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Spin Exchange Processes Involving Exited Triplet States

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Electron Spin Interactions in Chemistry and Biology

Part of the book series: Biological and Medical Physics, Biomedical Engineering ((BIOMEDICAL))

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Abstract

A general survey of the fundamentals and recent advances in the theory of spin exchange processes such as triplet-triplet and singlet-singlet energy transfer, triplet-triplet annihilation, up conversion and intersystem crossing is presented. These data have formed the theoretical basis for a deep understanding of the details of the mechanisms of numerous chemical and biological reactions, for the development of new methods of structural investigation and analysis, and for the construction of efficient devices for phototherapy, photoelectric processes, photoemission molecular logic systems, light-emitting diodes, light energy conversion, etc.

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References

  1. J. Vura-Weis, S.H. Abdelwahed, R. Shukla, R. Rathore, M.A. Ratner, M.R. Wasielewsk, Science 328, 1547 (2010)

    Google Scholar 

  2. J. Zhao, K. Xu, W. Yang, Z. Wang, F. Zhong, Chem. Soc. Rev. (2015) Ahead of Print

    Google Scholar 

  3. B. Zhou, B. Shi, D. Jin, X. Liu, Nat. Nanotechnol. 10, 924 (2015)

    Google Scholar 

  4. J. Vura-Weis, S.H. Abdelwahed, R. Shukla, R. Rathore, M.A. Ratner, R. Wasielewski, Science 328, 1547 (2010)

    Article  ADS  Google Scholar 

  5. Y. Feng, J. Cheng, L. Zhou, X. Zhou, H. Xiang, Analyst 137, 4885 (2012)

    Article  ADS  Google Scholar 

  6. D. Gust, Faraday discussions (2015). Ahead of Print

    Google Scholar 

  7. S. Fukuzumi, K. Ohkubo, Chem. Sci. 4, 561 (2013)

    Article  Google Scholar 

  8. A. Kamkaew, S. Lim, H. Lee, L. Kiew, L. Chung, K. Burgess, Chem. Soc. Rev. 42, 77 (2013)

    Article  Google Scholar 

  9. J.R. Lakowicz, Principles of Fluorescence Spectroscopy, 3rd edn. (Springer, 2006)

    Google Scholar 

  10. M. Sauer, J. Hofkens, J. Enderlein, Handbook of Fluorescence Spectroscopy and Imaging: From Ensemble to Single Molecules (Wiley, 2011)

    Google Scholar 

  11. D.W. Ball. Phosphorescence. in Field Guide to Spectroscopy (SPIE, Press books, 2015)

    Google Scholar 

  12. C.R. Ronda. Luminescence: From Theory to Applications (Wiley, 2008)

    Google Scholar 

  13. D.L. Dexter, J Chem. Phys. 21, 8361953)

    Google Scholar 

  14. A.N. Terenin, V.L. Ermolaev, Trans. Faraday Soc. 52, 1042 (1956)

    Article  Google Scholar 

  15. V.L. Ermolaev, E.N Bodunov, E.B., Sveshnikova, T.A. Shakhverdov, Radiationless Transfer of Electronic Excitation Energy (Nauka, Leningrad, 1977)

    Google Scholar 

  16. H.E. Zimmerman, G.L. Grunewald, J. Am. Chem. Soc. 88, 183 (1966)

    Article  Google Scholar 

  17. G.S. Hammond, J. Saltiel, J. Amer. Chem. Soc. 85, 2516 (1963)

    Article  Google Scholar 

  18. J. Saltiel, J.M. Mace, L.P. Watkins, D.A. Gormin, R.J. Clark, O. Dmitrenko, J. Amer. Chem. Soc. 125, 16158 (2003)

    Article  Google Scholar 

  19. K. Sandros, Acta Chem. Scand. 18, 2355 (1964)

    Article  Google Scholar 

  20. J.E. Subotnik, J. Vura-Weis, A.J. Sodt, M.A Ratner, J, Phys. Chem. A 114, 8665 (2010)

    Google Scholar 

  21. Z.Q. You, C.-P. Hsua, G.R. Fleming, J. Chem. Phys. 124, 044506 (2006)

    Article  ADS  Google Scholar 

  22. Y.-B. Si, X.-X. Zhong, W.-W. Zhang, Y. Zhao Chin, J. Phys. Chem. C 116, 12499 (2012)

    Article  Google Scholar 

  23. A. Neubauer, G. Grell, A. Friedrich, S.I. Bokarev, P. Schwarzbach, F. Gaertner, A.-E. Surkus, H. Junge, M. Beller, O. Kuehn, S. Lochbrunner, J. Phys. Chem. Lett. 5, 1355 (2014)

