Abstract
Basic chemical and physical properties of the components and phases in B-Fe and B-C-Fe systems are analyzed and the conditions of their existence and formation during the process of boriding of iron and its smelts are studied. Different types of iron borides (Fe3B, Fe2B, FeB, FeB2), their crystall lattices, concentration and temperature formation conditions are thoroughly investigated. The chapter also provides the values of hardness and chemical properties which form the exploitation characteristics of boronized layers.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
References
Osmond F. On the Critical Points of Iron and Steel // J. Iron Steel Inst. 1890. V. 37. I. P. 38–80.
Arnold J.O. The Physical Influence of Elements on Iron // J. Iron Steel Inst. 1894. V. 45. I. P. 107–155.
Moissan H. et Charpy G. Sur l‘acier au bore // Compt. Rend. Acad. Sci. Paris. 1895. V. 120. P. 130–132.
Guillet L. Boron Steels // J. Iron Steel Inst. 1907. V. 74. II. P. 207– 218.
Bolkhovitinov N.F. Metallovedeniye i termicheskaya obrabotka / Uchebnik dlya vuzov. Moscow, 1958. 431 p. [Physical Metallurgy and Thermal Processing]
Kershenbaum V.Ya., Prusakov B.A., ed. Mnogoyaychnyi tolkovyi slovar’ ‘Metally’. Moscow, 1999. 710 p. [Multi-language explanatory dictionary ‘Metals’]
Glaser F.W. // Journ. Metals. 1952. V. 4, № 4. P. 391.
Tschischewsky N. The Case-Hardening of Iron by boron // J. Iron Steel Inst. 1917. V. 95. P. 185–187.
Thomas W.R. and Leak G.M. Condition of Boron in Alpha Iron // Nature. 1955. July 2. V. 176, № 4470. P. 29–31.
Campbell T.P., and Fay H. The Case-Hardening of Steel by Boron and Nitrogen. //Ind. Eng. Chem. 1924. V. 6. P. 719–723.
Busby P.E., Warga M.E., and C. Wells. Diffusion and Solubility of Boron in Iron and Steel // J. Met. 1953. November. P. 1463–1468.
Busby P.E., and C. Wells. Diffusion of Boron in Alpha Iron // Trans. Am. Inst. Mining Met. Engrs. 1954. V. 200. P. 972
Digges T.G., Irish C.R., and Carwill N.L. Effect of Boron on the Hardenability of High-Purity Alloys and Commercial Steels // Bureau of Standards / J. Research. 1948. V. 41. P. 545–574.
McBride C.C., Spretnak J.E., and Speiser R. A study of the Fe-Fe2B System // Trans. Am. Soc. Metals. 1954. V. 46. P. 499–524.
Krishtal M.A. et al. Vnutrennee trenie v metallah i splavah. Moscow, 1964. 245 p. [Internal Friction in Metals and Alloys].
Krishtal M.A., Turkeltaub G.M. Mikrostruktura splavov zhelezo-bor // Metallovedeniye i termicheskaya obrabotka. 1967. №8. Pp. 63-64 [Mictrostructure of iron-boron smelts]
Voroshnin L.G., Lyakhovich L.S., Panich G.G., Protasevich G.F. Struktura splavov sistemy Fe-B // Metallovedeniye i termicheskaya obrabotka metallov. 1970. №9. Pp. 14-17 [The Structure of Fe-B system’s smelts]
Samsonov G.V. Tugoplavkiye soedineniya. Moscow, 1963. 397 p. [High-melting point compounds]
Portnoy K.I. Boridy // Bolshaya Sovetskaya Entcyklopediya. Moscow, 1970. Vol. 3. P. 567. [Borides].
Samsonov G.V., Vinitckiy I.M. Tugoplaviye soedineniya. Moscow, 1976. 559 p. [High-melting point compounds].
Hayashi Y. and Sugeno T. Nature of Boron in α-Iron // Acta Metallurgica. 1970. June. V. 18. P. 693–697.
Vol A.E. Bor-zhelezo (B-Fe) // Stroeniye i svoistva dvoinyh metallicheskix system. Moscow, 1959. Vol. 1. Pp. 679-686. [Boron-Iron (B-Fe)].
Goldhoff R.M. and Spretnak J.W. Distribution of Boron in Gamma Iron Grains // J. Met. 1957. October. P. 1278–1283.
Kiessling R., Liu Y.H. // Journ. Metals. 1951. V. 3. № 8. P. 639.
Samsonov G.V., Serebryakova T.I., Neronov V.A. Boridy. Moscow, 1975. 375 p. [Borides].
Gulyaev A.P. Metallovedeniye. Moscow, 1986. 544 p [Physical Metallurgy].
Matyushenko N.N. Kristallicheskiye struktury dvoinyh soedineniy. Moscow, 1969. 302 p. [Crystal structures of binary compounds]
Fichtl W.J.G. // Heat Treat. Met. 1983. P. 79–80.
Koifman I.S. et al. Rentgenograficheskii analiz borotsementita. // Metallovedeniye i termicheskaya obrabotka. 1969. №2. P. 59-60. [X-ray analysis of boron-cementite].
Lyakishev N.P., ed. Diagramy sostoyaniya dvoinyh metallicheskih system. Moscow, 1996. Vol. 1. Pp. 442-444 [Equilibrium diagrams of binary metallic systems].
