Skip to main content

Viscoelastic Relaxation of HEMA-DMAEMA Responsive Hydrogels

  • Conference paper
  • First Online:
Experimental and Applied Mechanics, Volume 4

Abstract

Responsive hydrogels are a class of shape memory materials that undergo a large elastic volumetric change when interacting with a stimulus and can return to their original shape when that stimulus is removed. Important to their use in these device applications are the fundamental mechanical properties of these materials. The pH-sensitive 2-hydroxyethyl methacrylate, 2-(dimethylamino) ethyl metha-crylate (HEMA-DMAEMA) hydrogel is a linear-viscoelastic polymer that is used in microfluidics because it can be easily polymerized within these devices and their special stimuli responsive capabilities making them ideal candidates for sensors and actuators. In the experiments described in this paper the stress relaxation due to a step strain is studied. The rise time for our experiments was 0.3 s and the step-strains ranged from 3 to 7 % strain. Relaxation was recorded over three decades of time (1, 10, 100 and 1000 s). It was found that within this range the HEMA-DMAEMA hydrogel displayed linear-viscoelastic behavior.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 129.00
Price excludes VAT (USA)
  • Available as EPUB and PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD 169.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info
Hardcover Book
USD 169.99
Price excludes VAT (USA)
  • Durable hardcover edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

References

  1. Beebe, D.J., Mensing, G.A., Walker, G.M.: Physics and applications of microfluidics in biology. Ann. Rev. Biomed. Eng. 4 (1), 261–286 (2002)

    Article  Google Scholar 

  2. Oh, K.W., Ahn, C.H.: A review of microvalves. J. Micromech. Microeng. 16 (5), R13 (2006)

    Article  Google Scholar 

  3. Gravesen, P., Branebjerg, J., Jensen, O.S.: Microfluidics-a review. J. Micromech. Microeng. 3 (4), 168 (1993)

    Article  Google Scholar 

  4. Shoji, S., Esashi, M.: Microflow devices and systems. J. Micromech. Microeng. 4 (4), 157 (1994)

    Article  Google Scholar 

  5. Elwenspoek, M., Lammerink, T.S.J., Miyake, R., Fluitman, J.H.J.: Towards integrated microliquid handling systems. J. Micromech. Microeng. 4 (4), 227 (1994)

    Article  Google Scholar 

  6. Benjamin, C.C., Springmann, J.C., Chindhy, S.A., Crone, W.C.: Characterization of the interfacial adhesion for responsive hydrogels on substrates. In: Conference Proceeding: American Physical Society (APS), vol. 57 (2012)

    Google Scholar 

  7. Lakes, R.S.: Viscoelastic Materials. Cambridge University Press, Cambridge (2009)

    Book  MATH  Google Scholar 

  8. Ferry, J.D.: Viscoelastic properties of polymers. Wiley, New York (1980)

    Google Scholar 

  9. Johnson, B.D., Bauer, J.M., Niedermaier D.J., Crone, W.C., Beebe, D.J.: Experimental techniques for mechanical characterization of hydrogels at the microscale. Exp. Mech. 44 (1), 21–28 (2004)

    Article  Google Scholar 

  10. ASTM Standard: D638: Standard test method for tensile properties of plastics. ASTM International, West Conshohocken (2010)

    Google Scholar 

  11. Instron Corporation: Instron operator’s guide. Technical Report, Instron Corporation (1997)

    Google Scholar 

  12. Lakes, R.S.: Viscoelastic measurement techniques. Rev. Sci. instrum. 75 (4), 797–810 (2004)

    Article  Google Scholar 

  13. Larraz, E., Elvira, C., Román, J.S.: Design and properties of novel self-curing acrylic formulations for application in intervertebral disks restoration. Biomacromolecules 6 (4), 2058–2066 (2005)

    Article  Google Scholar 

  14. Brazel, C.S., Peppas, N.A.: Dimensionless analysis of swelling of hydrophilic glassy polymers with subsequent drug release from relaxing structures. Biomaterials 20 (8), 721–732 (1999)

    Article  Google Scholar 

Download references

Acknowledgements

This research was supported with funds from the Graduate Engineering Research Scholars Program (CCB) and a Vilas Life Cycle Professorship from the University of Wisconsin-Madison, as well as the National Science Foundation Graduate Research Fellowship Program (CCB).

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Wendy C. Crone .

Editor information

Editors and Affiliations

Rights and permissions

Reprints and permissions

Copyright information

© 2017 The Society for Experimental Mechanics, Inc.

About this paper

Cite this paper

Benjamin, C.C., Lakes, R.S., Crone, W.C. (2017). Viscoelastic Relaxation of HEMA-DMAEMA Responsive Hydrogels. In: Zhu, Y., Zehnder, A. (eds) Experimental and Applied Mechanics, Volume 4. Conference Proceedings of the Society for Experimental Mechanics Series. Springer, Cham. https://doi.org/10.1007/978-3-319-42028-8_18

Download citation

  • DOI: https://doi.org/10.1007/978-3-319-42028-8_18

  • Published:

  • Publisher Name: Springer, Cham

  • Print ISBN: 978-3-319-42027-1

  • Online ISBN: 978-3-319-42028-8

  • eBook Packages: EngineeringEngineering (R0)

Publish with us

Policies and ethics