Abstract
Electrochemical properties of metallic biomaterials in tissue environment have a direct effect on the biocompatibility of implants manufactured out of them. On the other hand, improved corrosion resistance is primarily related to the chemical composition of the surface layer which is in direct contact with bone tissue. The paper proposes modification of the surface of the 316LVM steel with TiO\(_2\) oxide layer using the ALD method, because of the good tolerability of the compound in the human body. In order to determine the optimum number of cycles, and thereby a sufficient thickness of the layer, an electrochemical study (EIS) and corrosion resistance study (potentiostatic and potentiodynamic) were conducted. Studies were carried out in Ringer’s solution at the temperature of T \(=\) 37 \(^{\circ }\)C and pH \(=\) 6.8 ± 0.2. Finding out what is the optimal thickness of the TiO\(_2\) layer has a prospective importance and will contribute to the development of technological conditions with explicit parameters for depositing oxide coatings on implants made out of steel 316LVM. Based on the results it was found that the most favorable electrochemical properties in Ringer solution were shown by TiO\(_2\) layer deposited using ALD method with 500 cycles.
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References
Aarik, L., Arroval, T., Rammula, R., Mändar, H., Sammelselg, V., Aarik, J.: Atomic layer deposition of TiO2 from TiCl4 and O3. Thin Solid Films 542, 100–107 (2013)
Basiaga, M., Staszuk, M., Walke, W., Opilski, Z.: Mechanical properties of ALD TiO2 layers on stainless steel substrate. Materialwissenschaft Werkstofftechnik issue 5, 35–41 (2016)
Basiaga, M., Jendruś, R., Paszenda, Z., Kaczmarek, M., Popczyk, M.: Influence of surface modification on properties of stainless steel used for implants. Arch. Metall. Mater. 60(4), 2955–2959 (2015)
Basiaga, M., Paszenda, Z., Karasiński, P., Szewczenko, J.: The effects of a SiO2 coating on the corrosion parameters cpTi and Ti-6Al-7Nb alloy. Biomatter 4(1), e28535 (2014). doi:10.4161/biom.28535
Basiaga, M., Paszenda, Z., Walke, W., Karasiński, P., Marciniak, J.: Electrochemical impedance spectroscopy and corrosion resistance of SiO2 coated cpTi and Ti-6Al-7Nb alloy. Inf. Technol. Biomed. Adv. Intell. Syst. Comput. 284, 411–420 (2014). Springer
Carp, O., Huismas, C.L., Reller, A.: Photoinduced reactivity of titanium dioxide. Prog. Solid State Chem. 32, 33–177 (2004)
Díaza, B., Swiatowska, J., Mauricea, V., Seyeux, A., Normand, B., Härkönen, E., Ritala, M., Marcus, P.: Electrochemical and time-of-flight secondary ion mass spectrometry analysis of ultra-thin metal oxide (Al2O3 and Ta2O5) coatings deposited by atomic layer deposition on stainless steel. Electrochim. Acta 56, 10516–10523 (2011)
Fekry, A.M., El-Sherif, R.M.: Electrochemical corrosion behavior of magnesium and titanium alloys in simulated body fluid. Electrochim. Acta 54, 7280–7285 (2009)
Hannawa, T., Asami, K., Asoka, K.: Repassivation of titanium and surface oxide film regenerated in simulated bioliquid. J. Biomed. Mater. Res. 40, 530–538 (1998)
Houmarda, M., Nunesb, E.H.M., Vasconcelosb, D.C.L., Berthoméc, G., Joudc, J.-C., Langletd, M., Vasconcelosba, W.L.: Correlation between sol-gel reactivity and wettability of silica films deposited on stainless steel. Appl. Surf. Sci. 289, 218–222 (2014)
Kaczmarek, M.: Investigation of pitting and crevice corrosion resistance of NiTi alloy by means of electrochemical methods. Electr. Rev. 86(12), 102–105 (2010)
Kajzer, A., Kajzer, W., Dzielicki, J., Matejczyk, D.: The study of physicochemical properties of stabilizing plates removed from the body after treatment of pectus excavatum. Acta Bioeng. Biomech. 2, 35–44 (2015)
Kajzer, A., Kajzer, W., Semenowicz, J., Mroczka, A.: Corrosion resistance of hip endoprosthesis cups in the initial state and after implantation. Solid State Phenom. 227, 523–526 (2015)
