Abstract
Iron mainly exists as the magnetite and fayalite, while copper is primarily dispersed in the form of fine matte particles in the copper slag , which is difficult to recover by conventional separation techniques. In this paper, the feasibility of an integrated technological route to improve beneficiation of copper and iron components from copper slag through the modification of molten slag was investigated, and the results shows that: the copper grade of rougher copper concentrate was increased from 6.43 to 11.04%, iron recovery from magnetic separation was increased significantly from 32.40 to 63.36%, and other evaluation indexes were changed slightly, in comparison with unmodified copper slag. Meanwhile, the grains of the target minerals in the modified slag grew considerably to a mean size >50 μm after slow cooling. Ultimately, the beneficiation efficiency of copper and iron was improved because of the ease with which the target minerals were liberated.
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References
B. Gorai, R. Jana, M. Premchand, Characteristics and utilization of copper slag—a review. Resour. Conserv. Recycl. 39, 299–313 (2003)
H. Shen, E. Forssberg, An overview of recovery of metals from slags. Waste Manag. 23, 933–949 (2003)
C. Shi, C. Meyer, A. Behnood, Utilization of copper slag in cement and concrete. Resour. Conserv. Recycl. 52, 1115–1120 (2008)
I. Alpa, H. Deveci, H. Sungun, Utilization of flotation wastes of copper slag as raw material in cement production. J. Hazard. Mater. 159, 390–395 (2008)
M.M. Antonijevica, M.D. Dimitrijevic, Z.O. Stevanovic, S.M. Serbula, G.D. Bogdanovic, Investigation of the possibility of copper recovery from the flotation tailings by acid leaching. J. Hazard. Mater. 158, 23–34 (2008)
H.S. Altundogan, F. Tumen, Metal recovery from copper converter slag by roasting with ferric sulphate. Hydrometallurgy 44, 261–267 (1997)
D. Urosevic, M. Dimitrijevic, Z. Jankovic, D. Antic, Recovery of copper from copper slag and copper slag floatation tailings by oxidative leaching. Physicochemical Probl. Mineral Process. 51, 71–82 (2015)
I. Muravyov, V. Fomchenko, V.A. Usoltsev, F.K. Vasilyev, Leaching of copper and zinc from copper converter slag flotation tailings using H2SO4 and biologically generated Fe2(SO4)3. Hydrometallurgy 2012(119), 40–46 (2009)
X.L. Zhou, D.Q. Zhu, J. Pan, T.J. Wu, Utilization of waste copper slag to produce directly reduced Iron for weathering resistant steel. Int. ISIJ. 55, 1347–1352 (2015)
J. Zheng, K. Xiao, The research on using dispersant agent to iron recovery in copper slag. Nonferrous Metals Sci. Eng. 6, 71–73 (2011) (in Chinese)
D. Durincka, F. Engströmb, S. Arnouta, J. Heulensa, P.T. Jonesa, B. Björkmanb, B. Blanpaina, P. Wollants, Hot stage processing of metallurgical slags. Resour. Conserv. Recycl. 52, 1121–1131 (2008)
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Guo, Zq., Zhu, Dq., Pan, J., Zhang, F. (2017). Improving Separation of Cu–Fe from Copper Slag by Modification of the Molten Slag. In: Hwang, JY., et al. 8th International Symposium on High-Temperature Metallurgical Processing. The Minerals, Metals & Materials Series. Springer, Cham. https://doi.org/10.1007/978-3-319-51340-9_27
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DOI: https://doi.org/10.1007/978-3-319-51340-9_27
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