Thermo- and Electro-Transport in Solids

Abstract

If a current of electricity, or a flux of heat, is passed through an initially homogeneous alloy an unmixing occurs, that is a concentration gradient develops. These effects are called electro-transport and thermotransport, respectively. In electro-transport the atomic redistribution is similar to that studied in ionic conductors. However, in metals electrons carry essentially all of the electric current, and the ratio of electron to atomic currents is high. It appears that most of the atomic transport results from the impact of the large flux of electrons on the solute atoms making diffusive jumps. In thermo-transport, the redistribution of solute which occurs is analogous to the more widely studied thermoelectric effects that arise from the redistribution of electrons in a solid in a temperature gradient. The origin of the force driving the atoms is not clear.