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Ionic Transport and Dielectric Relaxation in Polymer Electrolytes

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Dielectric Properties of Ionic Liquids

Part of the book series: Advances in Dielectrics ((ADVDIELECT))

Abstract

Understanding the electrical properties of polymer electrolytes is a fundamentally and practically important problem in electrolyte science. The presence of salt not only poses challenges for the analysis of dielectric spectrum, but also leads to the emergence of new relaxation processes. In addition, the ionic transport mechanism in polymers remains poorly understood. Here we present a brief review of the methods for analysis of the dielectric spectra as well as an account of the phenomenology of ionic transport and dielectric relaxation in polymer electrolytes.

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Acknowledgments

The writing of this book chapter was supported by the Oak Ridge National Laboratory’s Center for Nanophase Materials Sciences, which is a DOE Office of Science User Facility.

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Authors and Affiliations

  1. Center for Nanophase Materials Sciences, Oak Ridge National Laboratory, Oak Ridge, TN, 37831, USA

    Yangyang Wang

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  1. Yangyang Wang
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Correspondence to Yangyang Wang .

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Editors and Affiliations

  1. Institute of Physics, University of Silesia in Katowice, Katowice, Poland

    Marian Paluch

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Wang, Y. (2016). Ionic Transport and Dielectric Relaxation in Polymer Electrolytes. In: Paluch, M. (eds) Dielectric Properties of Ionic Liquids. Advances in Dielectrics. Springer, Cham. https://doi.org/10.1007/978-3-319-32489-0_6

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