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Thermodynamic Analysis of Lead-Fluoride Ion-Water System

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REWAS 2013

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Abstract

Based on thermodynamic data, this paper analyzed the feasibility of removing fluoride in the waste acid solution using lead ions. Lead-fluoride ion-water system E-log[F-] diagram and the solubility curve of lead fluoride at 25°C were drawn. It was found that insoluble PbF2 only exists stably in a certain concentration range of fluoride ion. With the increase of lead ion concentration, the stable area for solid lead fluoride expands and the total fluoride ion concentration decreases. Therefore, it is possible to remove fluoride ion in the waste acid solution lead ion.

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Author information

Authors and Affiliations

  1. School of Metallurgical Science and Engineering, Central South University, Changsha, 410083, China

    Jiayuan Li, Tianzu Yang, Lin Chen & Weifeng Liu

  2. Department of Chemical Engineering and Life Science, Xiangnan University, Chenzhou, 423000, China

    Jiayuan Li

Authors
  1. Jiayuan Li
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  2. Tianzu Yang
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  3. Lin Chen
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  4. Weifeng Liu
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Editor information

Editors and Affiliations

  1. SINTEF, Trondheim, Norway

    Anne Kvithyld (a senior research scientist) (a senior research scientist)

  2. Umicore Precious Metals Refining, Hoboken, Belgium

    Christina Meskers (leads the business development and marketing team) (leads the business development and marketing team)

  3. Energy Systems Division, Argonne National Laboratory, USA

    Gregory Krumdick (principal systems engineer) (principal systems engineer)

  4. Kroll Institute for Extractive Metallurgy in Metallurgical & Materials Engineering, Colorado School of Mines, USA

    Brajendra Mishra (professor and the Assoc. Director) (professor and the Assoc. Director)

  5. Outotec Finland, Finland

    Markus Reuter (Director of Technology Management, Adjunct Professor, Professorial Fellow, Guest Professor, a professor) (Director of Technology Management, Adjunct Professor, Professorial Fellow, Guest Professor, a professor)

  6. Aalto University, Finland

    Markus Reuter (Director of Technology Management, Adjunct Professor, Professorial Fellow, Guest Professor, a professor) (Director of Technology Management, Adjunct Professor, Professorial Fellow, Guest Professor, a professor)

  7. University of Melbourne, Australia

    Markus Reuter (Director of Technology Management, Adjunct Professor, Professorial Fellow, Guest Professor, a professor) (Director of Technology Management, Adjunct Professor, Professorial Fellow, Guest Professor, a professor)

  8. Central South University Changsha, China

    Markus Reuter (Director of Technology Management, Adjunct Professor, Professorial Fellow, Guest Professor, a professor) (Director of Technology Management, Adjunct Professor, Professorial Fellow, Guest Professor, a professor)

  9. TU Delft, Netherlands

    Markus Reuter (Director of Technology Management, Adjunct Professor, Professorial Fellow, Guest Professor, a professor) (Director of Technology Management, Adjunct Professor, Professorial Fellow, Guest Professor, a professor)

  10. University of Stellenbosch, South Africa

    Markus Reuter (Director of Technology Management, Adjunct Professor, Professorial Fellow, Guest Professor, a professor) (Director of Technology Management, Adjunct Professor, Professorial Fellow, Guest Professor, a professor)

  11. Saint-Gobain Innovative Materials R&D, Belgium

    Cong Wang (Senior Research Engineer) (Senior Research Engineer)

  12. Missouri University of Science and Technology, USA

    Mark Schlesinger (Professor of Metallurgical Engineering) (Professor of Metallurgical Engineering)

  13. Golisano Institute for Sustainability, USA

    Gabrielle Gaustad Ph.D. (Assistant Professor) (Assistant Professor)

  14. Rochester Institute of Technology, USA

    Gabrielle Gaustad Ph.D. (Assistant Professor) (Assistant Professor)

  15. Worcester Polytechnic Institute (WPI), USA

    Diana Lados (Associate Professor, Founding Director) (Associate Professor, Founding Director)

  16. Integrative Materials Design Center (iMdc), USA

    Diana Lados (Associate Professor, Founding Director) (Associate Professor, Founding Director)

  17. Argonne National Laboratory, USA

    Jeffrey Spangenberger (Engineering Specialist, Senior) (Engineering Specialist, Senior)

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© 2013 TMS (The Minerals, Metals & Materials Society)

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Li, J., Yang, T., Chen, L., Liu, W. (2013). Thermodynamic Analysis of Lead-Fluoride Ion-Water System. In: Kvithyld, A., et al. REWAS 2013. Springer, Cham. https://doi.org/10.1007/978-3-319-48763-2_18

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