Skip to main content

Effect of MMT Nanoparticle Clay on Flexural Properties of Polymer Based BisGMA/Tegdma Resin

  • Conference paper
TMS 2016 145th Annual Meeting & Exhibition

Abstract

The objective of this study is to evaluate the (strength and modulus) and degree of conversion of dimethacrylate resin containing different amounts of Montomorillonite (MMT) Cloisite 20A nanoclay as filler. Eight formulations of polymer based BisGMA/TEGDMA (four with MMT and another four with barium glass (BG) as filler) at concentration of 20, 30, 40 and 50% by weight were studied. As control, a series of composites containing BG particles were also tested. The flexural strength data was analyzed using Kruskal-Wallis and Tukey’s tests. The addition of MMT nanoparticles in a BisGMA / TEGDMA resin matrix resulted in similar degree of conversion and higher elastic modulus values compared to the groups filled with BG. The decrease in the resistance value with increasing concentration of MMT may be due to the formation of agglomerates (clusters) that decreases the reinforcement efficiency.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 239.00
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
Hardcover Book
USD 219.99
Price excludes VAT (USA)
  • Durable hardcover edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. Min SH, Ferracane JL, Lee IB. “Effect of shrinkage strain, modulus, and instrument compliance on polymerization shrinkage stress of light-cured composites during the initial curing stage”. Dental Materials, 26 (2010), 1024–1033.

    Article  Google Scholar 

  2. Davidson CL, Davidson-Kaban SS., “Handling of mechanical stresses in composite restorations”. Dental Update, 25 (1998), 274–279.

    Google Scholar 

  3. Ferracane JL. “Developing a more complete understanding of stress produced in dental composites during polymerization”. Dental Materials, 21 (2005), 36–42.

    Article  Google Scholar 

  4. Mucci V, Pérez J, Vallo CI. (2010), “Preparation and characterization of light-cured methacrylate/ montmorillonite nanocomposites”. Polym Intern., 60, 247–254.

    Article  Google Scholar 

  5. Gonçalvez F, Azevedo CLN, Ferracane JL, Braga R.R. “BisGMA/TEGDMA ratio and filler content effects on shrinkage stress”. Dental Materials, 27 (2010), 520–526.

    Article  Google Scholar 

  6. Fournaris KG, Boukos N, Petridis D. “Aqueous polymerization of protonated 4-vinylpyridine in montimorillonite”. Appled Clay Science, 19 (2001),77–88.

    Article  Google Scholar 

  7. Alexandre M, Dubois P. “Polymer-layered silicate nanocomposites: preparation, properties and uses of a new class of materials. Materials Science and Engineering, 28 (2000), 61–63.

    Google Scholar 

  8. Discacciati JAC, Oréfice RL. “Structural analysis on photopolymerized dental resins containing nanocomponents”. Journal of Materials Science, 42 (2007), 3883–3893.

    Article  Google Scholar 

  9. Campos LMP, Lugão AB, Vasconcelos MR, Parra DF. “Polymerization Shrinkage Evaluation on Nanoscale-Layered Silicates: BisGMA/TEGMA Nanocomposites, in Photo-Activated Polymeric Matrices”. Journal of Applied Polymer Science, 131 (2014), 413–418.

    Google Scholar 

  10. Liu L, Qi Z, Zhu X. Studies on nylon-6-nanoclay nanocomposites by melt intercalation process. J Appl Polym Sci,1999; 71: 1133–1138.

    Article  Google Scholar 

  11. Salahudin N, Shehata M. (2001), “Polymethylmethacrilate-montmorillonite composites: preparation, characterization and properties”. Polymer., 42, 8379–8385.

    Article  Google Scholar 

  12. Discacciati JAC, Neves AD, Oréfice RL, Pimenta FJGS, Sander HH. “Effect of ligth intensy and irradiation time on the polymerization process of a dental composite resin”. Materials Research, 2, (2004), 313–318.

    Article  Google Scholar 

  13. Boaro LC, Gonçalves F, Guimarães TC, Ferracane JL, Pfeifer CS, Braga RR. “Sorption, solubility, shrinkage and mechanical properties of “low-shrinkage” commercial resin composites”. Dental Materials, 29, (2013), 398–404.

    Article  Google Scholar 

  14. Campbell PM, Johnston WN, O’brien WJ. “Light scattering gloss of an experimental quartz-filled composite”. Journal of Dental Research, 65 (1986), 892–894.

    Article  Google Scholar 

  15. Gonçalves F, Boaro LC, Ferracane JL,Braga RR. A comparative evaluation of polymerization stress data obtained with four different mechanical testing systems. Dental Materials, 28 (2012), 680–686.

    Article  Google Scholar 

  16. Massouras K, Silikas N, Watts DC. Correlation of filler content and elastics properties of resin-composites. Dental Materials, 24 (2008), 932–939.

    Article  Google Scholar 

  17. Hussain F, Chen J, Hojjati M. Epoxy-silicate nanocomposites: cure monitoring and characterization. Materials Science and Engineering, (2007), 467–476.

    Google Scholar 

  18. Fournaris K G, Boukos N, Petridis D. Aqueous polymerization of protonated 4-vinylpyridine in montimorillonite. Applied Clay Science,19 (2001), 77–88.

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Editor information

Rights and permissions

Reprints and permissions

Copyright information

© 2016 TMS (The Minerals, Metals & Materials Society)

About this paper

Cite this paper

Parra, D., Campos, L., Boaro, L., Ferreira, H., Lugão, A., Rangari, V. (2016). Effect of MMT Nanoparticle Clay on Flexural Properties of Polymer Based BisGMA/Tegdma Resin. In: TMS 2016 145th Annual Meeting & Exhibition. Springer, Cham. https://doi.org/10.1007/978-3-319-48254-5_28

Download citation

Publish with us

Policies and ethics