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A Uranium-Based Isothiosemicarbazone Schiff Base Complex

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Crystallizing Ideas – The Role of Chemistry

Abstract

A uranium(VI) complex UO2(L-Sal)EtOH has been synthesized by template reaction of 2-hydroxyacetophenone S-pentyl isothiosemicarbazone .hydrogen bromide (H2L), and salicylaldehyde (Sal) in the presence of uranium acetate salt. The complex was characterized by elemental analyses, IR, mass, UV–Vis, and X-ray diffraction methods. The crystal structure of the complex shows a distorted pentagonal bipyramidal geometry, where the oxo atoms occupy the axial positions and the pentagonal plane is defined by the N2O2 atoms of the tetradentate Schiff base ligand and the O atom of the ethanol molecule. The N2O2 donor ligand is coordinated to uranium(VI) via both deprotonated phenolic oxygen and azomethine nitrogen atoms.

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Acknowledgments

The study was financially supported by Ferdowsi University of Mashhad (Grant No. 3/30263 1392/12/17). RT expresses his sincere thanks to OPCW for supporting his trip to attend ICPAC 2014.

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Authors and Affiliations

  1. Faculty of Sciences, Department of Chemistry, Ferdowsi University of Mashhad, 91775-1436, Mashhad, Iran

    Reza Takjoo & Seyedeh Fatemeh Mirisalimi

  2. Faculty of Chemistry, University of Isfahan, 81746-73441, Isfahan, Iran

    Hadi Amiri Rudbari

Authors
  1. Reza Takjoo
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  2. Seyedeh Fatemeh Mirisalimi
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  3. Hadi Amiri Rudbari
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Corresponding author

Correspondence to Reza Takjoo .

Editor information

Editors and Affiliations

  1. Dep. of Chemistry, Fac. of Science, University of Mauritius, Reduit, Mauritius

    Ponnadurai Ramasami

  2. Dept of Chemistry, Faculty of Scien, University of Mauritius, Reduit, Mauritius

    Minu Gupta Bhowon

  3. Dept. of Chemistry, Faculty of Scie, University of Mauritius, Reduit, Mauritius

    Sabina Jhaumeer Laulloo

  4. Reduit, Mauritius

    Henri Li Kam Wah

Appendix A. Supplementary Material

Appendix A. Supplementary Material

CCDC 1028887 contains the supplementary crystallographic data for the compounds. These data can be obtained free of charge via http://www.ccdc.cam.ac.uk/conts/retrieving.html, or from the Cambridge Crystallographic Data Centre, 12 Union Road, Cambridge CB2 1EZ, UK; fax: +44 1223 336 033, or e-mail: deposit@ccdc.cam.ac.uk.

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Takjoo, R., Mirisalimi, S.F., Amiri Rudbari, H. (2016). A Uranium-Based Isothiosemicarbazone Schiff Base Complex. In: Ramasami, P., Gupta Bhowon, M., Jhaumeer Laulloo, S., Li Kam Wah, H. (eds) Crystallizing Ideas – The Role of Chemistry. Springer, Cham. https://doi.org/10.1007/978-3-319-31759-5_9

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