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The Influence of Low Temperature Clustering on Strengthening Precipitation in Al-Mg-Si Alloys

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Light Metals 2016
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Abstract

Heat-treatable 6000 series aluminum alloys are the most commonly extruded materials in the world. The precipitation process in these alloys is both complex and well characterized. The earliest clustering stage has been shown to have a large effect on subsequent strengthening precipitation, however little is known about the influence of clustering as a function of composition and processing parameters. The current work examines this influence considering the factors of relative and absolute magnesium and silicon content, and the extent of natural aging. Billets were cast and extruded prior to heat-treatment, and the hardening response was evaluated with hardness, conductivity, and transmission electron microscopy (TEM). This work advances the current understanding of Al-Mg-Si precipitation by correlating the kinetics of age hardening to composition and processing, and may lead to further optimization of 6000 series alloy strength and toughness.

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References

  1. C. S. T. C. John Banhart, “Natural Aging in Al-Mg-Si Alloys — A Process of Unexpected Complexity,” Adv. Eng. Mater., vol. 12, no. 7, pp. 559 – 571, 2010.

    Article  Google Scholar 

  2. M. Murayama and K. Hono, “Pre-precipitate clusters and precipitation processes in Al-Mg-Si alloys,” Acta Mater., vol. 47, no. 5, pp. 1537–1548, Mar. 1999.

    Article  Google Scholar 

  3. D. J. Chakrabarti and D. E. Laughlin, “Phase relations and precipitation in Al-Mg-Si alloys with Cu additions,” Prog. Mater. Sci., vol. 49, no. s 3–4, pp. 389–410, 2004.

    Article  Google Scholar 

  4. M. A. van Huis, J. H. Chen, M. H. F. Sluiter, and H. W. Zandbergen, “Phase stability and structural features of matrix-embedded hardening precipitates in Al-Mg-Si alloys in the early stages of evolution,” Acta Mater., vol. 55, no. 6, pp. 2183–2199, Apr. 2007.

    Article  Google Scholar 

  5. C. D. Marioara, S. J. Andersen, H. W. Zandbergen, and R. Holmestad, “The influence of alloy composition on precipitates of the Al-Mg-Si system,” Metall. Mater. Trans. A, vol. 36, no. 13, pp. 691–702, Mar. 2005.

    Article  Google Scholar 

  6. K. Matsuda, T. Kawabata, Y. Uetani, T. Sato, A. Kamio, and S. Ikeno, “HRTEM Observation of G.P. Zones and Metastable Phase in Al-Mg-Si Alloys,” Mater. Sci. Forum, vol. 331–337, pp. 989–994, 2000.

    Article  Google Scholar 

  7. M. Murayama, K. Hono, M. Saga, and M. Kikuchi, “Atom probe studies on the early stages of precipitation in Al-Mg-Si alloys,” Mater. Sci. Eng. A, vol. 250, no. 1, pp. 127–132, Jul. 1998.

    Article  Google Scholar 

  8. G. A. Edwards, K. Stiller, G. L. Dunlop, and M. J. Couper, “The precipitation sequence in Al–Mg–Si alloys,” Acta Mater., vol. 46, no. 11, pp. 3893–3904, Jul. 1998.

    Article  Google Scholar 

  9. A. Kelly and R. Nicholson, Precipitation hardening,. Oxford; New York: Pergamon Press, 1963.

    Google Scholar 

  10. H. Seyedrezai, D. Grebennikov, P. Mascher, and H. S. Zurob, “Study of the early stages of clustering in Al–Mg–Si alloys using the electrical resistivity measurements,” Mater. Sci. Eng. A, vol. 525, no. 1–2, pp. 186–191, Nov. 2009.

    Article  Google Scholar 

  11. A. Serizawa, S. Hirosawa, and T. Sato, “Three-Dimensional Atom Probe Characterization of Nanoclusters Responsible for Multistep Aging Behavior of an Al-Mg-Si Alloy,” Metall. Mater. Trans. A, vol. 39, no. 2, pp. 243–251, Jan. 2008.

    Article  Google Scholar 

  12. C. S. T. Chang and J. Banhart, “Low-Temperature Differential Scanning Calorimetry of an Al-Mg-Si Alloy,” Metall. Mater. Trans. A, vol. 42, no. 7, pp. 1960–1964, Jan. 2011.

    Article  Google Scholar 

  13. A. Cuniberti, A. Tolley, M. V. C. Riglos, and R. Giovachini, “Influence of natural aging on the precipitation hardening of an AlMgSi alloy,” Mater. Sci. Eng. A, vol. 527, no. 20, pp. 5307–5311, Jul. 2010.

    Article  Google Scholar 

  14. C. D. Marioara, S. J. Andersen, J. Jansen, and H. W. Zandbergen, “The influence of temperature and storage time at RT on nucleation of the β″ phase in a 6082 Al–Mg–Si alloy,” Acta Mater., vol. 51, no. 3, pp. 789–796, Feb. 2003.

    Article  Google Scholar 

  15. Y. Birol, “Effect of natural ageing on the performance of pre-ageing to improve bake-hardening response of a twin-roll cast Al–Mg–Si alloy,” Z. Für Met., vol. 96, no. 4, pp. 380–384, Apr. 2005.

    Article  Google Scholar 

  16. J. Røyset, T. Stene, J. A. Sæter, and O. Reiso, “The Effect of Intermediate Storage Temperature and Time on the Age Hardening Response of Al-Mg-Si Alloys,” Mater. Sci. Forum, vol. 519–521, pp. 239–244, 2006.

    Article  Google Scholar 

  17. S. Esmaeili, X. Wang, D. J. Lloyd, and W. J. Poole, “On the precipitation-hardening behavior of the Al-Mg-Si-Cu alloy AA6111,” Metall. Mater. Trans. A, vol. 34, no. 3, pp. 751–763, Mar. 2003.

    Article  Google Scholar 

  18. H. S. Zurob and H. Seyedrezai, “A model for the growth of solute clusters based on vacancy trapping,” Scr. Mater., vol. 61, no. 2, pp. 141–144, Jul. 2009.

    Article  Google Scholar 

  19. L. A. Girifalco and H. Herman, “A model for the growth of Guinier-Preston zones-the vacancy pump,” Acta Metall., vol. 13, no. 6, pp. 583–590, Jun. 1965.

    Article  Google Scholar 

  20. F. N. Shoichi Hirosawa, “First-Principles Calculation of Interaction Energies between Solutes and/or Vacancies for Predicting Atomistic Behaviors of Microalloying Elements in Aluminum Alloys,” Mater. Sci. Forum — MATER SCI FORUM, pp. 283–286, 2007.

    Google Scholar 

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Poznak, A., Sanders, P. (2016). The Influence of Low Temperature Clustering on Strengthening Precipitation in Al-Mg-Si Alloys. In: Williams, E. (eds) Light Metals 2016. Springer, Cham. https://doi.org/10.1007/978-3-319-48251-4_40

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