    Article  Google Scholar 

  24. J. Ma, X. Cui, F. Wang, W. Xueyan, J. Zhao, X. Li, J. Org. Chem. 79, 10855 (2014)

    Article  Google Scholar 

  25. L.M. Frutos, O. Castano, J.L. Andres, M. Merchan, A.U. Acuna, J. Chem. Phys. 120, 1208 (2004)

    Article  ADS  Google Scholar 

  26. F. Zapata, M. Marazzi, O. Castaño, A.U. Acuña, L.M. Frutos, J. Chem. Phys. 140, 034102 (2014)

    Article  ADS  Google Scholar 

  27. D. Chantal, Coord. Chem. Rev. 282–283, 19 (2015)

    Google Scholar 

  28. M. Durchan, J. Tichy, R. Litvin, V. Slouf, Z. Gardian, P. Hribek, F. Vacha, T. Polivka, J. Phys. Chem. B 116, 8880 (2012)

    Article  Google Scholar 

  29. F.S. Steinbacher, R. Krause, A. Hunze, A. Winnacker, Phys. Status Solidi A 209, 340 (2012)

    Article  ADS  Google Scholar 

  30. Z.-Q. You, C.-P. Hsu, J. Chem. Phys. 133, 074105 (2010)

    Article  ADS  Google Scholar 

  31. R.E. Merrifield, J. Chem. Phys. 48, 4318 (1968)

    Article  ADS  Google Scholar 

  32. R. Islangulov, J. Lott, C. Weder, F.N. Castellano, J. Am. Chem. Soc. 129, 12652 (2007)

    Article  Google Scholar 

  33. Ibrayev NK, V.A. Latoni. Dynamics of triplet excitations in Langmuir-Blodgett films of aromatic molecules. J. Lumin. 2000, 87–89, 760–763

    Google Scholar 

  34. V.M. Mekler, O.V. Belonogova, L.I. Borodenko, G.I Zhiznevskaya, S.F. Izmailov, in Spectroscopy of Biological Molecules, ed. by J.C. Merlin, S. Turrell, J.P. Huvenne, European Conference on the Spectroscopy of Biological Molecules, 6th, Villeneuve d’Ascq, Fr., Sept. 3–8, 1 405–406 (1995)

    Google Scholar 

  35. V.M. Mekler, F.T. Umarova, Biofizika 33, 720 (1988)

    Google Scholar 

  36. V.M. Mekler, G.I. Likhtenshtein, Biofizika 31, 568 (1986)

    Google Scholar 

  37. V.M. Mekler, A.I. Kotel’nikov, G.I. Likhtenshtein, M.A. Berkovich, Biofizika 27, 641 (1982)

    Google Scholar 

  38. T. Miteva, V. Yakutkin, G. Nelles, S. Baluschev, New J. Phys. 10, 103002 (2008)

    Article  ADS  Google Scholar 

  39. A. Benfredj, F.L. Hachani, S. Romdhane, H. Bouchriha, Phys. Rev. B 71, 075205 (2005)

    Article  ADS  Google Scholar 

  40. A.R. Monguzzi Meinardi, Phys. Rev. B 80, 039904(E) (2009)

    Google Scholar 

  41. T. Förster, Naturwissenschaften 33, 166 (1946)

    Article  ADS  Google Scholar 

  42. S. Faure, C. Stern, R. Guilard, P.D. Harvey, J. Am. Chem. Soc. 126, 1253 (2004)

    Article  Google Scholar 

  43. A.A. Setlur, J.J. Shiang, C.J. Vess, J. Phys. Chem. C. 2011(115), 3475–3480

    Google Scholar 

  44. M.D. LaCount, D. Weingarten, N. Hu, S.E. Shaheen, J. van de Lagemaat, G. Rumbles, D.M. Walba, M.T. Lusk, J. Phys. Chem. A 119, 4009 (2015)

