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Stripping of Fe(III) from P204 by Oxalic Acid

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Rare Metal Technology 2016
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Abstract

In the process of extracting vanadium from stone coal by sulfuric acid leaching — P204 solvent extraction, Fe(III) can accumulate in the organic phase which reduces the extraction of vanadium. In order to eliminate the effects of the accumulation of iron, oxalic acid was used as the stripping agent to strip the Fe(III). The effects of oxalic acid concentration, phase ratio O/A, stripping time and shake velocity on the stripping of Fe(III) were studied. The results showed that the Fe(III) stripping rate can reach beyond 96% at the room temperature with 70g/L oxalic acid using an O/A of 2 at 160 rpm shake velocity for 20min. After 2-stage stripping, the concentration of Fe(III) in organic phase was 0.008g/L.

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Correspondence to Mingyu Wang .

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© 2016 TMS (The Minerals, Metals & Materials Society)

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Jiang, C., Zhou, S., Wang, M., Wang, X. (2016). Stripping of Fe(III) from P204 by Oxalic Acid. In: Alam, S., Kim, H., Neelameggham, N.R., Ouchi, T., Oosterhof, H. (eds) Rare Metal Technology 2016. Springer, Cham. https://doi.org/10.1007/978-3-319-48135-7_18

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