Abstract
Aluminium doped zinc oxide (AZO) nano—structured films were deposited by nebulizer spray technique. The role of aluminium dopant concentration over the structural, optical and electrical properties was examined by different analytical techniques. The structural results from X-ray diffraction showed that preferential orientation of films obtained along the (002) direction. The surface morphology of the films showed a hexagonal facet with the nano—structured film. The parameters such as resistivity and activation energy were determined from electrical studies. The sensitivity of the films towards ethanol gas was investigated at room temperature.
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References
Mousavi, S.H., Haratizadeh, H., Minaee, H.: The effect of morphology and doping on photoluminescence of ZnO nanostructures. Opt. Commun. 284, 3558–3561 (2011)
Roy, S., Basu, S.: Improved zinc oxide film for gas sensor applications. Bull. Mater. Sci. 25, 513–515 (2002)
Repins, I., Contreras, M.A., Egaas, B., DeHart, C., Scharf, J., Perkins, C.L., To, B., Noufi, R.: 19.9 %-efficient ZnO/CdS/CuInGaSe2 solar cell with 81.2 % fill factor. Prog. Photovoltaics Res. Appl. 16, 235–239 (2008)
Nayak, P.K., Yang, J., Kim, J., Chung, S., Jeong, J., Lee, C., Hong, Y.: Spin-coated Ga-doped ZnO transparent conducting thin films for organic light-emitting diodes. J. Phys. D Appl. Phys. 42, 035102 (2009)
Xiu, X., Pang, Z., Lv, M., Dai, Y., Ye, L., Han, S.: Transparent conducting molybdenum-doped zinc oxide films deposited by RF magnetron sputtering. Appl. Surf. Sci. 253, 3345–3348 (2007)
Shi, J., Ma, H., Ma, G., Ma, H., Shen, J.: Structure and ultrafast carrier dynamics in n-type transparent Mo:ZnO nanocrystalline thin films. Appl. Phys. A 92, 357–360 (2008)
Gençyılmaz, O., Atay, F., Akyüz, İ.: Ellipsometric investigation of optical parameters and characterization of spray pyrolysis-derived ZnO films. Metall. Mater. Trans. A 46, 4247–4254 (2015)
Lucio-López, M.A., Luna-Arias, M.A., Maldonado, A., de la L. Olvera, M., Acosta, D.R.: Preparation of conducting and transparent indium-doped ZnO thin films by chemical spray. Sol. Energy Mater. Sol. Cells 90, 733–741 (2006)
Sukkar, M., Tuller, H.: Defect equilibria in ZnO varistor materials. In: Additives and Interfaces in Electronic Ceramics. Proceedings of the Special Conference held at Cincinnati 4–5 May 1982. Advances in Ceramics, p. 71 (1982)
Jeong, S.H., Park, B.N., Lee, S.B., Boo, J.H.: Structural and optical properties of silver-doped zinc oxide sputtered films. Surf. Coat. Technol. 193, 340–344 (2005)
Caglar, M., Ilican, S., Caglar, Y., Yakuphanoglu, F.: The effects of Al doping on the optical constants of ZnO thin films prepared by spray pyrolysis method. J. Mater. Sci. Mater. Electron. 19, 704–708 (2008)
Islam, M.N., Ghosh, T.B., Chopra, K.L., Acharya, H.N.: XPS and X-ray diffraction studies of aluminum-doped zinc oxide transparent conducting films. Thin Solid Films 280, 20–25 (1996)
Manouni, A.E., ManjĂłn, F.J., Mollar, M., MarĂ, B., GĂłmez, R., LĂłpez, M.C., Ramos-Barrado, J.R.: Effect of aluminium doping on zinc oxide thin films grown by spray pyrolysis. Superlattices Microstruct. 39, 185–192 (2006)
Bao, D., Gu, H., Kuang, A.: Sol-gel-derived c-axis oriented ZnO thin films. Thin Solid Films 312, 37–39 (1998)
Sahay, P.P., Nath, R.K.: Al-doped zinc oxide thin films for liquid petroleum gas (LPG) sensors. Sens. Actuators B Chem. 133, 222–227 (2008)
Fang, G., Li, D., Yao, B.-L.: Fabrication and characterization of transparent conductive ZnO: Al thin films prepared by direct current magnetron sputtering with highly conductive ZnO(ZnAl2O4) ceramic target. J. Cryst. Growth 247, 393–400 (2003)
Allah, F.K., AbĂ©, S.Y., Núñez, C.M., Khelil, A., Cattin, L., Morsli, M., Bernède, J.C., Bougrine, A., del Valle, M.A., DĂaz, F.R.: Characterisation of porous doped ZnO thin films deposited by spray pyrolysis technique. Appl. Surf. Sci. 253, 9241–9247 (2007)
Lokhande, B.J., Patil, P.S., Uplane, M.D.: Deposition of highly oriented ZnO films by spray pyrolysis and their structural, optical and electrical characterization. Mater. Lett. 57, 573–579 (2002)
Zhou, H.-M., Yi, D.-Q., Yu, Z.-M., Xiao, L.-R., Li, J.: Preparation of aluminum doped zinc oxide films and the study of their microstructure, electrical and optical properties. Thin Solid Films 515, 6909–6914 (2007)
Gómez-Pozos, H., Maldonado, A., Olvera, M.D.l.L.: Effect of the [Al/Zn] ratio in the starting solution and deposition temperature on the physical properties of sprayed ZnO:Al thin films. Mater. Lett. 61, 1460–1464 (2007)
