Abstract
Boiling water nuclear reactors (BWRs) throughout the world have applied the NobleChem™ (or noble metal chemical addition: NMCA) or Online NMCA (OLNC) process just before end-of-cycle shutdown or during an operation to mitigate the stress corrosion cracking (SCC) of structural materials in BWRs. When injected into BWR environments, the noble metal particles deposit on Type 304 stainless steel surfaces and reduce the corrosion potential, which decreases the propensity for SCC. Very fine noble metal particles are formed and able to potentially deposit inside a crack and maintain catalytic surfaces in the critical regions inside the crack. However, the current NMCA or OLNC process also introduces the unnecessary ionic species to the reactor water.
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P.L. Andresen, F.P. Ford, S.M. Murphy, J.M. Perks, “State of Knowledge of Radiation Effects on Environmental Cracking in Light Water Reactor Core Materials”, Proc. 4th Int. Symp. on Environmental Degradation of Materials in Nuclear Power Systems – Water Reactors, NACE, pp. 1–83 to 1–121, 1990.
S. Hettiarachchi, G.P. Wozadlo, P.L. Andresen, T.P. Diaz, R.L. Cowan, Proc. 7th Int Symp. On Env. Degradation of Materials in Nuclear Power Systems-Water Reactors, NACE International, August 7–10, Breckenridge, Colorado, 1995.
Y.J. Kim, L.W. Niedrach, M.E. Indig, P.L. Andresen, J. of Metals, Vol 44, No.2, p. 14–18, 1992.
S. Hettiarachchi, G.P. Wozadlo and T.P. Diaz, Paper#95413, Corrosion/1995, NACE.
P.L. Andresen, Y.J. Kim, S. Hetiarachchi, & T. Diaz, “OnLine NobleChem Mitigation of SCC”, Proc. 13th Int. Symposium on Environmental Degradation of Materials in Nuclear Power Systems-Water Reactors, Snowbird, UT, TMS, 2005
S. Hettiarachchi, R. Horn, P. Andresen, & Y-J Kim, “ECP Reduction and Crack Mitigation Experiences with NobleChem and On-Line NobleChem,” Proc. 14th Int. Symp. on Environmental Degradation of Materials in Nuclear Power System-Water Reactors, ANS (LaGrange Park, IL), 2009.
S. Hettiarachchi, T. Diaz, P.L. Andresen, Y.J. Kim, “On-Line Mitigation of Growing Cracks ----- Beyond NobleChem”, Proc. of International Conference on Water Chemistry of Nuclear Reactor Systems”, Session 3: Oct. 11–14, 2004, EPRI, San Francisco, CA.
L.W. Niedrach, “A New Membrane Type pH Sensor for Use in High Temperature High Pressure Water”, J Electrochem. Soc. 127, 2122 (1980).
Y. Hayashi, T. Sekino and K. Niihara, “New Phenomena and Application by Combination of Metal Oxide and Ultrasound”, Transactions of the Materials Research Society of Japan, 27, [1], 2002, 121–124.
Y. Hayashi, A. Okaho, T. Sekino and K. Niihara, “Synthesis of Nano-Sized Metal Particles by a Liquid-Solid Sonochemical System”, The Sixth International Conference on Nanostuctured Materials (NANO 2002), Orlando, FL, June 16–21, 2002.
Y. Mizukoshi, K. Okitsu, Y. Maeda, T. Yamamoto, R. Oshima and Y. Nagata, “Sonochemcial Preparation of Bimetallic Nanoparticles of Gold/Palladium in Aqueous Solution”, The Journal of Physical Chemistry B, vol. 101, no. 36 (1997) 7033–7037.
K. Okitsu, Y. Mizukoshi, H. Bandow, Y. Maeda, T. Yamamoto and Y. Nagata, “Formation of Noble Metal Particles by Ultrasonic Irradiation”, Ultrasonics Sonochemistry, 3 (1996) S249–S251.
K. Okitsu, H. Bandow and Y. Maeda, “Sonochemical Preparation of Ultrafine Palladium Particles”, Chem. Mater., 8 (1996) 315–317.
S.E. Pratsinis, “Flame Aerosol Technology for Nanoparticles: Catalysts, Non-Agglomerates and Scale-Up”, Nanoparticles 2003, Business Communications, Boston, MA, October 27–28, 2003.
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© 2011 TMS (The Minerals, Metals & Materials Society)
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Kim, YJ., Andresen, P.L., Hettiarachchi, S. (2011). Use of Noble Metal Nanopartice for SCC Mitigation in BWRs. In: Busby, J.T., Ilevbare, G., Andresen, P.L. (eds) Proceedings of the 15th International Conference on Environmental Degradation of Materials in Nuclear Power Systems — Water Reactors. Springer, Cham. https://doi.org/10.1007/978-3-319-48760-1_119
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DOI: https://doi.org/10.1007/978-3-319-48760-1_119
Publisher Name: Springer, Cham
Online ISBN: 978-3-319-48760-1
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