Abstract
The demand for high-strength and high-toughness material with lightweight and multifunctionality has always been a matter of concern. The specific properties of carbon fibre-reinforced polymer (CFRP) composites make it a promising candidate for various structural and functional applications. In this chapter, we review the performance of CFRP composites with various nanofillers (1) to enhance mechanical behaviours as structural materials, including interlaminar strength and toughness, impaction and fatigue performance, and (2) to enable/enhance multifunctional behaviour, including thermal conductivity, electrical conductivity and other performance. Overall, this discussion provides a broad overview and technically viable routes to obtain particular combinations of various mechanical and functional behaviours of CFRP with nanofillers included. Future exploration may involve using hybrid nanofillers to achieve multifunctionality and the application of electrospinning and 3D printing technologies for cost-effective and large-scale manufacture.
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D. Chung, Carbon Fiber Composites (Butterworth-Heinemann, Waltham, MA, 1994)
S.C. Tjong, Structural and mechanical properties of polymer nanocomposites. Mater. Sci. Eng. R 53, 73–197 (2006)
X.L. Xie, Y.W. Mai, X.P. Zhou, Dispersion and alignment of carbon nanotubes in polymer matrix: a review. Mater. Sci. Eng. R 49, 89–112 (2005)
Y. Tang, L. Ye, Z. Zhang, K. Friedrich, Interlaminar fracture toughness and CAI strength of fibre-reinforced composites with nanoparticles—a review. Compos. Sci. Technol. 86, 26–37 (2013)
R.K. Prusty, D.K. Rathore, B.C. Ray, Assessment and modification strategies for improved interlaminar properties of advanced FRP composites: a review. J Adv. Res. Manufac.Mate. Sci. Metallurg. Eng. 1, 1–25 (2014)
B. Fiedler, F.H. Gojny, M.H.G. Wichmann, M.C.M. Nolte, K. Schulte, Fundamental aspects of nano-reinforced composites. Compos. Sci. Technol. 66, 3115–3125 (2006)
W. Bouhofer, J.Z. Kovacs, A review and analysis of electrical percolation in carbon nanotube polymer composites. Compos. Sci. Technol. 69, 1486 (2009)
H. Qian, E.S. Greenhalgh, M.S.P. Shaffer, A. Bismarck, Carbon nanotube-based hierarchical composites: a review. J. Mater. Chem. 20, 4751–4762 (2010)
T.W. Chou, L. Gao, E.T. Thostenson, Z. Zhang, J.H. Byun, An assessment of the science and technology of carbon nanotube-based fibers and composites. Compos. Sci. Technol. 70, 1–19 (2010)
A.M. Diez-Pascual, M. Naffakh, C. Marco, M.A. Gomez-Fatou, G.J. Ellis, Multiscale fiber-reinforced thermoplastic composites incorporating carbon nanotubes: a review. Curr. Opin. Solid State Mater. Sci. 18, 62–80 (2014)
M. Arai, J. Hirokawa, Y. Hanamura, H. Ito, M. Hojo, M. Quaresimin, Characteristic of mode I fatigue crack propagation of CFRP laminates toughened with interlayer. Compos. Part B 65, 26–33 (2014)
B. Ashrafi, J. Guan, V. Mirjalili, Y. Zhang, L. Chun, P. Hubert, B. Simard, C.T. Kingston, O.~Bourne, A. Johnston, Enhancement of mechanical performance of epoxy/cabob fibre laminate composites using single-walled carbon nanotubes. Compos. Sci. Technol. 71, 1569–1578 (2011)
E. Bekyarova, E.T. Thostenson, A. Yu, H. Kim, J. Gao, J. Tang, H.T. Hahn, T.W. Chou, M.E.~Itkis, R.C. Haddon, Multiscale carbon nanotube carbon fiber reinforcement for advanced epoxy composites. Langmuir 23, 3970–3974 (2007)
E.J. Garcia, B.L. Wardle, A.J. Hart, Joining prepreg composite interfaces with aligned carbon nanotubes. Compos. Part A 39, 1065–1070 (2008)
A. Godara, L. Mezzo, F. Luizi, A. Warrier, S.V. Lomov, A.W. van Vuure, L. Gorbatikh, P.~Moldenaers, I. Verpoest, Influence of carbon nanotube reinforcement on the processing and the mechanical behaviour of carbon fibre/epoxy composites. Carbon 47, 2914–2923 (2009)
