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Layered Double Hydroxides in Energy Research: Advantages and Challenges

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Energy Technology 2015
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Abstract

Layered Double Hydroxides (LDH) are being used in energy related research for last several years. Among others, research interests include synthesis of catalysts, electrocatalysts, photocatalysts, electrode materials for batteries and super capacitors, and luminescence materials. They can be also applied for the production of renewable energy sources, such as hydrogen and oxygen. LDH materials have several advantages in general, such as their low cost, versatility of their chemical composition, easily manipulated properties, a wide range of preparation variables, unique anion exchange and intercalation properties, chemical stability, and colloidal and thermal behavior. On the other hand, their use in particular energy research produces some challenging physical and chemical aspects that need to be addressed. These include lack of knowledge on exact structure, postulation of interlayer arrangement, and some selectivity issues in catalysis. In this work, we will revisit these topics with an overview of the historical background and current literature survey.

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References

  1. G. Grünewald, K. Kaiser, and R. Jahn, “Hydrotalcite—A potentially significant sorbent of organic matter in calcareous alkaline soils,” Geoderma, 147 (2008), 141–150.

    Article  Google Scholar 

  2. Dongjin Wan et al., “Role of the Mg/Al atomic ratio in hydrotalcite-supported Pd/Sn catalysts for nitrate adsorption and hydrogenation reduction,” Journal of Colloid and Interface Science, 332(2009), 151–157.

    Article  Google Scholar 

  3. X. Guo, F. Zhang, D.G. Evans, and X. Duan, “Layered double hydroxide films: synthesis, properties and applications”. Chemical Communications, 46 (29) (2010), 5197–5210.

    Article  Google Scholar 

  4. L P.S. Braterman, Z.P. Xu and F. Yarberry In: S.M. Auerbach, K.A. Carrado and P.K. Dutta, Editors, Handbook of Layered Materials (New York, Dekker, 2004), 373–474.

    Google Scholar 

  5. V. Rives, ed., Layered Double Hydroxides: Present and Future (New York, Nova Science Publishers, 2001).

    Google Scholar 

  6. D. Evans, and R. Slade, “Structural Aspects of Layered Double Hydroxides Layered Double Hydroxides”, Layered Double Hydroxides (Structure and Bonding), ed., X. Duan and D. Evans (Berlin/Heidelberg, Springer. 2006), 1–87.

    Google Scholar 

  7. W. Canter, Nitrates in Groundwater (Boca Raton, FL, CRC Press, 1996), 217–256.

    Google Scholar 

  8. T.J. Pinnavaia, et al., “Organic chemical conversions catalyzed by intercalated layered double hydroxides (LDHs)”, Applied Clay Science, 10 (1–2) (1995), 117–117.

    Article  Google Scholar 

  9. A.D. Roy, and J.P. Besse, “Evolution of protonic conduction in some synthetic anionic clays”, Solid State Ionics, 46 (1–2) (1991), 95–101.

    Google Scholar 

  10. G. Fan, F. Li, D.G. Evans, and X. Duan, “Catalytic applications of layered double hydroxides: recent advances and perspectives,” Chemical Society Reviews, 43 (2014), 7040–7066.

    Article  Google Scholar 

  11. O.L. Alves, et al., “Application Layered Double Hydroxides (LDH) as heterogeneous catalysts for synthesis of biodiesel,” Journal of Physics Conference Series, 304 (012024) (2011), 1–8.

    Article  Google Scholar 

  12. X. Zou, A. Goswami and T. Asefa, “Efficient Noble Metal-Free (Electro)Catalysis of Water and Alcohol Oxidations by Zinc-Cobalt Layered Double Hydroxide”, Journal of American Chemical Society, 135 (2013), 17242–45.

    Article  Google Scholar 

  13. M. Gong, et al., “An Advanced Ni Fe Layered Double Hydroxide Electrocatalyst for Water Oxidation” Journal of American Chemical Society, 135 (2013), 8452–8455.

    Article  Google Scholar 

  14. T. Tsuneishia, et al., “Preparation of hydroxide ion conductive KOH-layered double hydroxide electrolytes for an all-solid-state iron-air secondary battery”, Journal of Asian Ceramic Societies, 2 (2014), 165–168.

    Article  Google Scholar 

  15. N. Zhuravleva, et al., “Energy transfer in luminescent Tb- and Eu-containing layered double hydroxides,” Mendeleev Communications, 14 (2004), 176–178.

    Article  Google Scholar 

  16. H. Curtius et al., “Preparation and characterization of Fe-, Co-, and Ni-containing Mg-Al-layered double hydroxides,” Clays and Clay Minerals, 61 (2013), 424–439.

    Article  Google Scholar 

  17. V. Gupta, S. Gupta, and N. Miura, “Potentiostatically deposited nanostructured CoxNi1-x layered double hydroxides as electrode materials for redox-supercapacitors,” Journal of Power Sources 175 (2008) 680–685.

    Article  Google Scholar 

  18. Jimenez et al., “Catalytic deoxygenation of triglycerides and fatty acids to hydrocarbons over Ni-Al layered double hydroxide,” Catalysis Today 237 (2014) 136–144.

    Article  Google Scholar 

  19. Li et al., “Synthesis, characterization and electrochemical performance of high-density aluminum substituted α-nickel hydroxide cathode material for nickel-based rechargeable batteries,” Journal of Power Sources 270 (2014) 121–130.

    Article  Google Scholar 

  20. Loh et al., “Co/Al layered double hydroxides nanostructures: A binderless electrode for electrochemical capacitor,” Electrochemistry Communications 43 (2014) 9–12.

    Article  Google Scholar 

  21. S. Nishimura, A. Takagaki, and K. Ebitani, “Characterization, synthesis and catalysis of hydrotalcite-related materials for highly efficient materials transformations,” Green Chem., 15 (2013) 2026.

    Article  Google Scholar 

  22. Qin et al., “Phosphorescent Sensor Based on Iridium Complex/Poly(vinylcarbazole) Orderly Assembled with Layered Double Hydroxide Nanosheets: Two-Dimensional Föster Resonance Energy Transfer and Reversible Luminescence Response for VOCs, J. Phys. Chem. C 118 (2014) 20538–20544.

    Article  Google Scholar 

  23. Song et al., “Self-assembled hierarchical porous layered double hydroxides by solvothermal method and their application for capacitors,” Microporous and Mesoporous Materials 148 (2012) 159–165.

    Article  Google Scholar 

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Gomes, A., Cocke, D., Tran, D., Baksi, A. (2015). Layered Double Hydroxides in Energy Research: Advantages and Challenges. In: Jha, A., et al. Energy Technology 2015. Springer, Cham. https://doi.org/10.1007/978-3-319-48220-0_34

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