Abstract
Stringent regulations on carbon dioxide (CO2) emissions from industrial sources (in general) and petroleum refineries (in particular) are being enforced world wide. Low-sulfur clean fuels enhance the demand for petroleum refinery utility gases (e. g., hydrogen, H2), which in turn leads to an increase in carbon-emission-intensive processes. This will ultimately force refineries to start implementing CO2 mitigation measures, which are increasingly evident in the strategies of industrial countries. In this work, we describe the major processes that contribute to a typical petroleum refinery's global CO2 emissions. Typical sources include unit utilities (i. e., heaters, boilers, and furnaces), fluid catalytic cracking units, hydrogen production (HP) units, flaring, and acid gas removal. A case study for a mega refinery structure is also given detailing a methodology for estimating CO2 emissions from various processes. The carbon footprint and specific emissions of various sources being considered are also reported.
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C. Patel, P. Lettieri, S.J.R. Simons, A. Germanà: Techno-economic performance analysis of energy production from biomass at different scales in the UK, Chem. Eng. J. 171, 986–996 (2011)
A. Thernesz, G. Szalmas, P. Dinka, T. Simon: CO2 capture-new challenge in refinery industry, MOL Scientific Mag. (Challenges) 3, 12–24 (2008)
J. van Straelen, F. Geuzebroek, N. Goodchild, G. Protopapas, L. Mahoney: CO2 capture for refineries, a practical approach, Int. J. Greenh. Gas Contr. 4, 316–320 (2010)
IEA: Prospects for CO2 capture and storage. Energy technology analysis (International Energy Agency and Organization for Economic Co-operation and Development 2004)
A. Samanta, A. Zhao, G.K.H. Shimizu, P. Sarkar, R. Gupta: Post-combustion CO2 capture using solid sorbents: A review, Ind. Eng. Chem. Res. 51, 1438–1463 (2010)
F. Dong, H. Lou, M. Goto, T. Hirose: The petlyuk PSA process for separation of ternary gas mixtures: Exemplification by separating a mixture of CO2-CH4-N2, Sep. Purif. Technol. 15, 31–40 (1990)
E.S. Kikkindes, R.T. Yang: Concentration and recovery of CO2 from flue gas by pressure swing adsorption, Ind. Eng. Chem. Res. 32, 2714–2720 (1993)
R.V. Sirwardance, M.S. Shen, E.P. Fisher, J.A. Poston: Adsorption of CO2 on molecular sieves and activated carbon, Energy Fuels 15, 279–284 (2001)
D.D. Do, K. Wang: A new model for the description of adsorption kinetics in heterogeneous activated carbon, Carbon 36, 1539–1554 (1998)
M. Andrei, M. De Simoni, A. Delbianco, P. Cazzani, L. Zanibelli: Enhanced oil recovery with CO2 capture and sequestration. In: Proc. 21st World Energ. Congr., Montréal (2010)
H. Al-Muslim, I. Dincer: Thermodynamic analysis of crude oil distillation systems, Int. J. Energ. Res. 29, 637–655 (2005)
D. Bonaquist: Analysis of CO 2 Emissions, Reductions and Capture for Large Scale Hydrogen Production Plants (Prazair, Daubury 2010)
MathPro Inc.: An introduction to petroleum refining and the production of ultralow sulfur gasoline and diesel fuel, theicct.org (2011) Report prepared for the International Council on Clean Transportation (ICCT)
I. Staffell: The Energy and Fuel Data Sheet (Univ. Birmingham 2011) http://www.academia.edu/1073990/The_Energy_and_Fuel_Data_Sheet
Hydrocarbon Publishing Company: Refinery CO 2 Management Strategies (Hydrocarbon, Frazer 2010)
M.A. Fahim, T.A. Al-Sahaf, A.S. Elkilani: Fundamentals of Petroleum Refining (Elsevier, Amsterdam 2010)
EIA: US Energy Information Agency Annex 4: IPCC Reference Approach for Estimating CO 2 Emissions from Fossil Fuel Combustion (EIA, Washington 2011)
EIA: US Energy Information Agency, Appendix N. Emission Factors for Steam and Chilled/Hot Water (EIA, Washington 2013)
EIA: US Energy Information Agency, http://www.eia.gov/todayinenergy/detail.cfm?id=9130 (EIA, Washington 2014)
J.H. Gary, G.E. Handwerk: Petroleum Refining: Technology and Economics, 3rd edn. (Marcel Dekker, New York 1994)
J. McKetta Jr.: Petroleum Processing Handbook, 1st edn. (Marcel Decker, New York 1992)
G. Collodi, F. Wheeler: Hydrogen production via steam reforming with CO2 capture, Chem. Eng. Trans. 19, 37–42 (2010)
L.M. Wolschlag, K.A. Couch, F.X. Zhu, J. Alves: UOP FCC Design Advancements to Reduce Energy Consumption and CO 2 Emissions (UOP LLC, Des Plaines 2009)
