Skip to main content

Thermal Properties of Polypropylene Nanocomposites with Organoclay and Discarded Bond Paper

  • Chapter
Characterization of Minerals, Metals, and Materials 2016

Abstract

This work concerns the study of the effect of discarded bond paper on the thermal behavior of the polypropylene/organophilic clay nanocomposite. A brown polycationic bentonite from state of Paraíba, Brazil, was treated industrially with sodium carbonate to transform it into a bentonite which swells in water and then treated with ammonium chloride hexadecyltrimethylammonium to turn it into a swellable organoclay in organic liquids. Polypropylene with 3 % polypropylene graft compatibilizer (PP-g-AM) was mixed with 1 % and 2 % by weight of discarded bond paper and with 1% , 2% e 5 % by weight of organophilic clay using a twin-screw extruder. The specimens were prepared by the injection process. The nanocomposite specimens were characterized by XRD, SEM, and thermal analysis (ATG and DSC). The nanocomposites showed improved thermal properties compared with the polymer without filler.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 239.00
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
Hardcover Book
USD 219.99
Price excludes VAT (USA)
  • Durable hardcover edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. S. Ifuku and H. Yano, “Effect of a silane coupling agent on the mechanical properties of a microfibrillated cellulose composite”, International Journal of Biological Macromolecules, 74 (2015), 428–432.

    Article  Google Scholar 

  2. A. Pappua, V. Patil, S. Jain, A. Mahindrakar, R. Haque and V. K. Thakur, “Advances in industrial prospective of cellulosic macromolecules enriched banana biofibre resources: A review”, International Journal of Biological Macromolecules, 79 (2015), 449–458.

    Article  Google Scholar 

  3. L. He, W. Li, D. Chen, D. Zhou, G. Lu and J. Yuan, “Effects of amino silicone oil modification on properties of ramie fiber and ramie fiber/polypropylene composites”, Materials and Design, 77 (2015), 142–148.

    Article  Google Scholar 

  4. V. Khoshkava, H. Ghasemi and M. R. Kamal, “Effect of cellulose nanocrystals (CNC) on isothermal crystallization kinetics of polypropylene”, Thermochimica Acta, 608 (2015), 30–39.

    Article  Google Scholar 

  5. S. Al-Malaika, H. Sheena , D. Fischer and E. Masarati, “Influence of processing and clay type on nanostructure and stability of polypropylene clay nanocomposites”, Polymer Degradation and Stability, 98 (2013), 2400–2410.

    Article  Google Scholar 

  6. A. Ladhari, H. B. Daly, H. Belhadjsala , K. C. Cole and J. Denault, “Investigation of water absorption in clay-reinforced polypropylene nanocomposites”, Polymer Degradation and Stability, 95 (2010), 429–439.

    Article  Google Scholar 

  7. M. Ataeefard and Siamak Moradian, “Surface properties of polypropylene/organoclay nanocomposites”, Applied Surface Science, 257 (2011), 2320–2326.

    Article  Google Scholar 

  8. T. Koukoulas, W. R. Broughton and P. Woolliams, “Assessment of nanoparticle loading and dispersion in polymeric materials using optical wavefront correlation”, Polymer Testing, 44 (2015), 57–65.

    Article  Google Scholar 

  9. A. S. Abreu, M. Oliveira and A. V. Machado, “Effect of clay mineral addition on properties of bio-based polymer blends”. Applied Clay Science, 104 (2015), 277–285.

    Article  Google Scholar 

  10. L. G. Furlan, C. I. Ferreira, C. Dal Castel, K. S. Santos, A. C. E. Mello, S. A. Liberman, M. A. S. Oviedo and R. S. Mauler, “Effect of processing conditions on the mechanical and thermal properties of high-impact polypropylene nanocomposites”, Materials Science and Engineering A, 528 (2011), 6715–6718.

    Article  Google Scholar 

  11. Z. Dominkovics, J. Hári, E. Fekete and B. Pukánszky, “Thermo-oxidative stability of polypropylene/layered silicate nanocomposites”, Polymer Degradation and Stability, 96 (2011), 581–587.

    Article  Google Scholar 

  12. D. D. J. Rousseaux, M. Sclavons, P. Godard and J. Marchand-Brynaert, “Tuning the functionalization chemistry of polypropylene for polypropylene/clay nanocomposites”, Reactive & Functional Polymers,72 (2012), 17–24.

    Article  Google Scholar 

  13. S. Zhu, J. Chen, Y. Zuo, H. Li and Y. Cao, “Montmorillonite/polypropylene nanocomposites: Mechanical properties, crystallization and rheological behaviors”, Applied Clay Science, 52 (2011), 171–178.

    Article  Google Scholar 

  14. M. R. Abadchi and A. Jalali-Arani, “Crystallization and melting behavior of polypropylene (PP) in (vulcanized nanoscale polybutadiene rubber powder/PP) polymer-nanocomposites”, Thermochimica Acta, 617 (2015), 120–128.

    Article  Google Scholar 

  15. M. Ataeefard and S. Moradian, “Surface properties of polypropylene/organoclay nanocomposites”, Applied Surface Science, 257 (2011), 2320–2326.

    Article  Google Scholar 

  16. LV. Yadong, Y. Huang, M. Kong, J. Yang, Qi. Yang and G. Li, “Creep Lifetime Prediction of Polypropylene/Clay Nanocomposites Based on a Critical Failure Strain Criterion”, Composites Science and Technology, 96 (2014), 71–79.

    Article  Google Scholar 

  17. W. Xu, G. Liang, H. Zhai, S. Tang, G. Hang and E. P. PAN, “Preparation and Crystallization Behavior of PP/PP-g-MAH/Org-MMT Nanocomposite”, European Polymer Journal, 39 (7) (2003), 1467–1474.

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Editor information

Editors and Affiliations

Rights and permissions

Reprints and permissions

Copyright information

© 2016 TMS (The Minerals, Metals & Materials Society)

About this chapter

Cite this chapter

Fermino, D.M., Andrade, C.G.B., Parra, D.F., Lugão, A.B., Diaz, F.R.V. (2016). Thermal Properties of Polypropylene Nanocomposites with Organoclay and Discarded Bond Paper. In: Ikhmayies, S.J., et al. Characterization of Minerals, Metals, and Materials 2016. Springer, Cham. https://doi.org/10.1007/978-3-319-48210-1_29

Download citation

Publish with us

Policies and ethics