Karambakhsh, A., Afshar, A., Malekinejad, P.: Corrosion resistance and color properties of anodized Ti-6Al-4V. J. Mater. Eng. Perform. 21, 121–127 (2012)
Kelly, E.J.: Electrochemical behavior of titanium. Mod. Aspect Electrochem. 14, 319–324 (1988)
Leskela, M., Ritala, M.: Angewandte Chemie International Edition 42, 5548 (2003)
Lim, B.S., Rahtu, A., Gordon, R.G.: Atomic layer deposition of transition metals. Nat. Mater. 2, 749–754 (2003)
Liua, X., Chub, P., Dinga, Ch.: Surface modification of titanium, titanium alloys, and related materials for biomedical applications. Mater. Sci. Eng. R 47, 49–121 (2004)
Liu, X., Chu, P.K., Ding, C.: Surface modification of titanium, titanium alloys and related materials for biomedical applications. Mater. Sci. Eng. R47, 49–121 (2004)
Long, M., Rack, H.J.: Titanium alloy in total joint replacement—a science perspective. Biomaterials 19, 1621–1639 (1998)
Lukaszczyk, J., Śmiga-Matuszowicz, M., Jaszcz, K., Kaczmarek, M.: Characterization of new biodegradable bone cement compositions based on functional polysuccinates and methacrylic anhydride. J. Biomater. Sci. Polym. Ed. 18(7), 825–842 (2007)
Marciniak, J., Szewczenko, J., Kajzer, W.: Surface modification of implants for bone surgery. Arch. Metall. Mater. 60(3B), 13–19 (2015)
Marin, E., Guzman, L., Lanzutti, A., Ensinger, W., Fedrizzi, L.: Ultilayer Al2O3/TiO2 atomic layer deposition coatings for the corrosion protection of stainless steel. Thin Solid Films 522, 283–288 (2012)
Martin, E., Lanzutti, A., Paussa, L., Guzman, L., Fedrizzi, L.: Long term performance of atomic layer deposition coatings for corrosion protection of stainless steel. Mater. Corros. 66(9), 909–914 (2015)
Saleem, M.R., Silfsten, P., Honkanen, S., Turunen, J.: Thin Solid Films 520, 5442–5446 (2012)
Shan, C.X., Hou, X., Choy, K.-L.: Corrosion resistance or TiO2 films grown on stainless steel by atomic layer deposition. Surf. Coat. Technol. 202, 2399–2402 (2008)
Standard: ASTM G48—11 (2015) An ASTM designation number identifies a unique version of an ASTM standard. G48—11(2015) G = corrosion, deterioration, and degradation of materials; 48 = assigned sequential number 11 = year of original adoption (or, in the case of revision, the year of last revision) (2015) = year of last reapproval: Standard Test Methods for Pitting and Crevice Corrosion Resistance of Stainless Steels and Related Alloys by Use of Ferric Chloride Solution
Szewczenko, J., Jaglarz, J., Basiaga, M., Kurzyk, J., Skoczek, E., Paszenda, Z.: Topography and thickness of passive layers on anodically oxidized Ti6Al4V alloys. Electr. Rev. 88(12B), 228–231 (2012)
Tamilselvi, S., Raman, V., Rajendran, N.: Corrosion behaviour of Ti-6Al-7Nb and Ti-6Al-4V ELI alloys in the simulated body fluid solution by electrochemical impedance spectroscopy. Electrochim. Acta 52, 839–846 (2006)
Textor, M., Sitting, C., Frauchiger, V., Tosatti, S.: Properties and Biological Significance of Natural Oxide Films on Titanium and its Alloys. Titanium in Medicine. Springer, Heidelberg (2001)
Walke, W., Paszenda, Z., Basiaga, M., Karasiński, P., Kaczmarek, M.: EIS study of SiO2 Oxide Film on 316L stainless steel for cardiac implants. Inf. Technol. Biomed. Adv. Intell. Syst. Comput. 284, 403–410 (2014). Springer
Zhang, L., Prosser, J.H., Feng, G., Lee, D.: Mechanical properties of atomic layer deposition-reinforced nanoparticle thin films. Nanoscale 4, 6543–6552 (2012)
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Hyla, A., Walke, W. (2016). Electrochemical Properties of TiO\(_2\) Oxide Film on 316LVM Stainless Steel for Orthopedic Implants. In: Piętka, E., Badura, P., Kawa, J., Wieclawek, W. (eds) Information Technologies in Medicine. ITiB 2016. Advances in Intelligent Systems and Computing, vol 472. Springer, Cham. https://doi.org/10.1007/978-3-319-39904-1_33
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