Khan Y., Kneller E., Sostarich M. // Z. Metallkunde. 1981. Bd. 72, № 8. S. 553–557.
Khan Y., Kneller E., Sostarich M. // Z. Metallkunde. 1982. Bd. 73, № 10. S. 624–626.
Voroshnin L.G., Lyakhovich L.S. Borirovaniye stali. Moscow, 1978. 239 p. [The Boriding of Steel].
Kiessling R. // Acta chem. scand. 1950. 4. № 2. P. 209–227. 26
Hendricks S.B., und Kosting P.R. // Zeitshr. Kristallogr. 1930. 74. S. 511–545.
Aronson B., Lundstrom T., Rundqvist S. Borides, Silicides and Phosphides. — London, « Methuen » . 1965. P. 230.
Anvil Kumar Sinha. Boriding (Boronizing) // ASM Handbook. V. 4. Heat Treating. 1998. P. 437–447.
Dubinin G.N., Kogan Ya. D., ed. Progressivnye metody khimiko-termicheskoi obrabotki. Moscow, 1979. 184 p. [Progressive methods of chemical-thermal processing].
Mildleham T. and others. // Iron and Steel. 1957. V. 30. P. 12.
Khansen M., Anderko K. Struktury dvoinyh splavov. Moscow, 1962. Vol. 1. 608 p. [The structures of binary smelts]
Serebryakova T.I., Neronov V.A., Peshev P.D. Vysokotemperaturnye boridy. Moscow, Chelyabinsk, 1991. 368 p. [High-termperature borides]
Kunst H. und Schaaber O. // Harterei-Technische Mitteilungen, 1967. Bd. 22. H. 3. H. 4. S. 275–292.
Lyakhovich L.S., ed. Khimiko-termicheskaya obrabotka metallov i splavov. Spravochnik. Moscow, 1981. 424 p [Chemical-thermal processing of metals and smelts. Reference book.]
Krukovich M.G. Issledovaniye zhidkostnyh bezelektroliznyh protcessov khimiko-termicheskoi obrabotki. Minsk, 1974. 298 p. [The study of liquid non-electrolysis processes of chemical-thermal treatment].
Lyakhovich L.S., Krukovich M.G., Turov Yu. V., Kosachevskii L.N. Sovremennoe napravlenie primeneniya zhidkostnogo borirovaniya dlya povysheniya stoikosti izdelii. Minsk, 1975. 20 p. [Modern trends of applying liquid boriding for increasing wear-resistance of details].
Krukovich M.G. Razrabotka teoreticheskih i prikladnyh aspektov upravleniya strukturoi i svoistvami borirovannyh sloev i ih ispolzovanie pri proizvodstve transportnoi tekhniki. Moscow, 1995. 416 p. [The development of theretical and practical aspects of controlling the structure and properties of boronized layers and their usage in producting transportation vehicles]
Tsipas D.N., Rus J., and Noguerra H. // The Metals Society. 1988. P. 203–210
Bernstein M.L., Rachstadt A.G., ed. Metallovedeniye i termicheskaya obrabotka. Spravochnik. Moscow, 1962. Vol. 2. Pp. 1041–1043 [Metallurgy and thermal processing. Reference book]
Dearnley P.A., Farrell T., and Bell T. // J. Mater. Energy Sys. 1986. V. 8, № 2. P. 128–131
Krukovich M.G. Odnofaznoe borirovaniye stalei // Poverkhnostnye metody uprochneniya metallov i splavov v mashinostroenii. Moscow, 1983. P. 81–84. [One-phase steel boriding]
Minkevich A.N. Khimiko-termicheskaya obrabotka metallov i splavov. Moscow, 1965. 491 p. [Chemical-thermal processing of metals and alloys]
Glukhov V.P. Boridnye pokrytiya na zheleze i stalyah. Kiev, 1970. 208 p. [Boride coatings on iron and steels]
Fichtl W.J.G. // Hart.-Tech. Mitt. 1974. Bd. 29. № 2, S. 113–119
Lakhtin Yu. M., Kozlovskiy I.S. Borirovaniye // Termicheskaya obrabotka v mashinostroenii. Moscow, 1967. Pp. 344–350. [Boriding]
Bokiy G.B. Vvedeniye v kristallokhimiyu. Moscow, 1971. 425 p. [Introduction to the chemistry of crystals]
Mirkin L.I. Spravochnik po rentgenostrukturnomu analizy polikristalov. Moscow, 1961. 863 p. [Reference book on the x-ray diffraction analysis of polycrystals]
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
Copyright information
© 2016 Springer International Publishing Switzerland
About this chapter
Cite this chapter
Krukovich, M.G., Prusakov, B.A., Sizov, I.G. (2016). The Components and Phases of Systems ‘Boron-Iron’ and ‘Boron-Carbon-Iron’. In: Plasticity of Boronized Layers. Springer Series in Materials Science, vol 237. Springer, Cham. https://doi.org/10.1007/978-3-319-40012-9_3
Download citation
DOI: https://doi.org/10.1007/978-3-319-40012-9_3
Published:
Publisher Name: Springer, Cham
Print ISBN: 978-3-319-40011-2
Online ISBN: 978-3-319-40012-9
eBook Packages: Chemistry and Materials ScienceChemistry and Material Science (R0)