Skip to main content

Abstract

Corrosion is a significant problem in a large number of aerospace and commercial applications. Prediction of expected pit size and distribution due to localized corrosion processes is essential in understanding product life. Until now, the approach to predict pit size has been based on statistical analysis of pits in exposure tests. In this work, a combined experimental and multi-scale modeling method is used to develop a physics-based approach to understanding the factors that affect pit growth. The integrated approach uses thermodynamic modeling to understand the pit solution chemistry, atomistic modeling to study the kinetics, and experimental electro-kinetic measurements to validate the model predictions. Each of these pieces feed into an analytical model of pit growth to determine the maximum theoretical size. Model assumptions, results and pit size predictions for model aluminum systems are discussed.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 149.00
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
Hardcover Book
USD 169.99
Price excludes VAT (USA)
  • Durable hardcover edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. J.R. Galvele, “Transport Processes and the Mechanism of Pitting of Metals,” J Electrochem Soc, 123 (1976) 464–474.

    Article  Google Scholar 

  2. T.R. Beck, “Salt Film Formation During Corrosion of Aluminum,” Electrochimica Acta, 29 (1984) 485–491.

    Article  Google Scholar 

  3. M. Verhoff, R. Alkire, “Experimental and Modeling Studies of Single Pits on Pure Aluminum in pH 11 NaCl Solutions,” J Electrochem Soc, 147 (2000) 1349–1358.

    Article  Google Scholar 

  4. F. Cui, F.J. Persuel-Moreno, R.G. Kelly, “Computational modeling of cathodic limitations on localized corrosion of wetted SS 316L at room temperature,” Corr Sci, 47 (2005) 2987–3005.

    Article  Google Scholar 

  5. O. Guseva, P. Schmutz, T. Suter, O. von Trzebiatowski, “Modeling of anodic dissolution of pure aluminum in sodium chloride,” Electrochimica Acta, 54 (2009) 4514–4524.

    Article  Google Scholar 

  6. J. Xiao, S. Chaudhuri, “Predictive modeling of localized corrosion: An application to aluminum alloys,” Electrochimica Acta, 56 (2011) 5630–5641.

    Article  Google Scholar 

  7. Z.Y. Chen, R.G. Kelly, “Computational Modeling of Bounding Conditions for Pit Size on Stainless Steel in Atomspheric Environments,” J Electrochem Soc, 157 (2010) C69-C78.

    Article  Google Scholar 

  8. J. Duan and J. Gregory, “Coagulation by hydrolyzing metal salts,” Adv. Colloid Interfac. 100–102 (2003) 475–502.

    Article  Google Scholar 

  9. X. Jin, W. Yang, Z. Qian, Y. Wang, and S. Bi, “DFT study on the interaction between monomeric aluminum and chloride ion in aqueous solution,” Dalton Trans. 40 (2011) 5052–58.

    Article  Google Scholar 

  10. Gaussian 03, Revision E.01, M.J. Frisch, et al., Gaussian, Inc., Pittsburgh, PA (2003).

    Google Scholar 

  11. R.W. Ashcraft, S. Raman, and W.H. Green, “Ab initio aqueous thermochemistry: application to the oxidation of hydroxylamine in nitric acid solution,” J Phys Chem B 111 (2007) 11968–83.

    Article  Google Scholar 

  12. M.W. Verbrugge, D.R. Baker, J. Newman, “Dependent-Variable Transformation for the Treatment of Diffusion, Migration, and Homogenous Reactions. Application to a Corroding Pit,” J Electrochel Soc, 140 (1993) 2530–2537.

    Article  Google Scholar 

  13. M. Alkire, R. Verhoff, “Experimental and Modeling Studies of Single Corrosion Pits on Pure Aluminum in pH 11 NaCl Solutions. II. Pit Stability,” J Electrochem Soc 147 (2000) 1349–1358.

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Editor information

Editors and Affiliations

Rights and permissions

Reprints and permissions

Copyright information

© 2013 TMS (The Minerals, Metals & Materials Society)

About this chapter

Cite this chapter

Smith, K.D. et al. (2013). ICME Approach to Corrosion Pit Growth Prediction. In: Li, M., Campbell, C., Thornton, K., Holm, E., Gumbsch, P. (eds) Proceedings of the 2nd World Congress on Integrated Computational Materials Engineering (ICME). Springer, Cham. https://doi.org/10.1007/978-3-319-48194-4_5

Download citation

Publish with us

Policies and ethics