Abstract
Graphene is a graphite sheet with (6,3) covering and all sp2 carbon atoms. In this chapter, two structural modifications of graphene are presented: the cones and CorSu (coronene-sumanene) tessellation. Topology of these modified graphenes is given in terms of several counting polynomials and corresponding topological indices. Analytical formulas were derived either by numerical analysis or by the cutting procedure. In the case of CorSu lattice, composition rules (with fragmental contributions) for the Omega polynomial were established.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
References
Abouimrane A, Compton OC, Amine K, Nguyen ST (2010) Non − annealed graphene paper as a binder − free anode for lithium − iron batteries. J Phys Chem C 114:12800–12804
Alipour MA, Ashrafi AR (2009) A numerical method for computing the Wiener index of one − heptagonal carbon nanocone. J Comput Theor Nanosci 6:1204–1207
Ashrafi AR, Gholaminezhad F (2008) The edge Szeged index of one − pentagonal carbon nanocones. Int J Nanosci Nanotechnol (IJNN) 4:135–138
Ashrafi AR, Gholaminezhad F (2009) The PI and edge Szeged indices of one − heptagonal carbon nanocones. Curr Nanosci 5:51–53
Ashrafi AR, Manoochehrian B, Yousefi − Azari H (2006) On the PI polynomial of a graph. Util Math 71:97–108
Clar E (1964) Polycyclic hydrocarbons. Academic, London
Clar E (1972) The aromatic sextet. Wiley, New York
Das B, Prasad KE, Ramamurty U, Rao CNR (2009) Nano − indentation studies on polymer matrix composites reinforced by few − layer graphene. Nanotechnology 20:25705
Denis PA (2009) Density functional investigation of thioepoxidated and thiolated graphene. J Phys Chem C 113:5612–5619
Diudea MV (2006) Omega polynomial. Carpath J Math 22:43–47
Diudea MV (2010a) Omega polynomial: composition rules in CorSu lattice. Int J Chem Model 2(4):1–6
Diudea MV (2010b) Counting polynomials and related indices by edge cutting procedures. MATCH Commun Math Comput Chem 64:569–590
Diudea MV, Ilić A (2009) CorSu network − a new graphene design. Studia Univ “Babes − Bolyai” Chemia 54(4):171–177
Diudea MV, Cigher S, John PE (2008) Omega and related counting polynomials. MATCH Commun Math Comput Chem 60:237–250
Diudea MV, Cigher S, Vizitiu AE, Florescu MS, John PE (2009) Omega polynomial and its use in nanostructure description. J Math Chem 45:316–329
Djoković D (1973) Distance preserving subgraphs of hypercubes. J Combin Theory Ser B 14:263–267
Ebbesen TW (1998) Cones and tubes: geometry in the chemistry of carbon. Acc Chem Res 31:558–566
Eda G, Unalan HE, Rupesinghe N, Amaratunga GAJ, Chhowalla M (2008) Field emission from graphene based composite thin films. Appl Phys Lett 93:233–502
Geim AK, Novoselov KS (2007) The rise of graphene. Nat Mater 6:183–191
Green AA, Hersam MC (2009) Solution phase production of graphene with controlled thickness via density differentiation. Nano Lett 9:4031–4036
Gutman I (1994) A formula for the Wiener number of trees and its extension to graphs containing cycles. Graph Theory Notes N Y 27:9–15
Ilić A, Diudea MV, Gholami − Nezhaad F, Ashrafi AR (2010) Topological indices in nanocones. In: Gutman I, Furtula B (eds) Novel Molecular structure descriptors − theory and applications. Univ Kragujevac, Kragujevac, pp 217–226
John PE, Vizitiu AE, Cigher S, Diudea MV (2007) CI index in tubular nanostructures. MATCH Commun Math Comput Chem 57:479–484
Khadikar PV (2000) On a novel structural descriptor PI. Nat Acad Sci Lett 23:113–118
Khalifeh MH, Yousefi − Azari H, Ashrafi AR (2008) Vertex and edge PI indices of cartesian product graphs. Discret Appl Math 156:1780–1789
Klavžar S (2008a) Some comments on co graphs and CI index. MATCH Commun Math Comput Chem 59:217–222
Klavžar S (2008b) A bird’s eye view of the cut method and a survey of its applications in chemical graph theory. MATCH Commun Math Comput Chem 60:255–274
