Abstract
Inadequate prediction of acid rock drainage (ARD) can result in the reputational damage of mine operators, the spending of significant costs for post-closure management and lasting impacts to ecosystems. Instead, accurate prediction of ARD will allow a reduction of environmental risks and associated financial liabilities. At present, the mining industry use a range of static and kinetic chemical tests to measure the balance between the acid generating and acid neutralizing potentials of mine waste materials. The resulting data are used to prepare risk assessments and design waste classification schemes. However, associated with these established tests and practices are several shortcomings including: inadequate sampling; performance of a limited number of tests; late initiation of kinetic trials; classification using restricted waste classification categories; and no consideration given to biological and physical parameters that can influence ARD formation. Therefore, current practices only provide a broad indication of ARD potential over time. Fundamentally, ARD is a multifaceted process controlled by several variables, and therefore new tests and protocols developed in this area must reflect this.
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References
Al TA, Blowes DW, Martin CJ, Cabri LJ, Jambor JL (2007) Aqueous geochemistry and analysis of pyrite surfaces in sulphide-rich mine tailings. Geochim Cosmochim Acta 61:2353–2366
Andrina J, Wilson GW, Miller S, Neale A (2006) Performance of the acid rock drainage mitigation waste rock trial dump at Grasberg mine. In: Proceedings from the 7th international conference on acid rock drainage, pp 30–44
Bezaazoua B, Bussieré B, Dagenais AM, Archambault M (2004) Kinetic tests comparison and interpretation for prediction of the Joutel tailings acid generation potential. Environ Geol 46:1086–1101
Blowes DW, Jambor JL (1990) The pore-water geochemistry and the mineralogy of the vadose zone of sulphide tailings, Waite Amulet, Quebec, Canada. Appl Geochem 5:327–346
Borden RK (2003) Environmental geochemistry of the Bingham Canyon porphyry copper deposit, Utah. Environ Geol 43:752–758
Comarmond J (1997) Chemical methods for predicting the acid mine drainage/acid rock drainage potential of mine wastes in Australia. Environmental division, ANSTO. http://www.environment.gov.au/ssd/publications/ssr/pubs/ssr125-appendices.pdf
Cook NJ, Ciobanu CL, Pring A, Skinner W, Danyushevsky L, Shimizu M, Saini-Eidukat B, Melcher F (2009) Trace and minor elements in sphalerite: a LA-ICP-MS study. Geochim Cosmochim Acta 73:4761–4791
Diehl SF, Koenig AE, Hageman PL, Smith KS, Fey DL, Lowers HA (2007) From the micro to the macroscale: a textural and chemical perspective of characterising waste-rock material. In: Proceedings from the 2007 society for mining, metallurgy and exploration (SME) annual meeting and exhibit, and the 109th national western mining conference, Denver, Colorado. Society for Mining, Metallurgy and Exploration, Littleton, pp 7–21
Dobos SK (2000) Potential problems with geologically uncontrolled sampling and the interpretation of chemical tests for waste characterisation and ARD prediction. In: Proceedings from the 4th Australian ARD workshop on acid and metalliferous mine drainage. Australian Centre for Minerals Extension and Research, Brisbane, pp 25–29
Downing BW, Giroux G (1993) Estimation of a waste rock ARD block model for the Windy Craggy massive sulphide deposit, northwestern British Columbia. Explor Min Geol 2:203–215
Downing BW, Madeisky HE (1997) Lithogeochemical methods for acid rock drainage studies and prediction. Explor Min Geol 6:367–379
Du Bray EA (1995) Preliminary compilation of descriptive geoenvironmental mineral deposit models. United States Geological Survey, Open-file Report, pp 95–831
Ficklin WH, Plumlee GS, Smith KS, McHugh JB (1992) Geochemical classification of mine drainages and natural drainages in mineralized areas. In: Proceedings from the 7th international water-rock interaction conference. Park City, Utah, pp 381–384
GARD (Global Acid Rock Drainage) Guide (2016) The international network for acid prevention (INAP). http://www.gardguide.com/
Hakkou R, Bezaazoua M, Bussiere B (2009) Laboratory evaluation of the use of alkaline phosphate wastes for the control of acidic mine drainage. Mine Water Environ 28:206–218
