Abstract
CuInSe2 semiconductor nanoparticles were synthesized by the hydrothermal method. X-ray diffraction (XRD), scanning electron microscopy (SEM ), transmission electron microscopy (TEM ), FT-Raman , UV-spectroscopy and photoluminescence (PL) spectrum analyses had been done to study of the synthesized samples crystallinity, morphological and optical properties. The chalcopyrite (tetragonal) structure was confirmed by XRD pattern of CuInSe2. The Raman spectrum of the CuInSe2 showed the dominant A1 modes at 176 cm−1. The synthesized samples were composed of cubes which is shown by SEM and TEM analyses with the size of nanometers. The optical property of the synthesized nanoparticles was studied from the photoluminescence spectrum. At different frequencies for different temperatures the dielectric properties of CuInSe2 nanoparticles were studied. CuInSe2 nanoparticles dielectric constant and the dielectric loss decreased with increase in frequency.
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References
Guillemoles, J.F., Kronik, L., Cahen, D., Rau, U., Jasenek, A., Schock, H.W.: Stability issues of Cu (In, Ga) Se2-based solar cells. J. Phys. Chem B. 104, 4849 (2000)
Guillen, C., Herrero, : Improvement of the optical properties of electrodeposited CuInSe2 thin films by thermal and chemical treatments. J. Sol. Energy Mater. Sol. Cells. 43, 47–57 (1996)
Nadenau, V., Braunger, D., Hariskos, D., Kaiser, M., Koble, C., Oberacker, A., Ruckh, M., Ruhle, U., Schaffler, R., Schmid, D., Walter, T., Zweigart, S., Schock, H.W.: Solar cells based on CuInSe2 and related compounds: material and device properties and processing. Progr. Photovolt.: Res. Appl. 3, 363–382 (1995)
Niki, S., Fons, P.J., Yamada, A., Kurafuji, T., Chichibu, S., Nakanishi, H., Bi, W.G., Tu, C.W.: High quality CuInSe2 films grown on pseudo-lattice-matched substrates by molecular beam epitaxy. Appl. 69, 647 (1996)
Zhang, L., Liang, J., Peng, S., Shi, Yunhui, C.: Solvothermal synthesis and optical characterization of chalcopyrite CuInSe2 microspheres. Mater. Chem. Phys. 106, 296–300 (2007)
Grisaru, H., Oleg, P., Gedanken, A.: Microwave-assisted polyol synthesis of CuInTe2 and CuInSe2 nanoparticles. Inorg. Chem. 42, 7148–7155 (2003)
Wei, G., Forrest, S.R.: Intermediate-band solar cells employing quantum dots embedded in an energy fence barrier. Nano Lett. 7, 218–222 (2007)
Shim, J.B., Kim, C.G., Jeon, D.J., Chung, T.M., An, K.S., Lee, S.S., Lim, J.S., Jeong, S.J., Park, B.K. and Lee, Y.K.: Hydrothermal synthesis of CuInSe2 nanoparticles in acetic acid. J. Phys. Chem. Solids. 74, 867–871 (2013)
Lu, W.L., Fu, Y.S., Tseng, B.H.: Preparation and characterization of CuInSe2 nanoparticles. J. Phys. Chem. Solids 69, 637–640 (2008)
Wu, C.H., Chen, F.S., Lin, S.H., Lu, C.H.: Preparation and characterization of CuInSe2 particles via the hydrothermal route for thin-film solar cells. J. Alloys. Compd. 509, 5783–5788 (2011)
Lin, Pei-Ying, Yaw-Shyan, Fu: Fabrication of CuInSe2 light absorption materials from binary precursors via wet chemical process. Mater. Lett. 75, 65–67 (2012)
Lu, Chung-Hsin, Chung-Han, Lee, Chung-Hsien, Wu: Microemulsion-mediated solvothermal Synthesis of copper indium diselenide powders. Sol. Energy Mater. Sol. Cells 94, 1622–1626 (2010)
Yang, Yi-Han, Yit-Tsong, Chen: Solvothermal preparation and spectroscopic characterization of copper indium diselenide nanorods. J. Phys. Chem. B 110, 17370–17374 (2006)
Kim, Ki-Hyun, Young-Gab, Chun, Byung-Ok, Park, Kyung- Hoon, Yoon: Synthesis of CuInSe2 and CuInGaSe2 nanoparticles by solvothermal route. Mater. Sci. Forum 449–452, 273–276 (2004)
Zaretskaya, E.P., Gremenok, V.F., Riede, V., Schmitz, W., Bente, K., Zalesski, V.B., Ermakov, O.V.: Raman spectroscopy of CuInSe2 thin films prepared by selenization. J. Phys. Chem. Solids 64, 1989 (2003)
Chen, H., Yu, S.M., Shin, D.W., Yoo, J.B.: Solvothermal synthesis and characterization of chalcopyrite CuInSe2 nanoparticles. Nanoscale Res. Lett. 5, 217–223 (2010)
Guo, Q., Kim, S.J., Kar, M., Shafarman, W.N., Birkmire, R.W., Stach, E.A., Agrawal, R., Hillhouse, H.W.: Development of CuInSe2 nanocrystal and nanoring inks for low-cost solar cells. Nano Lett. 8, 2982 (2008)
Liborio, L.M., Bailey, C.L., Mallia, G., Tomić, S. and Harrison, N.M.: Chemistry of defect induced photoluminescence in chalcopyrites: the case of CuAlS2. J. Appl. Phys. 109, 023519 (2011)
Suresh, S., Arunseshan, C.: Dielectric properties of cadmium selenide (CdSe) nanoparticles synthesized by solvothermal method. Appl. Nanosci. 4, 179–184 (2014)
Suresh, S.: Studies on the dielectric properties of CdS nanoparticles. Appl Nanosci. 4, 325–329 (2014)
Sagadevan, S.: Synthesis and electrical properties of TiO2 nanoparticles using a wet chemical technique. Am. J. Nanosci. Nanotech. 1(1), 27–30 (2013)
Suresh, S.: Synthesis, structural and dielectric properties of zinc sulfide nanoparticles. Int. J. Phys. Sci. 8, 1121–1127 (2013)
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Sagadevan, S., Podder, J., Das, I. (2017). Synthesis and Characterization of CuInSe2 Nanoparticles by Hydrothermal Method. In: Ebenezar, J. (eds) Recent Trends in Materials Science and Applications. Springer Proceedings in Physics, vol 189. Springer, Cham. https://doi.org/10.1007/978-3-319-44890-9_9
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DOI: https://doi.org/10.1007/978-3-319-44890-9_9
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