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Evaluation of the Silver Recovery from Radiographic Films in a Filter Press Electrochemical Reactor

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Energy Technology 2015

Abstract

In this work the evaluation of a filter press type electrochemical reactor (REOV-01) with stainless steel (A304) electrode was realized, applied in the silver recovery from radiographic films. Macroelectrólisis studies were performed at different flow velocities with empirical and dimensionless correlations, and parameters such as: current efficiency, energy consumption Es and space-time yield. The results of the variation of the concentration of Ag at different flow linear velocities allowed the determination of the mass transfer coefficients of silver (obtained about the order of 10exp-5) for A304 SS electrode, which are consistent with the literature. The current efficiency values above 100% indicated that the electrochemical process is coupled to an electroless process. The results showed low energy consumption Es and high space-time yield values indicating that the reactor REOV-01 presents an excellent performance in the recovery of silver from radiographic films.

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References

  1. Ramírez O.P. A, Estudio electroquímico preliminar para depositar Ag proveniente de los desechos sólidos de la industria fotográfica y radiográfica. Tesis de Licenciatura, UAEH, Hidalgo, México (2006).

    Google Scholar 

  2. K. Guenter, Silver Recycling from photographic solutions: review of the methods, Chemical Labor Betr. 32 (1981), p40–48.

    Google Scholar 

  3. M. I. Ismail, Electrochemical reactors, their science and technology, part A: fundamentals, electrolysers, batteries and fuel cells; Elseiver Science Publishers B. V., Ámsterdam, Holanda (1989).

    Google Scholar 

  4. A. A. Wragg y A. A. Leontaritis. Chem. Eng. J. 66 (1997)

    Google Scholar 

  5. D. Pletcher y F. C. Walsh. Industrial Electrochemistry, 2nd Edn., Chapman & Hall, London (1990).

    Google Scholar 

  6. D. A. McInnes, The Principles of electrochemistry. New York, USA (1990).

    Google Scholar 

  7. D. Pletcher. A First Course in Electrode Processes. RSC Publishing, UK (1991).

    Google Scholar 

  8. C. J. Brown, D. Pletcher, F. C. Walsh, J. K. Hammond y D. Robinson. Studies of Space-Averaged Mass Transport in the FM01-LC Laboratory Electrolyser. J. of Appl. Electrochem. 22 (1992) 631.

    Article  Google Scholar 

  9. G. M. Zarkadas, A. Stergiou y G. Papanastasiou, Influence of citric acid on the silver electrodeposition from aqueous AgNO3 solutions, J. Electrochimica Acta 50 (2005) 5022–2031.

    Article  Google Scholar 

  10. N. Nakiboglu, D. Toscali y I. Yasa, Silver recovery from waste photographic films by enzematic method, Turk J. Chem. 25 (2001) 349p–353.

    Google Scholar 

  11. P. C. Holloway, K. P. Merriam y T. H. Etsell, Nitric acid leaching of silver sulphide precipitates, J. Hidrometallurgy 74 (2004) 213–220.

    Article  Google Scholar 

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© 2015 TMS (The Minerals, Metals & Materials Society)

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Ortega, P.A.R., Cruz, V.E.R., Hernández, L.G., Islas, D.A., Guerrero, M.U.F., Lechuga, L.G. (2015). Evaluation of the Silver Recovery from Radiographic Films in a Filter Press Electrochemical Reactor. In: Jha, A., et al. Energy Technology 2015. Springer, Cham. https://doi.org/10.1007/978-3-319-48220-0_26

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