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Mechanoluminescence of Coordination Compounds

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Triboluminescence

Abstract

Mechanoluminescence (ML) involves all luminescence phenomena induced by mechanical action on solids. In this case, a wide varieties of mechanical stimuli, such as compressing, stretching, static loading (pressure-step), pressure pulse, cleaving, rubbing, and grinding, might induce the excitation of solids, yielding luminescence phenomena. The present chapter discusses on mechanoluminescent properties of transition metal and lanthanide coordination compounds. The principal aim of this chapter is to describe the recent facts about the mechanisms of mechanoluminescence and their correlation with structural properties. It will be also presented a concise overview on the latest progress made on the current variety of ML coordination compounds or materials based on transition and lanthanide metals. The recent studies in this area may lead to the development of ML materials for smart optical sensors for real-time damage detections, monitoring civil and military structures, luminescent probes for biological applications, and lightning systems.

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Abbreviations

acac− :

Acetylacetonate

acbz:

1,4-Diacetylbenzene

acetbz:

1,4-Diacetoxybenzene

APY:

4-Aminopyridinium

bipy:

2,2′-Bipyridine

BIPYPO:

3,3′-Bis(diphenylphosphoryl)-2,2′-bipyridine

BL:

Bioluminescence

CL:

Chemiluminescence

dbm− :

Dibenzoylmethanate

dia:

4,5-Diazafluoren-9-one

dmbp:

4,4′-Dimethyl-2,2′-bipyridinate

dmdpy:

4,4′-Dimethyl-2,2′-bipyridyl ligand

DMPY:

1,4-Dimethylpyridinium

dmtph:

1,4-Dimethyltherephthalate

DPEPO:

Bis[2-(diphenylphosphino)phenyl]ether oxide

dpm:

Pivaloylmethanate

EL:

Electroluminescence

FL:

Fractoluminescence

hfac− :

Hexafluoroacetoacetonate

hmpa:

Hexamethylphosphoramide

EuD4TEA:

HNEt3[Eu(dbm)4]

HPPI:

3-Phenyl-4-propanoyl-5-isoxazone

LEDs:

Lighting-emitting devices

LMCT:

Ligand-to-metal charge transfer states

Ln3+ :

Trivalent lanthanide ions

LRR :

(−)-4,5-Pinene bipyridine

LSS :

(+)-4,5-Pinene bipyridine

ML:

Mechanoluminescence

MLCT:

Metal-to-ligand charge transfer

MLQ:

N-Methylisoquinolium

MOFs:

Metal-organic frameworks

N2 :

Nitrogen

NO3 − :

Nitrate ion

PD:

Photodiode

phen:

1,10-Phenantroline

PL:

Photoluminescence

PyO:

Pyridine N-oxide

PZL:

Piezoluminescence

S:

Singlet state

T:

Triplet state

TL:

Triboluminescence

tppo:

Triphenylphosphine oxide

tta− :

Thenoyltrifluoroacetonate

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Authors and Affiliations

  1. Department of Chemistry, Federal University of Paraiba, Cidade Universitária, João Pessoa, PB, 58051-970, Brazil

    Ercules Epaminondas Sousa Teotonio, Wagner Mendonça Faustino, Jandeilson Lima Moura, Israel Ferreira Costa & Paulo Roberto Silva Santos

  2. Department of Fundamental Chemistry, University of São Paulo, São Paulo, SP, 05508-000, Brazil

    Hermi Felinto Brito

  3. Institute of Nuclear Energy and Research, Av. Prof Lineu Prestes 2242 Cidade Universitária, São Paulo, SP, 05508-000, Brazil

    Maria Claudia França Cunha Felinto

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Corresponding author

Correspondence to Ercules Epaminondas Sousa Teotonio .

Editor information

Editors and Affiliations

  1. Industrial & Manufacturing Engineering Department, FAMU-FSU College of Engineering, Tallahassee, Florida, USA

    David O. Olawale

  2. Industrial & Manufacturing Engineering Department, FAMU-FSU College of Engineering, Tallahassee, Florida, USA

    Okenwa O. I. Okoli

  3. Naval Surface Warfare Center, Bethesda, Maryland, USA

    Ross S. Fontenot

  4. Dept of Physics, University of Louisiana, Lafayette, Louisiana, USA

    William A. Hollerman

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© 2016 Springer International Publishing Switzerland

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Teotonio, E.E.S. et al. (2016). Mechanoluminescence of Coordination Compounds. In: Olawale, D., Okoli, O., Fontenot, R., Hollerman, W. (eds) Triboluminescence. Springer, Cham. https://doi.org/10.1007/978-3-319-38842-7_3

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  • DOI: https://doi.org/10.1007/978-3-319-38842-7_3

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  • Publisher Name: Springer, Cham

  • Print ISBN: 978-3-319-38841-0

  • Online ISBN: 978-3-319-38842-7

  • eBook Packages: EngineeringEngineering (R0)

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