L. Gorbatikh, S.V. Lomov, I. Verpoest, Nano-engineered composites: a multiscale approach for adding toughness to fibre reinforced composites. Procedia Eng. 10, 3252–3258 (2011)
S.C. Joshi, V. Dikshit, Enhancing interlaminar fracture characteristics of woven CFRP prepreg composites through CNT dispersion. J. Compos. Mater. 46, 665–675 (2011)
K.L. Kepple, G.P. Sanborn, P.A. Lacasse, K.M. Gruenberg, W.J. Ready, Improved fracture toughness of carbon fiber composite functionalized with multi walled carbon nanotubes. Carbon 46, 2026–2033 (2008)
J.B. Knoll, B.T. Riecken, N. Kosmann, S. Chandrasekaran, K. Schulte, B. Fiedler, The effect of carbon nanoparticles on the fatigue performance of carbon fibre reinforced epoxy. Compos. Part A 67, 233–240 (2014)
S. Rahmanian, K.S. Thean, A.R. Suraya, M.A. Shazed, M.A. Mohd Salleh, H.M. Yusoff, Carbon and glass hierarchical fibers: influence of carbon nanotubes on tensile, flexural and impact properties of short fiber reinforced composites. Mater. Des. 43, 10–16 (2013)
G. Romhany, G. Szebenyi, Interlaminar crack propagation in MWCNT/fiber reinforced hybrid composites. Express Polym. Lett. 3, 145–151 (2009)
R.J. Sager, P.J. Klein, D.C. Davis, D.C. Lagoudas, G.L. Warren, H.J. Sue, Interlaminar fracture toughness of woven fabric composite laminates with carbon nanotube/epoxy interleaf films. J.~Appl. Polym. Sci. 121, 2394–2405 (2011)
Thaker PR. Processing and characterisation of carbon nanotubes reinforced epoxy resin based multi-scale multi-functional composites. Ph.D. Thesis, Texas A&M University, 2009
X. Xu, Z. Zhou, Y. Hei, B. Zhang, J. Bao, X. Chen, Improving compression-after-impact performance of carbon-fiber composites by CNTs/thermoplastic hybrid film interlayer. Compos. Sci. Technol. 95, 75–81 (2014)
T. Yokozeki, Y. Iwahori, M. Ishibashi, T. Yanagisawa, K. Imai, M. Arai, T. Takahashi, K.~Enomoto, Fracture toughness improvement of CFRP laminates by dispersion of cup-stacked carbon nanotubes. Compos. Sci. Technol. 69, 2268–2273 (2009)
G.J. Zhang, The effect of carbon fibres and carbon nanotubes on the mechanical properties of polyimide composites. Mech. Compos. Mater. 47, 447–450 (2011)
H. Zhang, Y. Liu, M. Kuwata, E. Bilotti, T. Peijs, Improved fracture toughness and integrated damage sensing capability by spray coated CNTs on carbon fibre prepreg. Compos. Part A 70, 102–110 (2015)
V. Kostopoulos, P. Tsotra, P. Karapappas, S. Tsantzalis, A. Vavouliotis, T.H. Loutas, A.~Paipetis, K. Friedrich, T. Tanimoto, Model I interlaminar fracture of CNF or/and PZT doped CFRPs via acoustic emission monitoring. Compos. Sci. Technol. 67, 822–828 (2007)
M. Quaresimin, R.J. Varley, Understanding the effect of nano-modifier addition upon the properties of fibre reinforced laminates. Compos. Sci. Technol. 68, 718–726 (2008)
P. Akangah, S. Lingaiah, K. Shivakumar, Effect of Nylon-66 nano-fiber interleaving on impact damage resistance of epoxy/carbon fiber composite laminates. Compos. Struct. 92, 1432–1439 (2010)
V. Kostopoulos, P. Karapappas, T. Loutas, A. Vavouliotis, A. Paioetis, P. Tsotra, Interlaminar fracture toughness of carbon fibre-reinforced polymer laminates with nano- and micro-fillers. Strain 47, e269–e282 (2011)
K. Molnar, E. Kostakova, L. Meszaros, The effect of needleless electrospun nanofibrous interleaves on mechanical properties of carbon fabrics/epoxy laminates. Express Polym. Lett. 8, 62–72 (2014)
M.M. Rahman, M. Hosur, K.T. Hsiao, L. Wallace, S. Jeelani, Low velocity impact properties of carbon nanofibers integrated carbon fiber/epoxy hybrid composites manufactured by OOA-VBO process. Compos. Struct. 120, 32–40 (2015)
