Abstract
The shaping, chemical modification, and functionalization of cellulose are largely depended on the process of dissolution in an efficient solvent. Viscose process as the most important method for production of cellulose-regenerated materials was introduced. The dissolution of cellulose in several other most frequently used eco-friendly solvents was also discussed, including cellulose carbamate, N-methylmorpholine-N-oxide, aqueous alkali system, and ionic liquids. These processes provide efficient platforms for development of new regenerated materials and other products based on cellulose.
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References
Hermanutz F, Gähr F, Uerdingen E et al (2008) New developments in dissolving and processing of cellulose in ionic liquids. Macromol Symp 262:23–27
Klemm D, Heublein B, Fink H-P et al (2005) Cellulose: fascinating biopolymer and sustainable raw material. Angew Chem Int Ed 44:3358–3393
Cross CF, Bevan EJ, Beadle C (1894) US Patent 520770
Hill JW, Jacobson RA (1938) Method for manufacturing cellulose carbamate. US Patent 2134825
Fink H-P, Ganster J, Lehmann A (2014) Progress in cellulose shaping: 20 years industrial case studies at Fraunhofer IAP. Cellulose 21:31–51
Yin C, Shen X (2007) Synthesis of cellulose carbamate by supercritical CO2-assisted impregnation: structure and rheological properties. Eur Polym J 43:2111–2116
Guo Y, Zhou J, Song Y et al (2009) An efficient and environmentally friendly method for the synthesis of cellulose carbamate by microwave heating. Macromol Rapid Commun 30:1504–1508
Fu F, Zhou J, Zhou X et al (2014) Green method for the production of cellulose multifilament from cellulose carbamate on a pilot-scale. ACS Sustain Chem Eng 2:2363–2370
Fu F, Guo Y, Wang Y et al (2014) Structure and properties of the regenerated cellulose membranes prepared from cellulose carbamate in NaOH/ZnO aqueous solution. Cellulose 212:819–830
Fu F, Yang Q, Zhou J et al (2014) Structure and properties of regenerated cellulose filaments prepared from cellulose carbamate−NaOH/ZnO aqueous Solution. ACS Sustain Chem Eng 2:2604–2612
Graenacher C, Sallmann R (1936) Assisting agents for the textile industry. US patent 2060568 A
Johnson DL (1969) Compounds dissolved in cyclic amine oxides. US patent 3447939 A
Fink H-P, Weigel P, Purz H et al (2001) Structure formation of regenerated cellulose materials from NMMO-solutions. Prog Polym Sci 26:1473–1524
Rosenau T, Potthast A, Sixta H et al (2001) The chemistry of side reactions and byproduct formation in the system NMMO/cellulose (Lyocell process). Prog Polym Sci 26:1763–1837
Maia E, Peguy A, Perez S (1981) Cellulose organic solvents. I. the structures of anhydrous N-methylmorpholine N-oxide and N-methylmorpholine N-oxide monohydrate. Acta Cryst B37:1858–1862
Rosenau T, Potthast A, Adorjan I et al (2002) Cellulose solutions in N-methylmorpholine-N-oxide (NMMO)—degradation processes and stabilizers. Cellulose 9:283–291
Sobue H, Kiessig H, Hess K (1939) The system: cellulose-sodium hydroxide-water in relation to the temperature. Z Phys Chem B43:309–328
Kamide K, Okajima K, Matsui T et al (1984) Study on the solubility of cellulose in aqueous alkali solution by deuteration IR and 13C NMR. Polymer 16:857–866
Yamane C, Saito M, Okajima K (1996) Manufacture of new cellulosic fibers from a spinning bath of an aqueous solution of alkali—soluble cellulose and caustic soda. Part 1. Development of a method for industrial preparation of an aqueous solution of highly soluble cellulose and caustic soda. Sen’i Gakkaish
Isogai A, Atalla RH (1998) Dissolution of cellulose in aqueous solutions. Cellulose 5:309–319
Egal M, Budtova T, Navard P (2008) The dissolution of microcrystalline cellulose in sodium hydroxide-urea aqueous solutions. Cellulose 15:361–370
Zhou J, Zhang L (2000) The solubility of cellulose in NaOH/ urea aqueous solution. Polym J 10:866–870
Cai J, Zhang L (2005) Rapid dissolution of cellulose in LiOH/urea and NaOH/urea aqueous solutions. Macromol Biosci 5:539–548
Qi H, Chang C, Zhang L (2009) Properties and applications of biodegradable transparent and photoluminescent cellulose films prepared via a green process. Green Chem 11:177–184
Ruan D, Zhang L, Zhou J et al (2004) Structure and properties of novel fibers spun from cellulose in NaOH/thiourea aqueous solution. Macromol Biosci 4:1105–1112
Yan L, Gao Z (2008) Dissolving of cellulose in PEG/NaOH aqueous solution. Cellulose 15:789–796
Qi H, Yang Q, Zhang L et al (2011) The dissolution of cellulose in NaOH-based aqueous system by two-step process. Cellulose 18:237–245
Cai J, Zhang L, Liu S et al (2008) Dynamic self-assembly induced rapid dissolution of cellulose at low temperatures. Macromolecules 41:9345–9351
Cai J, Zhang L, Zhou J et al (2007) Multifilament fibers based on dissolution of cellulose in NaOH/urea aqueous solution: structure and properties. Adv Mater 19:821–825
Zhu S, Wu Y, Chen Q et al (2006) Dissolution of cellulose with ionic liquids and its application: a mini-review. Green Chem 8:325–327
Bentivoglio G, Röder T, Fasching M et al (2006) Cellulose processing with chloride-based ionic liquids. Lenzinger Ber 86:154–161
Swatloski RP, Spear SK, Holbrey JD et al (2002) Dissolution of cellulose with ionic liquids. J Am Chem Soc 124:4974–4975
Gericke M, Fardim P, Heinze T (2012) Ionic liquids—promising but challenging solvents for homogeneous derivatization of cellulose. Molecules 17:7458–7502
Pinkert A, Marsh KN, Pang S et al (2009) Ionic liquids and their interaction with cellulose. Chem Rev 109:6712–6728
Feng L, Chen Z (2008) Research progress on dissolution and functional modification of cellulose in ionic liquids. J Mol Liq 142:1–5
King AWT, Asikkala J, Mutikainen I et al (2011) Distillable acid–base conjugate ionic liquids for cellulose dissolution and processing. Angew Chem Int Ed 50:6301–6305
Abe M, Fukaya Y, Ohno H (2012) Fast and facile dissolution of cellulose with tetrabutylphosphonium hydroxide containing 40 wt% water. Chem Commun 48:1808–1810
Kosan B, Michels C, Meister F (2008) Dissolution and forming of cellulose with ionic liquids. Cellulose 15:59–66
Heinze T, Schwikal K, Barthel S (2005) Ionic liquids as reaction medium in cellulose functionalization. Macromol Biosci 5:520–525
Sun N, Rahman M, Qin Y et al (2009) Complete dissolution and partial delignification of wood in the ionic liquid 1-ethyl-3-methylimidazolium acetate. Green Chem 11:646–655
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Qi, H. (2017). Platforms for Functionalization of Cellulose. In: Novel Functional Materials Based on Cellulose. SpringerBriefs in Applied Sciences and Technology. Springer, Cham. https://doi.org/10.1007/978-3-319-49592-7_2
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DOI: https://doi.org/10.1007/978-3-319-49592-7_2
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