Abstract
Corrosion is a significant problem in a large number of aerospace and commercial applications. Prediction of expected pit size and distribution due to localized corrosion processes is essential in understanding product life. Until now, the approach to predict pit size has been based on statistical analysis of pits in exposure tests. In this work, a combined experimental and multi-scale modeling method is used to develop a physics-based approach to understanding the factors that affect pit growth. The integrated approach uses thermodynamic modeling to understand the pit solution chemistry, atomistic modeling to study the kinetics, and experimental electro-kinetic measurements to validate the model predictions. Each of these pieces feed into an analytical model of pit growth to determine the maximum theoretical size. Model assumptions, results and pit size predictions for model aluminum systems are discussed.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
Preview
Unable to display preview. Download preview PDF.
References
J.R. Galvele, “Transport Processes and the Mechanism of Pitting of Metals,” J Electrochem Soc, 123 (1976) 464–474.
T.R. Beck, “Salt Film Formation During Corrosion of Aluminum,” Electrochimica Acta, 29 (1984) 485–491.
M. Verhoff, R. Alkire, “Experimental and Modeling Studies of Single Pits on Pure Aluminum in pH 11 NaCl Solutions,” J Electrochem Soc, 147 (2000) 1349–1358.
F. Cui, F.J. Persuel-Moreno, R.G. Kelly, “Computational modeling of cathodic limitations on localized corrosion of wetted SS 316L at room temperature,” Corr Sci, 47 (2005) 2987–3005.
O. Guseva, P. Schmutz, T. Suter, O. von Trzebiatowski, “Modeling of anodic dissolution of pure aluminum in sodium chloride,” Electrochimica Acta, 54 (2009) 4514–4524.
J. Xiao, S. Chaudhuri, “Predictive modeling of localized corrosion: An application to aluminum alloys,” Electrochimica Acta, 56 (2011) 5630–5641.
Z.Y. Chen, R.G. Kelly, “Computational Modeling of Bounding Conditions for Pit Size on Stainless Steel in Atomspheric Environments,” J Electrochem Soc, 157 (2010) C69-C78.
J. Duan and J. Gregory, “Coagulation by hydrolyzing metal salts,” Adv. Colloid Interfac. 100–102 (2003) 475–502.
X. Jin, W. Yang, Z. Qian, Y. Wang, and S. Bi, “DFT study on the interaction between monomeric aluminum and chloride ion in aqueous solution,” Dalton Trans. 40 (2011) 5052–58.
Gaussian 03, Revision E.01, M.J. Frisch, et al., Gaussian, Inc., Pittsburgh, PA (2003).
R.W. Ashcraft, S. Raman, and W.H. Green, “Ab initio aqueous thermochemistry: application to the oxidation of hydroxylamine in nitric acid solution,” J Phys Chem B 111 (2007) 11968–83.
M.W. Verbrugge, D.R. Baker, J. Newman, “Dependent-Variable Transformation for the Treatment of Diffusion, Migration, and Homogenous Reactions. Application to a Corroding Pit,” J Electrochel Soc, 140 (1993) 2530–2537.
M. Alkire, R. Verhoff, “Experimental and Modeling Studies of Single Corrosion Pits on Pure Aluminum in pH 11 NaCl Solutions. II. Pit Stability,” J Electrochem Soc 147 (2000) 1349–1358.
Author information
Authors and Affiliations
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 2013 TMS (The Minerals, Metals & Materials Society)
About this chapter
Cite this chapter
Smith, K.D. et al. (2013). ICME Approach to Corrosion Pit Growth Prediction. In: Li, M., Campbell, C., Thornton, K., Holm, E., Gumbsch, P. (eds) Proceedings of the 2nd World Congress on Integrated Computational Materials Engineering (ICME). Springer, Cham. https://doi.org/10.1007/978-3-319-48194-4_5
Download citation
DOI: https://doi.org/10.1007/978-3-319-48194-4_5
Publisher Name: Springer, Cham
Print ISBN: 978-3-319-48585-0
Online ISBN: 978-3-319-48194-4
eBook Packages: Chemistry and Materials ScienceChemistry and Material Science (R0)