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Effect of Calcium/Aluminium Ratio on Crystal Structure and Al2O3 Leaching Property of 12CaO·7Al2O3

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Light Metals 2014
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Abstract

12CaO·7Al2O3 (C12A7) with different calcium/aluminum ratio (C/A) were synthesized by sol-gel method and high-temperature sintering method in the paper. The phase composition of sinters was analyzed by XRD and the lattice constant was calculated by celref software. Finally, the alumina leaching experiments on sinters obtained from different synthesis methods were carried out. The results show the C/A of sinter with single phase C12A7 is 1.7 and the range of the best alumina leaching rate is between 1.6 and 1.8 when sol-gel method is used. On the other hand, the C/A is 1.6 and the range is between 1.4 and 1.6 when high-temperature sintering method is used. And the alumina leaching rate is direct proportion to the content of C12A7 and is inversely to the lattice constant under a certain conditions. Compared to sol-gel method, high-temperature sintering process can reduce the optimal C/A of C12A7.

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References

  1. K.P. Goodboy, “Investigation of a sinter process for extraction of A12O3 from coal wastes,” Metallurgical and Materials Transactions B, 7(4)(1976), 716–718.

    Article  Google Scholar 

  2. F. Seeley, et al., “Determination of extraction equilibria for several metals in the development of a process designed to recover aluminum and other metals from coal combustion ash,” Hydrometallurgy, 6(3)(1981), 277–290.

    Article  Google Scholar 

  3. P. Smith, “The processing of high silica bauxites-review of existing and potential processes,” Hydrometallurgy, 98(1)(2009), 162–176.

    Article  Google Scholar 

  4. [ R. Paramguru, P. Rath, V. Misra, “Trends in red mud utilization—A review,” Mineral Processing & Extractive Metall Rev, 26(1)(2004), 1–29.

    Article  Google Scholar 

  5. J. Grzymek, et al. The new way of alumina lixiviation from sinters containing 12CaO·7Al2O3 in J. Grzymek’s Method [M]. Light Metals 1988: 129–133.

    Google Scholar 

  6. M. Wôjcik, “The thermal decomposition of the carbonate reaction products,” Journal of Thermal Analysis and Calorimetry, 43(1)(1995), 149–156.

    Article  Google Scholar 

  7. L. Xiao-bin, et al., “Study and application of intensified sintering processfor alumina production,” The Chinese Journal of Nonferrous Metals, 14(6)(2004), 1031–1036.

    Google Scholar 

  8. T. Zhi-fang, B. Shi-wen, Y. Hai-yan, “Leaching kinetics of non-constant temperature process of calcium aluminate slag under microwave radiation,” The Chinese Journal of Nonferrous Metals, 16(2)(2006), 357–362.

    Article  Google Scholar 

  9. L. Gui-hua, et al., “Sintering process of diasporic bauxite with high iron content at low ratio of lime to silica for alumina production,” The Chinese Journal of Nonferrous Metals, 18(10)(2008), 1903–1908.

    Google Scholar 

  10. W. Bo, et al., “Effect of material ratio on leaching and self-disintegrating property of calcium aluminate slag,” Journal of Northeastern University: Natural Science, 29(11)(2008), 1593–1596.

    Google Scholar 

  11. H. Run-de, et al., “Research on alkali-limestone sintering process in handling the one-stage residues of pure alkali sintering process,” Journal of Guizhou University of Technology(Natural Science Edition), 33(3)(2004), 7–9.

    Google Scholar 

  12. L. Zhi-ying, et al., “Research on the intensified sintering mechanism of middle-grade bauxite and its digestion performances,” Light Metals, 12)(2009), 14–17.

    Google Scholar 

  13. X. Wei, et al., “Study on the process of extracting alumina from the middling grade bauxite using lime sinter,” Journal of Guizhou University of Technology (Natural Science Edition), 05)(2008), 41–43.

    Google Scholar 

  14. Z. Wu. Phase composition and leaching law of the sinter of CaO-Al2O3-SiO2 system [D]. Shenyang; Northeastern University, 2011.

    Google Scholar 

  15. H. Bartl, T. Scheller, “Zur struktur des 12CaO·7Al2O3,” Neues Jahrb MineralMonatsh, 35(1970), 547–552.

    Google Scholar 

  16. A.N. Christensen, “Neutron Powder Diffraction Profile Refinement Studies on Ca11.3Al14O32.3 and CaClO ” Acta Chemica Scandinavia A, 41(1987), 110–112.

    Google Scholar 

  17. Y. Adachi, et al., “Bistable resistance switching in surface-oxidized C12A7:e— single-crystal,” Materials Science and Engineering: B, 161(1–3)(2009), 76–79.

    Article  Google Scholar 

  18. S. Hui-lan, et al. Effect of Na2O on alumina leaching and self-disintegrating property of calcium aluminate slag; proceedings of the Light metals, F, 2010.

    Google Scholar 

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Bo, W., Jianxin, Z., Shufeng, Z., Huilan, S. (2014). Effect of Calcium/Aluminium Ratio on Crystal Structure and Al2O3 Leaching Property of 12CaO·7Al2O3 . In: Grandfield, J. (eds) Light Metals 2014. Springer, Cham. https://doi.org/10.1007/978-3-319-48144-9_15

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