Ilican, S., Caglar, Y., Caglar, M., Yakuphanoglu, F.: Electrical conductivity, optical and structural properties of indium-doped ZnO nanofiber thin film deposited by spray pyrolysis method. Phys. E 35, 131–138 (2006)
Tewari, S., Bhattacharjee, A.: Structural, electrical and optical studies on spray-deposited aluminium-doped ZnO thin films. Pramana 76, 153–163 (2011)
Aktaruzzaman, A.F., Sharma, G.L., Malhotra, L.K.: Electrical, optical and annealing characteristics of ZnO: Al films prepared by spray pyrolysis. Thin Solid Films 198, 67–74 (1991)
Joseph, B., Manoj, P.K., Vaidyan, V.K.: Studies on the structural, electrical and optical properties of Al-doped ZnO thin films prepared by chemical spray deposition. Ceram. Int. 32, 487–493 (2006)
Tarasov, K., Raccurt, O.: A wet chemical preparation of transparent conducting thin films of Al-doped ZnO nanoparticles. J. Nanopart. Res. 13, 6717–6724 (2011)
Ravichandran, K., Anbazhagan, A., Dineshbabu, N., Ravidhas, C.: Influence of Mo doping on transparent conducting properties of ZnO films prepared by a simplified spray technique. J. Mater. Sci. Mater. Electron. 26, 7649–7654 (2015)
Shukla, R.K., Srivastava, A., Srivastava, A., Dubey, K.C.: Growth of transparent conducting nanocrystalline Al doped ZnO thin films by pulsed laser deposition. J. Cryst. Growth 294, 427–431 (2006)
Cui, L., Zhang, H.-Y., Wang, G.-G., Yang, F.-X., Kuang, X.-P., Sun, R., Han, J.-C.: Effect of annealing temperature and annealing atmosphere on the structure and optical properties of ZnO thin films on sapphire (0001) substrates by magnetron sputtering. Appl. Surf. Sci. 258, 2479–2485 (2012)
Willander, M., Nur, O., Sadaf, J.R., Qadir, M.I., Zaman, S., Zainelabdin, A., Bano, N., Hussain, I.: Luminescence from zinc oxide nanostructures and polymers and their hybrid devices. Materials 3, 2643–2667 (2010)
Sha, Z.D., Wang, J., Chen, Z.C., Chen, A.J., Zhou, Z.Y., Wu, X.M., Zhuge, L.J.: Initial study on the structure and optical properties of ZnO film on Si(1011) substrate with a SiC buffer layer. Phys. E 33, 263–267 (2006)
Jeong, S.-H., Kim, B.-S., Lee, B.-T.: Photoluminescence dependence of ZnO films grown on Si(100) by radio-frequency magnetron sputtering on the growth ambient. Appl. Phys. Lett. 82, 2625–2627 (2003)
Jin, B.J., Im, S., Lee, S.Y.: Violet and UV luminescence emitted from ZnO thin films grown on sapphire by pulsed laser deposition. Thin Solid Films 366, 107–110 (2000)
Kumar, B., Gong, H., Chow, S.Y., Tripathy, S., Hua, Y.: Photoluminescence and multiphonon resonant Raman scattering in low-temperature grown ZnO nanostructures. Appl. Phys. Lett. 89, 071922 (2006)
Yadav, R.S., Mishra, P., Pandey, A.C.: Growth mechanism and optical property of ZnO nanoparticles synthesized by sonochemical method. Ultrason. Sonochem. 15, 863–868 (2008)
Børseth, T.M., Svensson, B.G., Kuznetsov, A.Y., Klason, P., Zhao, Q.X., Willander, M.: Identification of oxygen and zinc vacancy optical signals in ZnO. Appl. Phys. Lett. 89, 262112 (2006)
Li, L.M., Du, Z.F., Wang, T.H.: Enhanced sensing properties of defect-controlled ZnO nanotetrapods arising from aluminum doping. Sens. Actuators B Chem. 147, 165–169 (2010)
Nagase, T., Ooie, T., Makita, Y., Nakatsuka, M., Shinozaki, K., Mizutani, N.: A novel method for the preparation of green photoluminescent undoped zinc oxide film involving excimer laser irradiation of a sol-gel-derived precursor. Jpn. J. Appl. Phys. 39, L713 (2000)
Vanheusden, K., Warren, W.L., Seager, C.H., Tallant, D.R., Voigt, J.A., Gnade, B.E.: Mechanisms behind green photoluminescence in ZnO phosphor powders. J. Appl. Phys. 79, 7983–7990 (1996)
Gurlo, A., Ivanovskaya, M., Bârsan, N., Schweizer-Berberich, M., Weimar, U., Göpel, W., Diéguez, A.: Grain size control in nanocrystalline In2O3 semiconductor gas sensors. Sens. Actuators B Chem. 44, 327–333 (1997)
Acknowledgement
This work was financially supported by the University Grants Commission, New Delhi, India [F.no.42-903/2013(SR)] under Major Research Project Scheme (MRP) and Rajiv Gandhi National Fellowship (F1-17.1/2011-12/RGNF-SC-TAM-4843). The authors would like to record their sincere thanks to the commission.
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Ravi Dhas, C. et al. (2017). Structural, Optical and Ethanol Gas Sensing Performance of Aluminium Doped Zinc Oxide (AZO) Thin Films by Nebulizer Spray Technique. In: Ebenezar, J. (eds) Recent Trends in Materials Science and Applications. Springer Proceedings in Physics, vol 189. Springer, Cham. https://doi.org/10.1007/978-3-319-44890-9_33
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DOI: https://doi.org/10.1007/978-3-319-44890-9_33
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