colloid Interface Sci. 18(4), 311–323 (2013)
Song, J.-O., Henry, R.M., Jacobs, R.M., Francis, L.F.: Magnetic microrhoemeter for in situ characterization of coating viscosity. Rev. Sci. Instrum. 81(9), 093903 (2010)
Thomas, R.H., Walters, K.: The unsteady motion of a sphere in an elastic-viscous liquid. Rheol. Acta. 5(1), 23–27 (1966)
Song, J.-O.: In situ characterization of dynamic structures of coatings. Dissertation, University of Minnesota Twin Cities (2012)
Svåsand, E., Skjeltorp, A.T., Akselvoll, J., Helgesen, G.: Local viscosity measurements using oscillating magnetic holes. J. Appl. Phys. 101(5), 054910 (2007)
Panton, R.L.: Incompressible Flow, pp. 609–611. Wiley, New Jersey (2005)
Ceylan, K., Herdem, S., Abbasov, T.: A theoretical model for estimating of drag force in the flow of non-Newtonian fluids around spherical solid particles. Powder Technol. 103(3), 286–291 (1999)
Chang, I.D.: On the wall effect correction of the stokes drag formula for axially symmetric bodies moving inside a cylindrical tube. Z. Angew. Math. Phys. 12(1), 6–14 (1961)
Berdan II, C., Leal, C.G.: Motion of a sphere in the presence of a deformable interface: I. Perturbation of the interface from flat: the effects on drag and torque. J. Colloid Interface Sci. 87(1), 62–80 (1982)
Cairncross, R.A., Francis, L.F., Scriven, L.E.: Predicting drying in coatings that react and gel: drying regime maps. AICHE J. 42(1), 55–67 (1996)
Basu, S.K., Scriven, L.E., Francis, L.F., McCormick, A.V.: Mechanism of wrinkle formation in curing coatings. Prog. Org. Coat. 53(1), 1–16 (2005)
Kim, J.C., Hillmyer, M.A., Francis, L.F.: Magnetic microrheology of block copolymer solutions. ACS Appl. Mater. Interfaces. 5(22), 11877–11883 (2013)
Song, J.-O., McCormick, A.V., Francis, L.F.: Depthwise viscosity gradients in UV-cured epoxy coatings. Macromol. Mater. Eng. 298(2), 145–152 (2013)
Biermann, C.J.: Handbook of Pulping and Paper Making, pp. 244–245. Academic Press, San Diego (1996)
Smook, G.A.: Handbook for Pulp and Paper Technologists, pp. 319–324. Angus Wild Publications, Inc., Vancouver (2003)
Allen, A.J., Lock, G.: Creping release agents. US Patent 5,660,687, 26 Aug 1997
Furman, G.S., Li, X.H., Su, W., Grigoriev, V.A.: Modifying agent for yankee coatings. US Patent 8,101,045 B2, 24 Jan 2012
Acknowledgments
The authors would like to thank the industrial supporters of the Coating Process Fundamentals Program (CPFP) of the Industrial Partnership for Research in Interfacial & Materials Engineering (IPRIME) at the University of Minnesota. Parts of this work were carried out in the Characterization Facility, University of Minnesota, which receives partial support from NSF through the MRSEC program.
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Castro, D.J., Song, JO., Lade, R.K., Francis, L.F. (2017). Magnetic Microrheology for Characterization of Viscosity in Coatings. In: Wen, M., Dušek, K. (eds) Protective Coatings. Springer, Cham. https://doi.org/10.1007/978-3-319-51627-1_5
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DOI: https://doi.org/10.1007/978-3-319-51627-1_5
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