Krishnan A, Dujardin E, Treacy MMJ, Hugdahl J, Lynum S, Ebbesen TW (1997) Graphitic cones and the nucleation of curved carbon surfaces. Nature 388:451–454
Lee G, Lee B, Kim J, Cho K (2009) Ozone adsorption on graphene: ab initio study and experimental validation. J Phys Chem C 113:14225–14229
Ng YH, Lightcap IV, Goodwin K, Matsumura M, Kamat PV (2010) To what extent do graphene scaffolds improve the photovoltaic and photocatalytic response of TiO2 nanostructured films. J Phys Chem Lett 1:2222–2227
Novoselov KS, Geim AK, Morozov SV, Jiang D, Zhang Y, Dubonos SV, Grigorieva IV, Firsov AA (2004) Electric field effect in atomically thin carbon films. Science 306:666–669
Okamoto Y, Miyamoto Y (2001) Ab initio investigation of physisorption of molecular hydrogen on planar and curved graphenes. J Phys Chem B 105:3470–3474
Paci JT, Belytschko T, Schatz GC (2007) Computational studies of the structure, behavior upon heating, and mechanical properties of graphite oxide. J Phys Chem C 111:18099–18111
Seger B, Kamat PV (2009) Electrocatalytically active graphene − platinum nanocomposites. Role of 2 − D carbon support in PEM fuel cells. J Phys Chem C 113:7990–7995
Stankovich S, Dikin DA, Dommett GHB, Kohlhaas KM, Zimney EJ, Stach EA, Piner RD, Nguyen ST, Ruoff RS (2006) Graphene − based composite materials. Nature 442:282–286
Tylianakis E, Psofogiannakis GM, Froudakis GE (2010) Li − doped pillared graphene oxide: a graphene − based nanostructured material for hydrogen storage. J Phys Chem Lett 1:2459–2464
Ueta A, Tanimura Y, Prezhdo OV (2010) Distinct infrared spectral signatures of the 1,2 − and 1,4 − fluorinated single − walled carbon nanotubes: a molecular dynamics study. J Phys Chem Lett 1:1307–1311
Viculis LM, Mack JJ, Kaner RB (2003) A chemical route to carbon nanoscrolls. Science 299:1361
Vizitiu AE, Diudea MV (2006) Conetori of high genera. Studia Univ “Babes − Bolyai” Chemia 51:39
Wang Y, Shi ZQ, Huang Y, Ma YF, Wang CY, Chen MM, Chen YS (2009a) Supercapacitor devices based on graphene materials. J Phys Chem C 113:13103–13107
Wang S, Tang LA, Bao Q, Lin M, Deng S, Goh BM, Loh KP (2009b) Room − temperature synthesis of soluble carbon nanotubes by the sonication of graphene oxide nanosheets. J Am Chem Soc 131:16832–16837
Watcharotone S, Dikin DA, Stankovich S, Piner R, Jung I, Dommett GHB, Evmenenko G, Wu SE, Chen SF, Liu CP (2007) Graphene − silica composite thin films as transparent conductors. Nano Lett 7:1888–1892
Wiener H (1947) Structural determination of the paraffin boiling points. J Am Chem Soc 69:17–20
Winkler P (1984) Isometric embedding in products of complete graph. Discret Appl Math 7:221–225
Xie X, Ju L, Feng X, Sun Y, Zhou R, Liu K, Fan S, Li Q, Jiang K (2009) Controlled fabrication of high − quality carbon nanoscrolls from monolayer graphene. Nano Lett 9:2565–2570
Yu DS, Dai LM (2010) Self − assembled graphene/carbon nanotube hybrid films for supercapacitors. J Phys Chem Lett 1:467–470
Acknowledgments
MVD acknowledges the financial support offered by project PN-II-ID-PCE-2011-3-0346. Thanks are addressed to Professor Davide Proserpio, Universita degli Studi di Milano, Italy, for crystallographic data.
Author information
Authors and Affiliations
Corresponding author
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 2016 Springer International Publishing Switzerland
About this chapter
Cite this chapter
Gholaminezhad, F., Diudea, M.V. (2016). Graphene Derivatives: Carbon Nanocones and CorSu Lattice: A Topological Approach. In: Ashrafi, A., Diudea, M. (eds) Distance, Symmetry, and Topology in Carbon Nanomaterials. Carbon Materials: Chemistry and Physics, vol 9. Springer, Cham. https://doi.org/10.1007/978-3-319-31584-3_9
Download citation
DOI: https://doi.org/10.1007/978-3-319-31584-3_9
Published:
Publisher Name: Springer, Cham
Print ISBN: 978-3-319-31582-9
Online ISBN: 978-3-319-31584-3
eBook Packages: Chemistry and Materials ScienceChemistry and Material Science (R0)