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Encapsulation of Nanomaterials and Production of Nanofertilizers and Nanopesticides: Insecticides for Agri-food Production and Plant Disease Treatment

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Nanoscience and Plant–Soil Systems

Part of the book series: Soil Biology ((SOILBIOL,volume 48))

Abstract

Polymerization of citric acid onto the surface of oxidized multiwall carbon nanotubes led to the formation of MWCNTgraft-poly (citric acid) (MWCNT-g-PCA) hybrid materials. Because of the presence of conjugated citric acid branches, synthesized MWCNT-g-PCA hybrid materials were not only soluble in water but also able to trap water-soluble chemical species and metal ions. Trapping of pesticides such as Zineb, Mancozeb, Benomyl, Trichlorfon, and Pymetrozine (chess) in aqueous solution by MWCNT-g-PCA hybrid materials led to Encapsulated Pesticide (EP) into the polycitric acid shell. Optimum conditions for encapsulation of the pesticides in hyper branch polycitric acid such as pH, time of stirrer, and temperature were investigated by UV-Vis spectroscopy method. Encapsulation of pesticides on CNT-g-PCA hybrid material was confirmed via TEM analysis. Furthermore, the effect of encapsulated pesticides on Alternaria alternate fungi was investigated. Experiments indicated that new CNT-g-PCA-EP hybrid materials in comparison with bulk pesticides had a superior toxic influence on Alternaria alternata fungi.

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References

  • Adeli M, Bahari A, Hekmatara H (2008) Carbon nanotube-graft-poly (citric acid) nanocomposites. Nano 3:37–44

    Article  CAS  Google Scholar 

  • Ajayan P (1999) Nanotubes from carbon. Chem Rev 99:1787–1800

    Article  CAS  PubMed  Google Scholar 

  • Al-Degs YS, Al-Ghouti MA, El-Sheikh AH (2009) Simultaneous determination of pesticides at trace levels in water using multiwalled carbon nanotubes as solid-phase extractant and multivariate calibration. J Hazard Mater 169:128–135

    Article  CAS  PubMed  Google Scholar 

  • Brück E, Elbert A, Fischer R, Krueger S, Kühnhold J, Klueken AM, van Waetermeulen X (2009) Movento®, an innovative ambimobile insecticide for sucking insect pest control in agriculture: biological profile and field performance. Crop Protect 28:838–844

    Article  Google Scholar 

  • Burnett KG (2005) Chapter 8 Impacts of environmental toxicants and natural variables on the immune system of fishes. In: Mommsen TP, Moon TW (eds) Biochemistry and molecular biology of fishes, vol 6. Elsevier, St.Louis, pp 231–253

    Google Scholar 

  • Chung H, Son Y, Yoon TK, Kim S, Kim W (2011) The effect of multi-walled carbon nanotubes on soil microbial activity. Ecotoxicol Environ Saf 74:569–575

    Article  CAS  PubMed  Google Scholar 

  • Del Carmen Giménez-López M, Moro F, La Torre A, Gómez-García CJ, Brown PD, van Slageren J, Khlobystov AN (2011) Encapsulation of single-molecule magnets in carbon nanotubes. Nat Commun 2:407. doi:10.1038/ncomms1415

    Article  Google Scholar 

  • Doane WM (1992) Encapsulation of pesticides in starch by extrusion. Ind Crops Prod 1:83–87

    Article  CAS  Google Scholar 

  • Honeycutt Richard C, Zweig G, Ragsdale N, Durham William F (1985) Preface, introduction dermal exposure related to pesticide use. Am Chem Soc 273:11–14

    Google Scholar 

  • Kuo C-F, Chyau C-C, Wang T-S, Li C-R, Hu T-J (2009) Enhanced antioxidant and anti-inflammatory activities of Monascus pilosus fermented products by addition of turmeric to the medium. J Agr Food Chem 57(11397):11405

    Google Scholar 

  • Lewis D, Cowsar D (1977) Principles of controlled release pesticides. Paper presented at the ACS Symposium Series American Chemical Society

    Google Scholar 

  • Lin D, Xing B (2007) Phytotoxicity of nanoparticles: inhibition of seed germination and root growth. Environ Pollut 150:243–250