    Article  Google Scholar 

  45. G.B. Piland, J.J. Burdett, R.J. Dillon, C.J. Bardeen, J. Phys. Chem. Lett. 5, 2312 (2014)

    Article  Google Scholar 

  46. A. Monguzzi, J. Mezyk, F. Scotognella, R. Tubino, F. Meinardi, Phys. Rev. B 78, 195112 (2008)

    Article  ADS  Google Scholar 

  47. M. Bixon, J.J. Jortner, Chem. Phys. 48, 715 (1968)

    ADS  Google Scholar 

  48. A. Jabłoński, Nature 131, 839 (1933)

    Google Scholar 

  49. J.M. Bowman, Science 319, 40 (2008)

    Article  Google Scholar 

  50. A. Nakata, T. Tsuneda, K. Hirao, J. Chem. Phys. 135, 224106 (2011)

    Google Scholar 

  51. Q. Li, Y.-X. Qiu, X.-Y. Chen, W.H.E. Schwarz, S.G. Wang, Phys. Chem. Chem. Phys. 14, 6833 (2012)

    Article  Google Scholar 

  52. C.M. Marian, Wiley Interdisciplinary Rev: Comput. Mol. Sci. 187, 203 (2012)

    Google Scholar 

  53. Y. Si, W. Zhang, Y. Zhao, J. Phys. Chem. A 116, 2583 (2012)

    Article  Google Scholar 

  54. D. Chantal, Coord. Chem. Rev. 282–283, 19 (2015)

    Google Scholar 

  55. L.-G. Gao, X.-L. Song, Y.-C. Wang, L.-L. Lü, Comput. Theor. Chem. 3(968), 31–38 (2011)

    Article  Google Scholar 

  56. S. Koseki, M.S. Gordon, M.W. Schmidt, N. Matsunaga, J. Phys. Chem. 99, 12764 (1995)

    Article  Google Scholar 

  57. M. Baba, J. Phys. Chem. A 115, 9514 (2011)

    Article  Google Scholar 

  58. M.A. El-Sayed, Acc. Chem. Res. 1, 8 (1968)

    Article  Google Scholar 

  59. J.N. Harvey, Phys. Chem. Chem. Phys. 9, 331–343 (2007)

    Article  Google Scholar 

  60. Y. Si, W. Zhang, Y. Zhao, J. Phys. Chem. A 116, 2583 (2012)

    Article  Google Scholar 

  61. J. Chang, A.J. Fedro, van M. Veenendaal, Phys. Rev. B 82, 075124 (2010)

    Google Scholar 

  62. U. Fano, Phys. Rev. 124, 1866 (1961)

    Article  ADS  Google Scholar 

  63. A. Nakata, T. Tsuneda, K. Hirao, J. Chem. Phys. 135, 224106 (2011)

    Article  ADS  Google Scholar 

  64. S. Mai, P. Marquetand, L. Gonzalez, Intern. J. Quant. Chem. (2015). Ahead of Print]

    Google Scholar 

  65. M. Kleinschmidt, C. van Wüllen, C.M. Marian, J. Chem. Phys. 142, 094301/1 (2015)

    Google Scholar 

  66. M. Huix-Rotllant, N. Ferre, J. Chem. Phys. 140, 134305/1 (2014)

    Google Scholar 

  67. G.S. Orf, D.M. Niedzwiedzki, R.E. Blankenship, J. Phys. Chem. B 118, 2058 (2014)

    Article  Google Scholar 

  68. L.D. Landau, E.M. Lifshitz Quantum Mechanics, (Pergamon, Oxford, 1976)

    Google Scholar 

  69. O. Schalk, M.S. Schuurman, G. Wu, P. Lang, M. Mucke, R. Feifel, A. Stolow, J. Phys. Chem. A 118, 2279 (2014)

    Article  Google Scholar 

  70. E.F. Healy, S. Manzer, J. Gorman, A. Jones, N. Cristea, Chem. Phys. Lett. 485, 258 (2010)

    Article  ADS  Google Scholar 

  71. D. Ompong, J. Singh, Physica Status Solidi C: Current Topics in Solid State Physics (2015). Ahead of Print

