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Room Temperature Ionic Liquids

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Ionic Liquid Properties

Abstract

Room temperature ionic liquids (RTILs) melt below 100 ºC and in this book only commonly available, i.e., aprotic ones, are dealt with, but the properties of two atypical protic ones are shown. The structural aspects of RTILs as derived from diffraction studies and computer simulations, and the modelling of the properties of RTILs are dealt with. The thermochemical data that are tabulated include the melting and decomposition temperatures, the vaporization, cohesive energies and solubility parameters, the critical properties, heat capacities, and surface tension. Also dealt with are the volumetric properties, including the compressibilities and internal pressures. The refractive index and static permittivity are listed. The tabulated and discussed transport properties include the viscosity and electrical and thermal conductivities. The chemical properties that are discussed and listed comprise the solvatochromic parameters, the mutual solubility with water, the hydrophilic/hydrophobic balance, and the solubility of carbon dioxide in the RTILs.

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  1. Hebrew University of Jerusalem, Jerusalem, Israel

    Yizhak Marcus

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Marcus, Y. (2016). Room Temperature Ionic Liquids. In: Ionic Liquid Properties. Springer, Cham. https://doi.org/10.1007/978-3-319-30313-0_6

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