    Article  CAS  PubMed  Google Scholar 

  • Matthews GA (2000) Pests, pesticides and pest management. In: Mason SJ (Ed.), Highlights in environmental research. pp. 165–189

    Google Scholar 

  • McCarroll NE, Protzel A, Ioannou Y, Frank Stack HF, Jackson MA, Waters MD, Dearfield KL (2002) A survey of EPA/OPP and open literature on selected pesticide chemicals. III. Mutagenicity and carcinogenicity of benomyl and carbendazim. Mutat Res 512:1–35

    Article  CAS  PubMed  Google Scholar 

  • Petersen EJ, Pinto RA, Zhang L, Huang Q, Landrum PF, Weber WJ Jr (2011) Effects of polyethyleneimine-mediated functionalization of multi-walled carbon nanotubes on earthworm bioaccumulation and sorption by soils. Environ Sci Technol 45:3718–3724

    Article  CAS  PubMed  Google Scholar 

  • Prasad R, Kumar V, Prasad KS (2014) Nanotechnology in sustainable agriculture: present concerns and future aspects. Afr J Biotechnol 13:705–713

    Article  CAS  Google Scholar 

  • Rijtema PE, Groenendijk P, Kroes JG (1999) Environmental influences on processes. In: Rijtema PE, Groenendijk P, Kroes JG (eds) Environmental impact of land use in rural regions, vol 1. Imperial College Press, London, pp 167–203

    Chapter  Google Scholar 

  • Sayes CM, Liang F, Hudson JL, Mendez J, Guo W, Beach JM, Billups WE (2006) Functionalization density dependence of single-walled carbon nanotubes cytotoxicity in vitro. Toxicol Lett 161:135–142

    Article  CAS  PubMed  Google Scholar 

  • Scher Herbert B (1984) Advances in pesticide formulation technology advances in pesticide formulation technology. Am Chem Soc 254:1–7

    Google Scholar 

  • Stobinski L, Lesiak B, Kövér L, Tóth J, Biniak S, Trykowski G, Judek J (2010) Multiwall carbon nanotubes purification and oxidation by nitric acid studied by the FTIR and electron spectroscopy methods. J Alloys Compound 501:77–84

    Article  CAS  Google Scholar 

  • Suwalsky M, Benites M, Norris B, Sotomayor P (2000) Toxic effects of the fungicide benomyl on cell membranes. Compar Biochem Physiol Part C: Pharmacol Toxicol Endocrinol 125:111–119

    CAS  Google Scholar 

  • Tian F, Cui D, Schwarz H, Estrada GG, Kobayashi H (2006) Cytotoxicity of single-wall carbon nanotubes on human Fibroblasts. Toxicol In Vitro 20:1202–1212

    Article  CAS  PubMed  Google Scholar 

  • Tordoir WF (1994) The development of safe chemical pesticides occupational health in national development. World Scientific, pp 27–42

    Google Scholar 

  • Trimnell D, Shasha B, Wing R, Otey F (1982) Pesticide encapsulation using a starch–borate complex as wall material. J Appl Polym Sci 27:3919–3928

    Article  CAS  Google Scholar 

  • Ulbricht H, Hertel T (2003) Dynamics of C60 encapsulation into single-wall carbon nanotubes. J Phys Chem B 107:14185–14190

    Article  CAS  Google Scholar 

  • Xu M-J, Yang Z-L, Liang Z-Z, Zhou S-N (2009) Construction of a Monascus purpureus mutant showing lower citrinin and higher pigment production by replacement of ctnA with pks1 without using vector and resistance gene. J Agr Food Chem 57:9764–9768

    Article  CAS  Google Scholar 

  • Zheng Z, Shetty K (1998) Solid-state production of beneficial fungi on apple processing wastes using glucosamine as the indicator of growth. J Agr Food Chem 46:783–787

    Article  CAS  Google Scholar 

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Correspondence to Nahid Sarlak .

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Sarlak, N., Taherifar, A. (2017). Encapsulation of Nanomaterials and Production of Nanofertilizers and Nanopesticides: Insecticides for Agri-food Production and Plant Disease Treatment. In: Ghorbanpour, M., Manika, K., Varma, A. (eds) Nanoscience and Plant–Soil Systems. Soil Biology, vol 48. Springer, Cham. https://doi.org/10.1007/978-3-319-46835-8_18

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