    Google Scholar 

  72. S. Pal, N. Chatterjee, P.K. Bharadwaj, RSC Adv. 4, 26585 (2014)

    Google Scholar 

  73. S. Tobita, M. Arakawa, I. Tanaka, J. Phys. Chem. 89, 5649 (1985)

    Article  Google Scholar 

  74. M. Wierzchaczewski, A. Sidorowicz, E. Lukowiak, W. Strek, P. Gawryszewska, J. Appl. Spectrosc. 62, 221 (1995)

    Article  Google Scholar 

  75. D.M. Guldi, T.D. Mody, N.N. Gerasimchuk, D. Magda, J.L. Sessler, J. Am. Chem. Soc. 122, 8289 (2000)

    Article  Google Scholar 

  76. V. Volchkov, V. Ivanov, B. Uzhinov, Journal of Fluorescence 20, 299 (2010)

    Article  Google Scholar 

  77. J.A. Green, J.A. Singer, J.H. Parks, J. Chem. Phys. 58, 2690 (1973)

    Article  ADS  Google Scholar 

  78. V.A. Kuzmin, A.S. Tatikov, J. Chem. Phys. Let. 53, 606 (1978)

    Article  ADS  Google Scholar 

  79. A.F. Tarek, G. Grampp, S. Landgraf, Int. J. Photoenergy 1, 173 (1999)

    Article  Google Scholar 

  80. I.M. Bystryak, G.I. Likhtenshtein, A.I. Kotel’nikov, O. Hankovsky, K. Hideg, Russ. J. Phys. Chem. 60, 1679 (1986)

    Google Scholar 

  81. G.I. Likhtenstein, K. Ishii, S. Nakatsuji, Photochem. Photobiol. 83, 871 (2007)

    Article  Google Scholar 

  82. G.I. Likhtenshtein, Pure Appl. Chem. 80, 2125 (2008)

    Article  Google Scholar 

  83. G.I. Likhtenshtein, D. Pines, E. Pines, V. Khutorsky, Appl. Magn. Reson. 35, 459–472 (2009)

    Article  Google Scholar 

  84. K. Ishii, Y. Hirose, N. Kobayashi, J. Am. Chem. Soc. 123, 702–708 (2001)

    Article  Google Scholar 

  85. E. Lozinsky, V.V. Martin, T.A. Berezina, A. Shames, A.L. Weis, G.I. Likhtenshtein, J. Biochem. Biophys. Meth. 38, 29 (1999)

    Article  Google Scholar 

  86. N. Medvedeva, V.V. Martin, G.I. Likhtenshten, J. Photochem. Photobiol. A Chem 163, 45 (2004)

    Article  Google Scholar 

  87. E.M. Lozinsky, L.V. Martina, A.I. Shames, N. Uzlaner, A. Masarwa, G.I. Likhtenshtein, D. Meyerstein, V.V. Martin, Z. Priel, Detection of NO from pig trachea by a fluorescence method, Analyt. Biochem. 326, 139 (2004)

    Google Scholar 

  88. G.I. Likhtenshtein, Appl. biochem. biotech. 152, 135 (2009)

    Article  Google Scholar 

  89. G .I. Likhtenshtein, J. Yamauchi, S. Nakatsuji, A. Smirnov, Tamura R, Nitroxides: Application in Chemistry, Biomedicine, and Materials Science. (WILEY-VCH, Weinhem 2008)

    Google Scholar 

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Likhtenshtein, G. (2016). Spin Exchange Processes Involving Exited Triplet States. In: Electron Spin Interactions in Chemistry and Biology. Biological and Medical Physics, Biomedical Engineering. Springer, Cham. https://doi.org/10.1007/978-3-319-33927-6_2

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