Abstract
One way to increase the biocompatibility of the surface of titanium alloys is to produce a surface layer with better physicochemical properties of the whole set than the base. The most popular methods of surface modification used in medical products include: chemical methods (eg. sol-gel method, atomic layer deposition (ALD)) and electrochemical (eg. anodic oxidation, fluorescent processing). Therefore, authors of this paper carried out a comparative analysis of \(TiO_{2}\) layers produced both using chemical (ALD) and electrochemical (anodic oxidation) methods. The study was performed based on evaluation of electrochemical properties of produced TiO2 layer on the Ti6Al7Nb substrate alloy. As a part of electrochemical properties testing, potentiodynamic, potentiostatic and impedance studies were performed. All the tests were carried out in simulated physiological Ringer’s solution in T = \(37\pm 1^{\circ }C\) temperature. Based on the results it was found that the most favorable set of electrochemical properties characterises \(TiO_{2}\) layer deposited by ALD method.
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References
Li, P.H., Chu, P.K.: Thin film deposition technologies and processing of biomaterials. In: Thin Film Coatings for Biomaterials and Biomedical Applications, pp. 3–28 (2016)
Basiaga, M., Walke, W., Paszenda, Z., Kajzer, A.: The effect of EO and steam sterilization on mechanical and electrochemical properties of titanium grade 4. Materiali Tehnologije 50(1), 153–158 (2016)
Marin, E., Lanzutti, A., Lekka, M., Guzman, L., Ensinger, W., Fedrizzi, L.: Chemical and mechanical characterization of \(TiO_{2}/Al_{2}O_{3}\) atomic layer depositions on AISI 316 L stainless steel. Surf. Coat. Technol. 211, 84–88 (2012)
Shan, C.X., Hou, X., Choy, K.L.: Layers on implantable titanium alloys. Optica Applicata 43(1), 173–180 (2008)
Szewczenko, J., Jaglarz, J., Kurzyk, J., Paszenda, Z.: Optical methods applied in thickness and topography testing of passive layers on implantable titanium alloys. Optica Applicata 43(1), 173–180 (2013)
Babilas, D., et al.: On the electropolishing and anodic oxidation of Ti-15Mo alloy. Electrochimica Acta 205, 256–265 (2016)
Lia, X., Chena, T., Hua, J., Lib, S., Zouc, Q., Lia, Y., Jianga, N., Lia, H., Lia, J.: Modified surface morphology of a novel Ti-24Nb-4Zr-7.9Sn titanium alloy via anodic oxidation for enhanced interfacial biocompatibility and osseointegration. Colloids Surf. B Biointerfaces 144, 265–275 (2016)
Wang, W.K., et al.: Nanotribological properties of ALD-processed bilayer \(TiO_{2}/ZnO\) films. Microelectron. Reliab. 54(12), 2754–2759 (2014)
Borgese, L., Bontempi, E., Gelfi, M., Depero, L.E., Goudeau, P., Geandier, G., Thiaudière, D.: Microstructure and elastic properties of atomic layer deposited TiO2 anatase thin films. Acta Materialia 59(7), 2891–2900 (2011)
Aarik, L., Arroval, T., Rammula, R., Mändar, H., Sammelselg, V., Aarik, J.: Atomic layer deposition of \(TiO_{2}\) from \(TiCl_{4}\) and \(O_{3}\). Thin Solid Films 542, 100–107 (2013)
Saleem, M.R., Silfsten, P., Honkanen, S., Turunen, J.: Thermal properties of \(TiO_{2}\) films grown by atomic layer deposition. Thin Solid Films 520, 5442–5446 (2012)
Zhong, Q., Yan, J., Qian, X., Zhang, T., Zhang, Z., Lia, A.: Atomic layer deposition enhanced grafting of phosphorylcholine on stainless steel for intravascular stents. Colloids Surf. B Biointerfaces 121, 238–247 (2014)
Basiaga, M., Jendruś, R., Walke, W., Paszenda, Z., Kaczmarek, M., Popczyk, M.: Influence of surface modification on properties of stainless steel used for implants. Arch. Metall. Mater. 60(4), 2965–2969 (2015)
Basiaga, M., Staszuk, M., Walke, W., Opilski, Z.: Mechanical properties of ALD \(TiO_{2}\) layers on stainless steel substrate. Materialwissenschaft Werkstofftechnik 47(5), 1–9 (2016)
Kiel, M., Szewczenko, J., Nowińska, K.: Technological capabilities of surface layers formation on implants made of Ti-6Al-4V alloy. Acta Bioeng. Biomech. 17(1), 31–37 (2015)
Marciniak, J., Szewczenko, J., Kajzer, W.: Surface modification of implants for bone surgery. Arch. Metall. Mater. 60(3), 2123–2129 (2015)
ASTM F2129: Standard Test Method for Conducting Cyclic Potentiodynamic Polarization Measurements to Determine the Corrosion Susceptibility of Small Implant Devices (2015)
Kajzer, A., Kajzer, W., Dzielicki, J., Matejczyk, D.: The study of physicochemical properties of stabilizing plates removed from the body after treatment of pectus excavatum. Acta Bioeng. Biomech. 2, 35–44 (2015)
ASTM F746–04: Standard Test Method for Pitting or Crevice Corrosion of Metallic Surgical Implant Materials (2009)
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Basiaga, M., Szewczenko, J., Walke, W., Paszenda, Z., Antonowicz, M., Hyla, A. (2017). Electrochemical Properties of \(TiO_{2}\) Oxide Layer Deposited on Ti6Al7Nb Alloy. In: Gzik, M., Tkacz, E., Paszenda, Z., Piętka, E. (eds) Innovations in Biomedical Engineering. Advances in Intelligent Systems and Computing, vol 526. Springer, Cham. https://doi.org/10.1007/978-3-319-47154-9_1
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