Hughes J, Craw D, Peake B, Lindsay P, Weber P (2007) Environmental characterisation of coal mine waste rock in the field: an example from New Zealand. Environ Geol 52:1501–1509
Hutt NM, Morin KA (2000) Observations and lessons from the International Static Database (ISD) on neutralizing capacity. In: Proceedings from the 5th international conference on acid rock drainage, vol 1. Society for Mining, Metallurgy and Exploration, Littleton, pp 603–611
Jambor JL (2003) Mine-waste mineralogy and mineralogical perspectives of acid-base accounting. In: Jambor JL, Blowes DW, Ritchie AIM (eds) Environmental aspects of mine wastes. Mineralogical Association of Canada, Short Course Series 31, pp 117–145
Jambor JL, Dutrizac JE, Groat L, Raudsepp M (2002) Static tests of neutralization potentials of silicate and aluminosilicate minerals. Environ Geol 43:1–17
Jambor JL, Dutrizac JE, Raudsepp M (2006) Comparison of measured and mineralogically predicted values of the Sobek Neutralization Potential for intrusive rocks. In: Proceedings from the 7th international conference on acid rock drainage, pp 820–832
Jambor JL, Dutrizac JE, Raudsepp M (2007) Measured and computed neutralization potentials from static tests of diverse rock types. Environ Geol 52:1019–1031
Jamieson HE, Robinson C, Alpers CN, Nordstrom DK, Poustovetov A, Lowers HA (2005) The composition of coexisting jarosite-group minerals and water from the Richmond mine, Iron Mountain, California. USGS Published Research 475. http://digitalcommons.unl.edu/usgsstaffpub/475
Johnson DB, Hallburg KB (2005) Acid mine drainage, remediation options. Sci Total Environ 338:3–14
Kwong YTJ (1993) Prediction and prevention of acid rock drainage from a geological and mineralogical perspective. MEND report 1.32.1, Ottawa, Ontario
Lapakko KA (2002) Metal mine rock and waste characterization tools: an overview. Posted on the acid drainage initiative—Metal Mining Sector. www.mackay.unr.edu/adti
Lawrence RW, Scheske M (1997) A method to calculate the neutralization potential of mining wastes. Environ Geol 32:100–106
Lengke MF, Davis A, Bucknam C (2010) Improving management of potentially acid generating waste rock. Mine Water Environ 29:29–44
McLemore V, Heizler L, Donahue K, Dunbar N (2009) Characterization of weathering of mine rock piles: example from the Questa Mine, New Mexico, USA. In: Proceedings from the 8th international conference on acid rock drainage, Skelleftea, pp 1–10
Miller S, Jeffery J (1995) Advances in the prediction of acid generating mine waste materials. In: Proceedings from the 2nd Australian ARD workshop on acid and metalliferous mine drainage. Australian Centre for Minerals Extension and Research, Brisbane, pp 33–43
Miller SD (1996) Advances in acid mine drainage prediction and implications for risk management. In: Proceedings of the 3rd international and 21st annual minerals council of Australia, vol 1, Environmental Workshop, pp 14–18
Miller SD, Robertson A, Donahue T (1997) Advances in acid drainage prediction using the Net Acid Generation (NAG) test. In: Proceedings from the 4th international conference on acid rock drainage, Vancouver, pp 533–549
Miller SD, Stewart W, Rusdinar Y, Schumann R, Ciccarelli JM, Li J, Smart R (2010) Methods for estimation of long-term non-carbonate neutralization of acid rock drainage. Sci Total Environ 408:2129–2135
Mills C, Robertson A, Shaw S (2015) Acid rock drainage at Enviromine. http://technology.infomine.com/enviromine/ard/home.htm
Morin KA, Hutt NM (1998) Kinetic test and risk assessment for ARD. In: Proceedings of the 5th annual BC metal leaching and ARD workshop, Vancouver, pp 1–10
Morin KA, Hutt NM (1999) Internet case study #15: prediction of minesite-drainage chemistry using the “wheel“ approach. http://www.mdag.com/case_studies/cs11-99.html
Morin KA, Hutt NM (2009) Internet case study #32: on the nonsense of arguing the superiority of an analytical method for neutralization potential. www.mdag.com/case_studies/cs32.html
Müller G, Gastner M (1971) The Karbonate-Bombe, a simple device for determination of the calcium carbonate content in sediments, soils and other minerals. N Jb Miner Mh 10:466–469
Nesbitt HW, Jambor JL (1998) Role of mafic minerals in neutralizing ARD, demonstrated using a chemical weathering methology. In: Cabri LJ, Vaughan DJ (eds) Short course handbook on ore and environmental mineralogy. Mineralogical Association of Canada 27, pp 403–421
