Evaluation of High Temperature Refractory Corrosion by Liquid Al₂O₃–Fe₂O₃–MgO–SiO₂

Abstract

Corrosion mechanisms have been investigated between MgO refractory substrates and synthetic FeNi slags. The materials taken into consideration comprised a simple synthetically mixed slag with specific oxides of slags from a ferroalloy producer. The MgO refractory substrates with the slag specimens on it were heated in a hot stage microscope to two different characteristic temperatures, 1350 and 1650 °C. The experiments proceeded under a controlled gas atmosphere that simulates the relevant process conditions. The corrosion mechanisms of each system were determined by SEM analyses. The obtained results showed that slag corrosion is dominating with a pronounced partial dissolution of refractory. It was also observed that iron oxide present in the slag diffused into the coarse refractory grains forming the relative low melting magnesia wuestite. Finally, the comparison of these findings with those predicted by thermodynamic calculation (FactSage) indicated the corrosion mechanisms and draw implications for improving the refractory performance and lifetime.