Skip to main content

Abstract

Alloy 600, a nickel base alloy containing 15 % chromium, is used in the primary circuit of Pressurized Water Reactor (PWR). This alloy is well-known to be susceptible to Stress Corrosion Cracking (SCC) in PWR primary water. Despite the fact that many laboratory studies have been performed and that many models are proposed in the literature, the mechanisms involved are still not well-known. In some models, the transport of species (oxygen, hydrogen and chromium) has a key role. Therefore, experiments and calculations have been performed to study the transport of chromium, hydrogen and oxygen in Alloy 600 and in model microstructures. The results lead to the conclusion that the transport of oxygen and hydrogen cannot be considered as the rate-controlling steps. The asymmetric aspect of the crack tip and of the chromium depletion ahead of the crack lead to the conclusion that chromium diffusion could play a significant role in the mechanism.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 319.00
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

Similar content being viewed by others

References

  1. F. P. Ford, “Quantitative prediction of environmentally assisted cracking”, Corrosion Science, 52, pp. 375–395, 1996

    Article  Google Scholar 

  2. P. Scott, An overview of internal oxidation as a possible explanation of intergranular SCC of Alloy 600 in PWRs”, Proceedings of the 9th international symposium on environmental degradation of materials in nuclear power systems water reactors, Newport Beach, 1999

    Google Scholar 

  3. Th. Magnin, F. Foct, O. de Bouvier, “Hydrogen effects on PWR SCC mechanisms in monocristalline Alloy 600”, Proceedings of the 9th International Symposium on environmental degradation of materials in nuclear power systems water reactors, Newport Beach, 1999

    Google Scholar 

  4. H. K. Birnbaum, P. Sofronis, “Hydrogen enhanced localized plasticity — a mechanism for hydrogen related fracture”, Material Science and Engineering A, 176, pp. 191–202, 1994

    Article  Google Scholar 

  5. J. Chêne, C. Guerre, F. Jambon, P. Laghoutaris, L. Marchetti, G. Odemer, “Hydrogen-assisted intergranular cracking of nickel base alloys. Consequences on the stress corrosion cracking in PWR primary water”, 2008 International Hydrogen Conference, Effects of Hydrogen on Materials, September 7–10, 2008, Jackson Lake Lodge, Moran, Wyoming, USA

    Google Scholar 

  6. P. Laghoutaris, C. Guerre, J. Chene, R. Molins, F. Vaillant, I. De Curieres, “Contribution to model stress corrosion cracking of Alloy 600 in PWR primary water”, Workshop on Detection, Avoidance, Mechanisms, Modeling, and Prediction of SCC Initiation in Water-Cooled Nuclear Reactor Plants, 07/09/2008 — 12/09/2008, Beaune, France

    Google Scholar 

  7. P. Laghoutaris, Thesis, Ecole des Mines de Paris (2009)

    Google Scholar 

  8. M. Sennour, P. Laghoutaris, C. Guerre, R. Molins, “Advanced TEM characterization of stress corrosion cracking of Alloy 600 in pressurized water reactor primary water environment”, Journal of Nuclear Materials 393 (2009) 254–266

    Article  Google Scholar 

  9. J. Panter, Thesis, INP Toulouse (2002)

    Google Scholar 

  10. F. Delabrouille, Thesis, INP Toulouse (2005).

    Google Scholar 

  11. S. M. Payne, P. Mc Intyre, “Influence of grain boundary microstructure on susceptibility of Alloy 600 to intergranular attack and stress corrosion cracking”, NACE 1987, Corrosion vol. 44 No. 5, May (1988).

    Google Scholar 

  12. S. C. Tsai, A. M. Huntz and C. Dolin, “Growth mechanism of Cr2O3 scales: oxygen and chromium diffusion, oxidation kinetics and effect of yttrium”, Materials science and engineering, A212, p. 6–13, 1996.

    Article  Google Scholar 

  13. A. M. Huntz , S. C. Tsaï, J. Balmain, K. Messaoudi, B. Lesage and C. Dolin, “Atomic transport in Cr2O3 and Al2O3 scales: growth mechanism and effect of yttrium”, Materials science Forum, 251–254, p. 313–324, 1997.

    Article  Google Scholar 

  14. L. Marchetti-Sillans, Thesis, ENSMSE (2007)

    Google Scholar 

  15. P. Laghoutaris, C. Guerre, J. Chêne, C. Duhamel and R. Molins, Contribution to a model for stress corrosion cracking of Alloy 600 in PWR primary water, in: Eurocorr 2009, Nice, France, 2009

    Google Scholar 

  16. D.D. Pruthi, M.S. Anand, R.P. Agarwala, Diffusion of chromium in Inconel 600, Journal of nuclear materials, 64 (1976) p. 206–210

    Article  Google Scholar 

  17. B. Chetroiu, C. Guerre, F. Miserque, C. Duhamel, J. Crépin, L. Marchetti, P. Laghoutaris and J. Chêne, « Mécanismes de la corrosion sous contrainte de l’Alliage 600 en milieu primaire REP: mise au point de dépôt du chrome », (Paper presented at Journées jeunes chercheurs 2011, Commission « Corrosion-sous-contrainte-Fatigue-Corrosion, CEFRACOR, 11–12 July 2011, Lyon, France)

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Editor information

Editors and Affiliations

Rights and permissions

Reprints and permissions

Copyright information

© 2011 TMS (The Minerals, Metals & Materials Society)

About this paper

Cite this paper

Guerre, C. et al. (2011). Stress Corrosion Cracking of Alloy 600 in PWR Primary Water : Influence of Chromium, Hydrogen and oxygen Diffusion. In: Busby, J.T., Ilevbare, G., Andresen, P.L. (eds) Proceedings of the 15th International Conference on Environmental Degradation of Materials in Nuclear Power Systems — Water Reactors. Springer, Cham. https://doi.org/10.1007/978-3-319-48760-1_91

Download citation

Publish with us

Policies and ethics