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CO2 Adsorption on Unsupported and Graphene Oxide Supported Layered Double Hydroxides in a Fixed-Bed

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Supported Layered Double Hydroxides as CO2 Adsorbents for Sorption-enhanced H2 Production

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Abstract

This chapter addresses the CO2 adsorption kinetics and equilibria of LDH and LDH/GO hybrids under dry and wet conditions using breakthrough curve responses obtained in a fixed-bed column. A comparative study between temperature-swing and isothermal N2 purge experiments is presented. In addition, a mathematical model based on the linear driving force approximation is used to describe the dry experiment profiles.

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Notes

  1. 1.

    First-contact refers to the first exposure to the adsorptive gas after activation.

  2. 2.

    The procedure to synthesise the adsorbents and their physicochemical properties are given in Chaps. 5 and 6.

  3. 3.

    The optimal estimated value of kLDF was found with the gPROMS in-built parameter estimation facility based on a Maximum Likelihood formulation. The 95 % t-value was ≫ 95 % reference t-value in all cases. In addition, the confidence intervals were ≪ respective estimated parameter value.

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Authors and Affiliations

  1. Department of Chemical Engineering, Imperial College London, London, UK

    Diana Iruretagoyena Ferrer

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  1. Diana Iruretagoyena Ferrer
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Correspondence to Diana Iruretagoyena Ferrer .

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Iruretagoyena Ferrer, D. (2016). CO2 Adsorption on Unsupported and Graphene Oxide Supported Layered Double Hydroxides in a Fixed-Bed. In: Supported Layered Double Hydroxides as CO2 Adsorbents for Sorption-enhanced H2 Production. Springer Theses. Springer, Cham. https://doi.org/10.1007/978-3-319-41276-4_7

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  • DOI: https://doi.org/10.1007/978-3-319-41276-4_7

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  • Publisher Name: Springer, Cham

  • Print ISBN: 978-3-319-41275-7

  • Online ISBN: 978-3-319-41276-4

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