Y. Shao, T. Yashiro, K. Okubo, T. Fujii, Effect of cellulose nano fiber (CNF) on fatigue performance of carbon fiber fabric composites. Compos. Part A 76, 244–254 (2015)
J. Zhang, T. Lin, X. Wang, Electrospun nanofiber toughened carbon/epoxy composites: effects of polyetherketone cardo (PEK-C) nanofiber diameter and interlayer thickness. Compos. Sci. Technol. 70, 1660–1666 (2010)
I.S. Chronakis, Novel nanocomposites and nanoceramics based on polymer nanofibers using electrospinning process—a review. J. Mater. Process. Technol. 167, 283–293 (2005)
Y.A. Dzenis, D.H. Reneker, Delamination resistant composites prepared by small diameter fiber reinforcement at ply interfaces. U.S. Patent 6265333, USA, 2001
Y. Fukushima, S. Inagaki, Synthesis of an intercalated compound of montmorillonite and 6-polyamide. J. Incl. Phenom. 5, 473–482 (1987)
O. Becker, R.J. Varley, G.P. Simon, Use of layered silicates to supplementarily toughen high performance epoxy-carbon fiber composites. J. Mater. Sci. Lett. 22, 1411–1414 (2003)
D. Dean, A.M. Obore, S. Richmond, E. Nyairo, Multiscale fibre-reinforced nanocomposites: synthesis, processing and properties. Compos. Sci. Technol. 66, 2135–2142 (2006)
K. Iqbal, S.U. Khan, A. Munir, J.K. Kim, Impact damage resistance of CFRP with nanoclay-filled epoxy matrix. Compos. Sci. Technol. 69, 1949–1957 (2009)
N.A. Siddiqui, R.S.C. Woo, J.K. Kim, C.C.K. Leung, A. Munir, Model I interlaminar fracture behaviour and mechanical properties of CFRPs with nanoclay-filled epoxy matrix. Compos. Part A 38, 449–460 (2007)
J.F. Timmerman, B.S. Hayes, J.C. Seferis, Nanoclay reinforcement effects on the cryogenic microcracking of carbon fiber/epoxy composites. Compos. Sci. Technol. 62, 1249–1258 (2002)
Y. Xu, S.V. Hoa, Mechanical properties of carbon fiber reinforced epoxy/clay nanocomposites. Compos. Sci. Technol. 68, 854–861 (2008)
S. Sprenger, C. Eger, A.J. Kinloch et~al., Nanotoughening of epoxies. Proceedings of Stick! Conference 2003, Nuernberg, Germany, Vincentz Verlag, 9 April 2003
T.H. Hsieh, A.J. Kinloch, K. Masania, J.S. Lee, A.C. Taylor, S. Sprenger, The toughness of epoxy polymers and fibre composites modified with rubber microparticles and silica nanoparticles. J Mater. Sci. 45, 1193–1210 (2010)
S. Sprenger, Fiber-reinforced composites based on epoxy resins modified with elastomers and surface-modified silica nanoparticles. J. Mater. Sci. 49, 2391–2402 (2014)
Y. Tang, L. Ye, D. Zhang, S. Deng, Characterisation of transverse tensile, interlaminar shear and interlaminate fracture in CF/EP laminates with 10 wt% and 20 wt% silica nanoparticles in matrix resins. Compos. Part A 42, 1943–1950 (2011)
Y. Zeng, H.Y. Liu, Y.-W. Mai, X.S. Du, Improving interlaminar fracture toughness of carbon fibre/epoxy laminates by incorporation of nano-particles. Compos. Part B 43, 90–94 (2012)
S. Sprenger, Epoxy resin composites with surface-modified silicon dioxide nanoparticles: a~review. J. Appl. Polym. Sci. 130, 1421–1428 (2013)
C.M. Manjunatha, A.C. Taylor, A.J. Kinloch, S. Sprenger, The effect of rubber micro-particles and silica nano-particles on the tensile fatigue behaviour of a glass-fibre epoxy composite. J.~Mater. Sci. 44, 342–345 (2009)
C. Eger, S. Sprenger, Polymere Epoxidharz-Zusammensetzung. German Patent DE50304047, filing date: 03/12/2003 (2004)
T. Ogasawara, Y. Ishida, T. Kasai, Mechanical properties of carbon fiber/fullerene-dispersed epoxy composites. Compos. Sci. Technol. 69, 2002–2007 (2009)
X. Huang, X. Qi, F. Boey, H. Zhang, Graphene-based composites. Chem. Soc. Rev. 41, 666–686 (2012)
J.R. Potts, D.R. Dreyer, C.W. Bielawski, R.S. Ruoff, Graphene-based polymer nanocomposites. Polymer 52, 5–25 (2011)
P. He, B. Huang, L. Liu, Q. Huang, T. Chen, Preparation of multiscale graphene oxide-carbon fabric and its effect on mechanical properties of hierarchical epoxy resin composite. Polym. Compos. (2014). doi:10.1002/pc.23321
