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Crystalline Structure and Surface Morphology of AIIIBVI Type Lamellar Semiconductor Nanocomposites Obtained by Heat Treatment in Cd and Zn Vapor

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Nanostructures and Thin Films for Multifunctional Applications

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Abstract

The semiconductors like GaS, GaSe and InSe crystallize in lamellar structures with crystal lattice composed of B–A–A–B type packings bound by Van der Waals forces. Materials composed of Ga, In, Cd and Zn chalcogenide crystallites with sizes of 10–30 nm are obtained by heat treatment of GaS, GaSe, GaTe and InSe single crystalline plates in Zn and Cd vapor at temperatures from 653 to 853 K. Phase transformations of GaSe and GaTe compounds with formation of Ga 2 Se 3, CdGa 2 Se 4 and Ga 2 Te 3 compounds occur, as well as the formation of Ga-Cd and Cd-Te clusters on the surface, during the process of producing CdTe-GaTe and CdSe-GaSe nanocomposites.

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Authors and Affiliations

  1. Photonics and Physical Metrology Laboratory, Department of Physics and Engineering, Moldova State University, Chisinau, Moldova

    Igor Evtodiev, Valeriu Kantser, Dumitru Untila, Irina Rotaru, Liliana Dmitroglo, Silvia Evtodiev & Mihail Caraman

  2. “Vasile Alecsandri” University of Bacau, Bacau, Romania

    Iuliana Caraman

  3. Institute of Electronic Engineering and Nanotechnologies “D. Ghitu”, Academy of Sciences of Moldova, Chisinau, Moldova

    Igor Evtodiev, Valeriu Kantser & Dumitru Untila

  4. University of European Political and Economical Studies “Constantin Stere”, Stefan cel Mare si Sfint bd 200, MD-2004, Chisinau, Moldova

    Silvia Evtodiev

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  1. Igor Evtodiev
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Correspondence to Igor Evtodiev .

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Editors and Affiliations

  1. Academy of Sciences of Moldova, Chisinau, Moldova

    Ion Tiginyanu

  2. Alecu Russo Balti State University, Balti, Moldova

    Pavel Topala

  3. Laboratory of Nanotechnologies, Academy of Sciences of Moldova, Chisinau, Moldova

    Veaceslav Ursaki

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Evtodiev, I. et al. (2016). Crystalline Structure and Surface Morphology of AIIIBVI Type Lamellar Semiconductor Nanocomposites Obtained by Heat Treatment in Cd and Zn Vapor. In: Tiginyanu, I., Topala, P., Ursaki, V. (eds) Nanostructures and Thin Films for Multifunctional Applications. NanoScience and Technology. Springer, Cham. https://doi.org/10.1007/978-3-319-30198-3_11

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