Abstract
This chapter illustrates the pivotal role of electron spin—electron spin and electron—nuclear interactions in various areas of photochemistry and photophysics. Advanced methods based on these interactions allow to elucidate detail mechanism of radical reactions and also to control them. Long distance exchange interactions govern the process of the photoinduced charge separation in donor-acceptor pairs, which is in fact the act of conversion of light energy to chemical energy. Exchange interaction also form a basis for triplet-triplet energy transfer and annihilation, processes of great basic and applied importance. Analogy between spin exchange, triplet-triplet energy transfer and electron transfer have been stressed.
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Likhtenshtein, G. (2016). Electron Spin Effects in Chosen Chemical and Physical Processes. In: Electron Spin Interactions in Chemistry and Biology. Biological and Medical Physics, Biomedical Engineering. Springer, Cham. https://doi.org/10.1007/978-3-319-33927-6_8
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