E. Kandare, A.A. Khatibi, S. Yoo, R. Wang, J. Ma, P. Olivier, N. Gleizes, C.H. Wang, Improving the through-thickness thermal and electrical conductivity of carbon fibre/epoxy laminates by exploiting synergy between graphene and silver nano-inclusions. Compos. Part A 69, 72–82 (2015)
E. Mannov, H. Schmutzler, S. Chandrasekaran, C. Viets, S. Buschhorn, F. Tolle, R. Mulhaupt, K. Schulte, Improvement of compressive strength after impact in fibre reinforced polymer composites by matrix modification with thermally reduced graphene oxide. Compos. Sci. Technol. 87, 36–41 (2013)
X. Yang, Z. Wang, M. Xu, R. Zhao, X. Liu, Dramatic mechanical and thermal increments of thermoplastic composites by multi-scale synergetic reinforcement: carbon fiber and graphene nanoplatelet. Mater. Des. 44, 74–80 (2013)
D. Zhang, L. Ye, S. Deng, J. Zhang, Y. Tang, Y. Chen, CF/EP composite laminates with carbon black and copper chloride for improved electrical conductivity and interlaminar fracture toughness. Compos. Sci. Technol. 72, 412–420 (2012)
X. Zhang, X. Fan, C. Yan, H. Li, Y. Zhu, X. Li, L. Yu, Interfacial microstructure and properties of carbon fiber composites modified with graphene oxide. ACS Appl. Mater. Interfaces 4, 1543–1552 (2012)
R.J. Young, I.A. Kinloch, L. Gong, K.S. Novoselov, The mechanics of graphene nanocomposites: a review. Compos. Sci. Technol. 72, 1459–1476 (2012)
Y. Ye, H. Chen, J. Wu, C.M. Chan, Interlaminar properties of carbon fiber composites with halloysite nanotube-toughened epoxy matrix. Compos. Sci. Technol. 71, 717–723 (2011)
A.M. Diez-Pascual, M. Naffakh, Inorganic nanoparticle-modified poly(phenylene sulphide)/carbon fibre laminates: thermomechanical behaviour. Materials 6, 3171–3193 (2013)
H. Qian, A. Bismarck, E.S. Greenhalgh, M.S.P. Shaffer, Carbon nanotube grafted carbon fibres: a study of wetting and fibre fragmentation. Compos. Part A 41, 1107–1114 (2010)
H. Qian, A. Bismarck, E.S. Greenhalgh, M.S.P. Shaffer, Carbon nanotube grafted silica fibres: characterising the interface at the single fibre level. Compos. Sci. Technol. 70, 393–399 (2010)
H.P. Kan, Enhanced reliability prediction methodology for impact damaged composite structures. Report DOT/FAA/AR-97-79, October (1998)
S.A. Hitchen, R.M.J. Kemp, The effects of stacking sequence on impact damage in a carbon fibre/epoxy composite. Composites 26, 207–214 (1995)
E. Fuoss, P.V. Straznicky, C. Poon, Effects of stacking sequence on the impact resistance in composite laminates—Part I: parametric study. Compos. Struct. 41, 67–77 (1998)
D.D.R. Cartie, P.E. Irving, Effect of resin and fibre properties on impact and compression after impact performance of CFRP. Composites: Part A 33, 483–493 (2002)
G.A.O. Davies, X. Zhang, G. Zhou, S. Watson, Numerical modelling of impact damage. Composites 25, 342–350 (1994)
M.O.W. Richardson, M.J. Wishart, Review of low-velocity impact properties of composite materials. Compos. Part A 27A, 1123–1131 (1996)
Z. Hashin, A. Rotem, A fatigue failure criterion for fiber reinforced materials. J. Compos. Mater. 7, 448–456 (1973)
K. Schulte, C.H. Baron, Load and failure analyses of CFRP laminates by means of electrical resistivity measurements. Compos. Sci. Technol. 36, 349–356 (1989)
M.C. Koecher, J.H. Pande, S. Merkley, S. Henderson, D.T. Fullwood, A.E. Bowden, Piezoresistive in-situ stain sensing of composite laminate structures. Compos. Part B 69, 534–541 (2015)
E.T. Thostenson, T.W. Chou, Carbon nanotube networks: sensing of distributed strain and damage for life prediction and self-healing. Adv. Mater. 18, 2837–2841 (1996)
