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Coke Calcination Levels and Aluminum Anode Quality

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Essential Readings in Light Metals

Abstract

The calcination temperature of petroleum coke for aluminum anode applications has been generally increased during the past 10 years. This change by coke suppliers has often been done at the request of anode manufacturers (smelters) who seek special quality requirements for the calcined coke. Such an increase in calcining temperatures not only affects coke properties, but also has an effect on calciner operations and may have some unexpected effects on anode quality.

One high and one low sulphur coke were calcined industrially at two different levels. The four individual calcined cokes were characterized. Then laboratory scale anodes were produced with each individual calcined coke. These all-coke anodes were first evaluated for optimum pitch content. Then the anodes were baked over a range of temperatures (920 to 1260°C) in order to evaluate the influence of this heat treatment on anode properties.

The results show the influence of calcining temperature on coke properties and anode properties, including the most important influence of the anode baking level.

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References

  1. E.E. Hardin, C.L. Beilharz, L.L. Melvin, “A Comprehensive Review of the Effect of Coke Structure and Properties When Calcined at Various Temperatures,” Light Metals 1993, p. 501–508.

    Google Scholar 

  2. E.A. Heintz, “Crystallite Growth and Ordering of Cokes in the Pre-graphitization Temperature Range,” Proc. 5th London International Carbon and Graphite Conference, Society of Chemical Industry, Vol. II, p. 575–587, (1978d).

    Google Scholar 

  3. R.E. Gehlbach, L.I. Grindstaff and M.P. Whittaker, “Effect of Calcination Temperature on Real Density of High Sulfur Coke,” Light Metals 1977.

    Google Scholar 

  4. E.E. Hardin, P.J. Ellis, C.L. Beilharz and L. McCoy, “A Comprehensive Review of the Effects of Calcination at Various Temperatures on Coke Structure and Properties Part II,” Light Metals 1994, p. 571–581.

    Google Scholar 

  5. R.M. Garbarino and R.T. Tonti, “Desulfurization and its Effect on Calcined Coke Properties,” Light Metals 1993, p. 517–520.

    Google Scholar 

  6. W.K. Fischer and R. Perruchoud, “Influence of Coke Calcination Parameters on Petroleum Coke Quality,” Light Metals 1985, p. 811–826.

    Google Scholar 

  7. E. Barrillon, “Evolution Thermique de la Texture Poreuse des Cokes de Pétrole,” (Carbon 1967, Vol. 5, p. 167–171).

    Article  Google Scholar 

  8. E. Barrillon, “Modification de la Texture du Coke de Pétrole lors d’une Désulfuration Thermique,” Journal Chimie Physigue (1968–65 n° 3), p. 428.

    Google Scholar 

  9. A.F. Bopp, G.B. Graff and B.H. Howard, “Influence of Maximum Temperature and Heat Soak Times on the Properties of Calcined Coke,” Light Metals 1984. p. 869–882.

    Google Scholar 

  10. S.R. Brandzaeg and H.A. Oye, “High Temperature Calcination of Anthracite, Petrol Coke and Pitch Coke,” Light Metals 1985, p. 839–852.

    Google Scholar 

  11. M.H. Wagner, H. Pauls, H. Tillmanns and G. Wilhelmi, “Calcination: the Effect of Maximum Heat Treatment Temperature on the Properties of Coke,” 16th biennial Conference on Carbon 1983. p. 583–585.

    Google Scholar 

  12. A. Slagtern, K. Grjotheim, T. Foosnaes and T. Naterstad, “Thermal Expansion of Carbon Materials Calcined at Various Temperatures: Structure, Pore Volume and Content of Impurities,” Light Metals 1987. p. 449–458.

    Google Scholar 

  13. MF. Vogt, K. Ries, M. Smith, “Anode Desulfurization During Baking.” Light Metals 1995. p. 691–700.

    Google Scholar 

  14. D. Belitskus, D.J. Danka, “A Comprehensive Determination of Effects of Calcined Petroleum Coke Properties of Aluminum Reduction Cell Anode Properties,” Light Metals 1989, p. 429–439.

    Google Scholar 

  15. P. Rhedey, “A Review of Factors Affecting Carbon Anode Consumption in the Electrolytic Production of Aluminum,” Light Metals 1971. The Metallurgical Society of AIME, Warrendale, PA, p. 385–407(1971).

    Google Scholar 

  16. P.J. Rhedey “Carbon Reactivity and Aluminium Reduction Cell Anodes,” Light Metals 1982. 713–725.

    Google Scholar 

  17. W.K. Fischer, F. Keller, R.C. Perruchoud, “Interdependence Between Anode Net Consumption and Pot Design, Pot Operating Parameters and Anode Properties,” Light Metals 1991. p. 681–686.

    Google Scholar 

  18. W.K. Fischer, “Materials for the Production of Prebaked Anodes,” 3rd Australasian Aluminum Smelting Technology Course. Nov. 1989.

    Google Scholar 

  19. L. Lavigne, L. Castonguay, “Prediction of Anode Performance from Calcined Coke Properties,” Light Metals 1993. p. 569–575.

    Google Scholar 

  20. D. Belitskus, “Effects of Petroleum Coke Calcination Temperature and Anode Baking Temperature on Anodes Properties,” Light Metals 1991. p. 557–563.

    Google Scholar 

  21. T. Müftüoglu, R. Fernandez, “The Effects of Feedstock and Coke Calcination Degree on the Properties of Bench Scale Anodes,” Light Metals 1990. p. 511–519.

    Google Scholar 

  22. Hang Shi, J.N. Reimers and J.R. Dahn, J. Appl. Cryst (1993), 26, p. 827–836.

    Google Scholar 

  23. B. Coste, J.P. Schneider, “Influence of Coke Real Density on Anode Reactivity. Consequence on Anode Baking,” Light Metals 1994. 583–591.

    Google Scholar 

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Dreyer, C., Samanos, B., Vogt, F. (2016). Coke Calcination Levels and Aluminum Anode Quality. In: Tomsett, A., Johnson, J. (eds) Essential Readings in Light Metals. Springer, Cham. https://doi.org/10.1007/978-3-319-48200-2_12

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