K. Nillson, L. Zetterberg, M. Ahman: Allowance Allocation and CO 2 Intensity of the EU15 and Norwegian Refineries (IVL Swedish Environmental Research Institute, Stockholm 2005)
I. Moore: Reducing CO2 emissions, Pet. Technol. Q. Q2, 1–6 (2005)
C.C. Wear: The concept of delta coke, Catalagram 106, 3–9 (2009)
U.T. Turaga, R. Ramanathan: Catalytic naphtha reforming: Revisiting its importance in the modern refinery, J. Scientific Ind. Res. 62, 963–978 (2003)
J.G. Speight: Gas Processing: Environmental Aspects and Methods (Butterworth Heinemann, Oxford 1993)
S. Mokhatab, W.A. Poe, J.G. Speight: Handbook of Natural Gas Transmission and Processing (Elsevier, Amsterdam 2006) pp. 261–294
B. Jiang, X. Wang, M.L. Gray, Y. Duan, D. Luebke, B. Li: Development of amino acid and amino acid-complex based solid sorbents for CO2 capture, Appl. Energ. 109, 112–118 (2013)
C. Wein, G. Puxty, P. Feron: Amino acid salts for CO2 capture at flue gas temperatures, Chem. Eng. Sci. 107, 218–226 (2014)
H. Mounzer: Reducing CO2 emissions from refineries through amine chemistry upgrade. In: Proc. 3rd Kuwait Chem. Conf., Kuwait City (2014)
M. Stockle, T. Bullen: Integrating refinery CO2 reduction strategies into your refinery. In: Proc. 31st ERTC Sustainable Refining Conf., Brussels (2008)
J. van Straelen, F. Geuzebroek, N. Goodchild, G. Protopapas, L. Mahoney: CO2 capture for refineries: A practical approach, Energ. Procedia 1, 179–185 (2009)
US EPA: Available and Merging Technologies for Reducing Greenhouse gas Emissions from the Petroleum Refining Industry (Office of air and radiation, Research Triangle Park 2010)
Ecofys: Methodology for the free allocation of emission allowances in the EU: ETS post 2012 (Sector report for the refinery industry 2009)
J. Martin, J. Lumbreras, M.E. Rodríguez: Testing flare emission factors for flaring in refineries, http://www.epa.gov/ttnchie1/conference/ei12/poster/martin.pdf (2014)
Code of Federal Regulations: Calculating GHG emissions. Title 40, CFR 98.253, http://www.law.cornell.edu/cfr/text/40/98.233
I. Al-Hajri: Integration of Hydrogen and CO 2 Management Within Refinery Planning, Ph.D. Thesis (Chemical Engineering Department, Univ. Waterloo, Waterloo 2008)
A. Szklo, R. Schaeffer: Fuel specification, energy consumption and CO2 emission in oil refineries, Energy 32, 1075–1092 (2007)
M. Petrick, J. Pellegrino: The Potential for Reducing Energy Consumption in the Refining Industry, Report No. ANL/ESD/TM-158 (Argonne National Laboratory, Lemont 1999)
Liberty Gases: CO2 fact sheet, http://www.libertygases.com/carbon-dioxide.html (2011)
IPIECA: Oil and gas industry guidance on voluntary sustainability reporting. Appendix D: Measurements units and conversion factors, 2014, http://www.ipieca.org/system/files/uploads/IPIECA_Reporting_Guidance_Measurement_units.pdf (London, 2014)
D. Johansson, P. Franck, T. Berntsson: CO2 capture in oil refineries: Assessment of the capture avoidance costs associated with different heat supply options in a future energy market, Energ. Convers. Manag. 66, 127–142 (2013)
D. Johansson, P. Franck, K. Pettersson, T. Berntsson: Comparative study of Fischer–Tropsch production and post-combustion CO2 capture at an oil refinery: Economic evaluation and GHG (greenhouse gas emissions) balances, Energy 59, 387–401 (2013)
D. Johansson, J. Rootze, T. Berntsson, F. Johnsson: Assessment of strategies for CO2 abatement in the European petroleum refining industry, Energy 42, 375–386 (2012)
S.M. Al-Salem: Carbon dioxide (CO2) emission sources in Kuwait from the downstream industry: Critical analysis with a current and futuristic view, Energy 81, 575–587 (2015)
Acknowledgements
The authors are grateful to the Kuwait Institute for Scientific Research (KISR) for funding project PF060K. The contribution from Dr. A.R. Khan of KISR (ELSRC) is gratefully appreciated. Parts of this chapter were previously published in Al-Salem [32.47].
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Al-Salem, S.M., Ma, X., Al-Mujaibel, M.M. (2017). Carbon Dioxide Mitigation. In: Hsu, C.S., Robinson, P.R. (eds) Springer Handbook of Petroleum Technology. Springer Handbooks. Springer, Cham. https://doi.org/10.1007/978-3-319-49347-3_32
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DOI: https://doi.org/10.1007/978-3-319-49347-3_32
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