Abstract
The evolution of derma porosity during pre-tanning, tanning, retanning, and modifications with inorganic particles was investigated with techniques of standard contact porosimetry, transmission, and scanning electron microscopy. The method, which allows us to perform quantitative analysis of pore size distribution of the hierarchical structure, has been proposed. The interrelation between porosity due to different elements of the structure (helices, microfibrils, fibrils, fibril bundles, and fibers) and the total porosity was found to be described by a linear polynomial function. Ordering-disordering, loosing-compaction, and shrinkage-swelling at each structure level, which are affected by chemical treatment of the derma, tanning, retanning, and filling with bentonite, are analyzed.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
References
Lal R, Shukla MK (2004) Principles of soil physics. Marsel Dekker, New York
Evert RF (2006) Esau’s plant anatomy. meristems, cells, and tissues of the plant body: their structure, function and development, 3rd edn. Wiley, Hoboken, NJ
Chinga-Carrasco G (2009) Exploring the multi-scale structure of printing paper—a review of modern technology. J Microsc 234:211–242
Lomov SV, Huysmans G, Verpoest I (2001) Hierarchy of textile structures and architecture of fabric geometric models. Text Res J 71:534–543
Covington AD (2009) Tanning chemistry: the science of leather. RSC Publishing, Cambridge
Fratzl P, Weinkamer R (2007) Nature’s hierarchical materials. Prog Mater Sci 52:1263–1334
Kozar O, Mokrousova O, Woznyak B (2014) Deformation characteristics of leather for shoe upper, filled with natural minerals. J Chem Chem Eng 8:47–53
Lakshmiarayana Y, Jaisankar SN, Ramalingam S et al (2002) A novel water dispersable bentonite: acrylic graft copolymer as filler cum retanning agent. J Am Leather Chem Assoc 97:14–22
Mokrousova OR, Danilkovich AG (2006) Formation of collagen structure of derma by mineral dispersions. Sci Proc Riga Tech Univ, Ser 1 Materialzinat Lietiska Kim 14:83–91
Mokrousova O, Danylkоvich A, Palamar V (2015) Resources-saving chromium tanning of leather with the use of modified montmorillonite. Rev Chim 66:353–357
Guinier A, Fournet G (1955) Small-angle scattering of x-rays. Chapman and Hall, London
Gregg SJ, Sing KSW (1991) Adsorption, surface area, and porosity, 2nd edn. Academic, London
Pyrz WD, Buttrey DJ (2008) Particle size determination using TEM: a discussion of image acquisition and analysis for the novice microscopist. Langmuir 24:11350–11360
Wittemore OJ, Halsey GD (1983) Pore structure characterization by mercury porosimetry. In: Rossington DR, Condrate RA, Snyder RL (eds) Advances in materials characterization, vol 15, Materials science research. Plenum Press, New York, pp 147–157
Volfkovich YM, Bagotsky VS (2014) Experimental methods for investigation of porous materials and powders. In: Volfkovich YM, Filippov AN, Bagotsky VS (eds) Porous materials and powders used in different fields of science and technology. Springer, London, pp 1–8
Volfkovich YM, Sosenkin VE (2012) Porous structure and wetting of fuel cell components as the factors determining their electrochemical characteristics. Russ Chem Rev 81:936–959
Volfkovich YM, Sosenkin VE, Bagotzky VS (2010) Structural and wetting properties of fuel cell components. J Power Sources 195:5429–5441
Rouquerol J, Baron G, Denoyel R et al (2012) Liquid intrusion and alternative methods for the characterization of macroporous materials (IUPAC Technical Report). Pure Appl Chem 84:107–136
Dzyazko Y, Rozhdestveskaya L, Zmievskii Y et al (2015) Heterogeneous membranes modified with nanoparticles of inorganic ion-exchangers for whey demineralization. Mater Today: Proc 2:3864–3873
Dzyazko YS, Ponomaryova LN, Volfkovich YM et al (2013) Polymer ion-exchangers modified with zirconium hydrophosphate for removal of Cd2+ ions from diluted solutions. Sep Sci Technol 48:2140–2149
Kononenko NA, Fomenko MA, Volfkovich YM (2015) Structure of perfluorinated membranes investigated by method of standard contact porosimetry. Adv Colloid Interface Sci 222:425–435
Yartsev DV, Lakhin AV, Vol’fkovich YM et al (2010) Study of the porous structure of a monolayer carbon-ceramic composite material of the C-SiC composition. Russ J Non-Ferrous Metals 51:364–368
Neimark AV, Robens E, Unger KK et al (1994) Self similarity in swelling systems: fractal properties of peat. Fractals 2:45–53
Dzyazko YS, Volfkovich YM, Sosenkin VE et al (2014) Composite inorganic membranes containing nanoparticles of hydrated zirconium dioxide for electrodialytic separation. Nanoscale Res Lett 9:271
Jones FE, Schoonover RM (2002) Handbook of mass measurements. CRC Press, London
Author information
Authors and Affiliations
Corresponding author
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 2016 Springer International Publishing Switzerland
About this paper
Cite this paper
Mokrousova, E., Dzyazko, Y., Volfkovich, Y., Nikolskaya, N. (2016). Hierarchical Structure of the Derma Affected by Chemical Treatment and Filling with Bentonite: Diagnostics with a Method of Standard Contact Porosimetry. In: Fesenko, O., Yatsenko, L. (eds) Nanophysics, Nanophotonics, Surface Studies, and Applications. Springer Proceedings in Physics, vol 183. Springer, Cham. https://doi.org/10.1007/978-3-319-30737-4_23
Download citation
DOI: https://doi.org/10.1007/978-3-319-30737-4_23
Published:
Publisher Name: Springer, Cham
Print ISBN: 978-3-319-30736-7
Online ISBN: 978-3-319-30737-4
eBook Packages: Physics and AstronomyPhysics and Astronomy (R0)