Abstract
Calcium sulphate dihydrate (CaSO4·2H2O) (gypsum) is often used as an amendment to improve soil structure. As this treatment eventually increases soil strength, thereby exacerbating conditions for root growth, reclamation of red mud tailings using this treatment can become counterproductive. Several years (7) after lithification by added gypsum, the effect of crushing, and added phyto-organics, on some physical properties of red mud wastes (RMW) was examined under laboratory conditions. It was hypothesized that mechanically breaking up the hardened masses would increase their permeability. However, on the contrary, crushing these rock-hard masses into 2-mm particles did not increase permeability. A phyto-organic treatment on the other hand greatly improved permeability of the crushed entities such that infiltration rates increased from 0 to 10 cm/h. After 24 weeks of incubation, the structure of the newly formed phyto-organically treated gypsum-hardened RMW aggregates was also substantially improved over that of the controls, as a 3-fold increase in resistance to disintegration during wet sieving was exhibited by the phyto-organically treated samples. The increase in water infiltration by combining crushing with phyto-organic infusions was ascribed to a decrease in particle dispersion, creating more stable clay clusters, which in turn stabilized micro channels and pores. This treatment increased the plant-growth-medium potential of the age-hardened gypsum-treated red muds, thereby justifying prior atmospheric carbonation and lithification of the red muds. Conversely, it was concluded that the singular crushing of CGR in the waste dumps to create a growth medium is potentially wasteful and ineffective. However, as CGR was seemingly of greater durability than soft limestone marl, it promises effectiveness as a stable road-bed material.
Original article: Structural improvement of age-hardened gypsum-treated bauxite red mud waste using readily decomposable phyto-organics. Environmental Geology, Volume 56, No. 8, February 2009.
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Harris, M.A. (2016). Structural Amelioration of Indurated Gypsum-Treated Bauxite Red Mud Tailings Using Bacterially Mediated Organic Treatments. In: Geobiotechnological Solutions to Anthropogenic Disturbances. Environmental Earth Sciences. Springer, Cham. https://doi.org/10.1007/978-3-319-30465-6_10
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