Ohlander B, Müller B, Axelsson M, Alakangas L (2007) An attempt to use LA-ICP-SMS to quantify enrichment of trace elements on pyrite surfaces in oxidizing mine tailings. J Geochem Explor 92:1–12
Paktunc AD (1999) Mineralogical constraints on the determination of neutralising potential and prediction of acid mine drainage. Environ Geol 39:103–112
Paktunc AD (2001) MODAN a computer program for estimating mineral quantities based on bulk composition, Windows version. Comput Geosci 28:883–886
Parbhakar-Fox A, Lottermoser BG (2015) A critical review of acid rock drainage processes and practices. Min Eng 82:107–124
Parbhakar-Fox A, Edraki M, Walters S, Bradshaw D (2011) Development of a textural index for the prediction of acid rock drainage. Min Eng 24:1277–1287
Parbhakar-Fox A, Lottermoser BG, Bradshaw D (2013) Evaluating waste rock mineralogy and microtexture during kinetic testing for improved acid rock drainage prediction. Min Eng 52:111–124
Plumlee GS (1999) The environmental geology of mineral deposits. In: Plumlee GS, Logsdon MJ (eds) The environmental geochemistry of mineral deposits part A: processes, techniques and health issues. Rev Econ Geol 6A:71–116
Price WA (2009) Prediction manual for drainage chemistry from sulphidic geologic materials. CANMET Mining and Mineral Sciences Laboratories, Canada
Raudsepp M, Pani E (2003) Application of Rietveld analysis to environmental mineralogy. Mineralogical Association of Canada, Short Course 3, pp 165–180
Savage KS, Stefan D, Lehner S (2008) Impurities and heterogeneity in pyrite: influences on electrical properties and oxidation products. Appl Geochem 23:103–120
Seal II RR, Foley NK, Wanty RB (2002) Introduction to geoenvironmental models of mineral deposits. In: Seal II RR, Foley NK (eds) Progress on geoenvironmental models for selected mineral deposit types, US Geological Survey Open-File Report 02-195
Smart R, Skinner WM, Levay G, Gerson AR, Thomas JE, Sobieraj H, Schumann R, Weisener CG, Weber PA, Miller SD, Stewart WA (2002) ARD test handbook: project P387A, prediction and kinetic control of acid mine drainage. AMIRA International Ltd., Melbourne
Smith LJ, Neuner M, Gupton M, Moore M, Bailey BL, Blowes DW, Smith L, Sego DC (2009) Diavik waste rock project: from the laboratory to the Canadian arctic. In: Securing the future and 8th ICARD: proceedings of the conference, Skellefteå, Sweden, pp 40–50
Stewart W (2004) Development of acid rock drainage prediction methodologies for coal mine wastes. PhD. thesis, University of South Australia, Adelaide
Stewart WA, Miller SD, Smart R (2006) Advances in acid rock drainage (ARD) characterisation of mine wastes. In: Proceedings from the 7th international conference on acid rock drainage, Missouri, pp 2098–2119
United States Environmental Protection Agency (2003) Nationwide identification of hardrock mining sites. Report 2004-P-00005
Verplank PL, Van Gosen BS, Seal RR, McCafferty AE (2014) A deposit model for carbonatite and peralkaline intrusion-related rare earth element deposits. U.S. Geological Survey Scientific Investigations Report 2010-5070-J
Weber PA, Hughes JB, Conner, LB, Lindsay P, Smart R.St.C (2006) Short-term acid rock drainage characteristics determined by paste pH and kinetic NAG testing. In: 7th International Conference on Acid Rock Drainage (ICARD), St. Louis, North America, Cypress prospect, New Zealand, pp 2289–2310
Weber PA, Thomas JE, Skinner WM, Smart St RC (2004) Improved acid neutralisation capacity assessment of iron carbonates by titration and theoretical calculation. Appl Geochem 19:687–694
Weber PA, Thomas JE, Skinner WM, Smart St RC (2005) A method to determine the acid-neutralisation capacity of rock samples. Can Mineral 43:1183–1192
Weisener CG, Weber PA (2010) Preferential oxidation of pyrite as a function of morphology and relict texture. NZ J Geol Geophys 53:22–33
White WW, Lapakko KA, Cox RL (1999) Static test methods most commonly used to predict acid mine drainage: practical guidelines for use and interpretation. In: Plumlee GS, Logsdon MJ (eds) The environmental geochemistry of mineral deposits part A: processes, techniques, and health issues. Rev Econ Geol 6A:325–338
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Parbhakar-Fox, A., Lottermoser, B. (2017). Prediction of Sulfidic Waste Characteristics. In: Lottermoser, B. (eds) Environmental Indicators in Metal Mining. Springer, Cham. https://doi.org/10.1007/978-3-319-42731-7_3
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