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Synthesis and Characterization of Co(II), Ni(II) and Cu(II) Complexes with Thio-1,3,4-oxadiazole Derivatives

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Crystallizing Ideas – The Role of Chemistry

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Abstract

Transition metal complexes of Ni(II), Co(II) and Cu(II) with the ligands [L 1  = 2-(5-phenyl-1,3,4-oxadiazole-2-ylthio)benzenamine, L 2  = (E)-3-(2-(5-phenyl-1,3,4-oxadiazole-2-ylthio)phenylimino)indolin-2-one, L 3  = 2,2′-(5,5′-1,4-phenylene)bis(1,3,4-oxadiazole-5,2-diyl)bis(sulfanediyl)dibenzenamine], derived from the condensation of 5-phenyl-1,3,4-oxadiazole-2-thiol, 5,5′-(1,4-phenylene)bis(1,3,4-oxadiazole-2-thiol) and 2-aminothiophenol or isatin were synthesized. The ligands and their complexes were characterized on the basis of analytical, conductance, magnetic data, infrared, electronic spectra and 1H-NMR data. IR spectral data suggest that the ligands were chelated with the ionic metal through S and N atoms. On the basis of the spectral, physicochemical data as well as magnetic moment measurements, octahedral geometries were assigned for the complexes.

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Acknowledgements

The authors are thankful to the Chemistry Department, College of Education for facilities for accomplishing the present work, the Al-AL Bayt University Central Labs (Jordan) for 1H-NMR study and the University of Tikrit for IR study.

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Authors and Affiliations

  1. College of Education, University of Salahaddin, Erbil, Iraq

    Hikmat Ali Mohamad & Beriwan Mohamad Hamad Ameem

Authors
  1. Hikmat Ali Mohamad
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  2. Beriwan Mohamad Hamad Ameem
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Corresponding author

Correspondence to Hikmat Ali Mohamad .

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Editors and Affiliations

  1. Dep. of Chemistry, Fac. of Science, University of Mauritius, Reduit, Mauritius

    Ponnadurai Ramasami

  2. Dept of Chemistry, Faculty of Scien, University of Mauritius, Reduit, Mauritius

    Minu Gupta Bhowon

  3. Dept. of Chemistry, Faculty of Scie, University of Mauritius, Reduit, Mauritius

    Sabina Jhaumeer Laulloo

  4. Reduit, Mauritius

    Henri Li Kam Wah

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© 2016 Springer International Publishing Switzerland

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Mohamad, H.A., Ameem, B.M.H. (2016). Synthesis and Characterization of Co(II), Ni(II) and Cu(II) Complexes with Thio-1,3,4-oxadiazole Derivatives. In: Ramasami, P., Gupta Bhowon, M., Jhaumeer Laulloo, S., Li Kam Wah, H. (eds) Crystallizing Ideas – The Role of Chemistry. Springer, Cham. https://doi.org/10.1007/978-3-319-31759-5_17

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