L. Boger, M.H.G. Wichmann, L.O. Meyer, K. Schulte, Load and health monitoring in glass fibre reinforced composites with an electrically conductive nanocomposites epoxy matrix. Compos. Sci. Technol. 68, 1886–1894 (2008)
Y. Lin, M. Gigliotti, M.C. Lafarie-Frenot, J. Bai, D. Marchand, D. Mellier, Experimental study to assess the effect of carbon nanotube addition on the through-thickness electrical conductivity of CFRP laminates for aircraft applications. Compos. Part B 76, 31–37 (2015)
E.F. Reia da Costa, A.A. Skordos, I.K. Partidge, A. Rezai, RTM processing and electrical performance of carbon nanotube modified epoxy/fibre composites. Compos. Part A 43, 593–602 (2012)
S. Hida, T. Hori, T. Shiga, J. Elliott, J. Shiomi, Thermal resistance and phonon scattering at the interface between carbon nanotube and amorphous polyethylene. Int. J. Heat Mass Transf. 67, 1024–1029 (2013)
D.J. Radcliffe, H.M. Rosenberg, The thermal conductivity of glass-fibre and carbon-fibre/epoxy composites from 2 to 80 K. Cryogenics 22(5), 245–249 (1982)
Wikipedia.org. https://en.wikipedia.org/wiki/Rule_of_mixtures. Accessed 9/5/2016
J.R. Gaier, Y. YoderVandenberg, S. Berkebile, H. Stueben, F. Balagadde, The electrical and thermal conductivity of woven pristine and intercalated graphite fibre-polymer composites. Carbon 41, 2187–2193 (2003)
H. Jopek, T. Strek, Optimization of the effective thermal conductivity of a composite, in Convection and Conduction Heat Transfer, ed. by A. Ahsan (Intech, Croatia, 2011), pp. 197–214
G. Gkikas, D.D. Douka, N.M. Barkoula, A.S. Paipetis, Nano-enhanced composite materials under thermal shock and environmental degradation: a durability study. Compos. Part B 70, 206–214 (2015)
A.J. Kinloch, R.D. Mohammed, A.C. Taylor, S. Sprenger, D. Egan, The interlaminar toughness of carbon-fibre reinforced plastic composites using “hybrid-toughened” matrices. J. Mater. Sci. 41, 5043–5046 (2006)
S.A. Xu, G.T. Wang, Y.W. Mai, Effect of hybridization of liquid rubber and nanosilica particles on the morphology, mechanical properties and fracture toughness of epoxy composites. J. Mater. Sci. 48, 3546–3556 (2013)
K.J. Bowles, S. Frimpong, Void effects on the interlaminar shear strength of unidirectional graphite-fibre-reinforced composites. J. Compos. Mater. 26, 1487–1509 (1992)
C.L. Lee, K.H. Wei, Resin transfer molding (RTM) process of a high performance epoxy resin. II: effects of process variables on the physical, static and dynamic mechanical behaviour. Polym. Eng. Sci. 40, 935–943 (2000)
B.G. Compton, J.A. Lewis, 3D printing: 3D-printing of lightweight cellular composites. Adv. Mater. 26, 5930–5935 (2014)
J.R. Tumbleston, D. Shirvanyants et al., Continuous liquid interface production of 3D objects. Science 347, 1349–1352 (2015)
S. Pimenta, S.T. Pinho, Recycling carbon fibre reinforced polymers for structural applications: technology review and market outlook. Waste Manag. 31, 378–392 (2011)
D. Bello, B.L. Wardle, N. Yamamoto, R.G. deVilloria, E.J. Garcia, A.K. Hart, K. Ahn, M.J. Ellenbecker, M. Hallock, Exposure to nanoscale particles and fibers during machining of hybrid advanced composites containing carbon nanotubes. J. Nanopart. Res. 11, 231–249 (2009)
Acknowledgements
Y Tang and L Ye are grateful for the support of the Premier’s Research and Industry Fund (PRIF) with a Catalyst Research Grant and the Australian Research Council (ARC) with a Discovery Project (DP) grant for the research work, respectively.
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Han, W., Tang, Y., Ye, L. (2017). Carbon Fibre-Reinforced Polymer Laminates with Nanofiller-Enhanced Multifunctionality. In: Beaumont, P., Soutis, C., Hodzic, A. (eds) The Structural Integrity of Carbon Fiber Composites. Springer, Cham. https://doi.org/10.1007/978-3-319-46120-5_8
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