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Abstract

Calcite precipitation rates on glass tablets located under three drip sites have been recorded monthly for around one year. Recorded rates range from 0.2 to 4.7 mg d−1. Results are compared with several potential predictors including external temperature, rainfall, drip rate and composition. Differences between sites have been found to be correlated mainly to drip flow rate while only within one site correlation with calcium concentration is significant. Theoretical predicted values overestimate experimental values on average by a factor two, and fail to predict the observed correlation with drip rate. It is therefore proposed to modify the standard theory by considering an effective drip rate lower than measured drip rate by a factor Φ 1. This factor accounts for drip water by-passing the glass tablet due to drop splashing. Best fit of experimental data is obtained when about 99.9 % of water is considered to be ejected during drop impingement. The order of magnitude is confirmed by additional laboratory experiment and comparison with literature data.

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References

  • Baker A, Smart PL (1995) Recent flowstone growth rates: field measurements in comparison to theoretical predictions. Chem Geol 122:121–128

    Article  Google Scholar 

  • Baker A, Genty D, Barnes WL (1996) Recent stalagmite growth rates: cave measurements, theoretical predictions and the environmental record, climate change: the karst record. Karst Waters Inst Spec Publ 2:7–9

    Google Scholar 

  • Baker A, Genty D, Dreybrodt W, Barnes WL, Mockler NJ, Grapes J (1998) Testing theoretically predicted stalagmite growth rate with recent annually laminated samples: implications for past stalagmite deposition. Geochim Cosmochim Acta 62:393–404

    Article  Google Scholar 

  • Baldini JUL (2010) The geochemistry of cave calcite deposits as a record of past climate. Sediment Rec 8(2):4–9

    Google Scholar 

  • Baldini JUL, McDermott F, Hoffmann DL, Richards DA, Clipson N (2008) Very high-frequency and seasonal cave atmosphere PCO2 variability: implications for stalagmite growth and oxygen isotope-based paleoclimate records. Earth Planet Sci Lett 272:118–129

    Article  Google Scholar 

  • Banner JL, Guilfoyle A, James EW, Stern LA, Musgrove M (2007) Seasonal variations in modern speleothem calcite growth in central texas, U.S.A. J Sediment Res 77:615–622

    Article  Google Scholar 

  • Buhmann D, Dreybrodt W (1985a) The kinetics of calcite dissolution and precipitation in geologically relevant situations of karst areas: 1. Open system. Chem Geol 48:189–211

    Article  Google Scholar 

  • Buhmann D, Dreybrodt W (1985b) The kinetics of calcite dissolution and precipitation in geologically relevant situations of karst areas: 2. Closed system. Chem Geol 53:109–124

    Article  Google Scholar 

  • Curl RL (1973) Minimum diameter stalagmites. Bull Nat Speleol Soc 35:1–9

    Google Scholar 

  • Day CC, Henderson GM (2011) Oxygen isotopes in calcite grown under cave-analogue conditions. Geochim Cosmochim Acta 75:3956–3972

    Article  Google Scholar 

  • Dreybrodt W (1988) Processes in karst systems—physics, chemistry and geology, vol 5., Springer Series in Physical EnvironmentSpringer, Berlin

    Book  Google Scholar 

  • Dreybrodt W (1998) Limestone dissolution rates in karst environments. Bull d’Hidrogeologie 16:167–183

    Google Scholar 

  • Dreybrodt W (1999) Chemical kinetics, speleothem growth and climate. Boreas 28:347–356

    Article  Google Scholar 

  • Dreybrodt W (2008) Evolution of the isotopic composition of carbon and oxygen in a calcite precipitating H2O–CO2–CaCO3 solution and the related isotopic composition of calcite in stalagmites. Geochim Cosmochim Acta 72:4712–4724

    Article  Google Scholar 

  • Dreybrodt W (2012) Comment on “Oxygen isotopes in calcite grown under cave-analogue conditions” by C.C. Day and G.M. Henderson. Geochim Cosmochim Acta 85:383–387

    Article  Google Scholar 

  • Dreybrodt W, Buhmann D (1991) A mass transfer model for dissolution and precipitation of calcite from solutions in turbulent motion. Chem Geol 90:107–122

    Article  Google Scholar 

  • Dreybrodt W, Romanov D (2008) Regular stalagmites: the theory behind their shape. Acta Carslogica 37:175–184

    Google Scholar 

  • Franke WH (1965) The theory behind stalagmite shapes. Stud Speleol 1:89–95

    Google Scholar 

  • Genty D, Baker A, Vokal B (2001) Intra- and inter-annual growth rate of modern stalagmites. Chem Geol 176:191–212

    Article  Google Scholar 

  • Hansen M, Dreybrodt W, Scholz D (2013) Chemical evolution of dissolved inorganic carbon species flowing in thin water films and its implications for (rapid) degassing of CO2 during speleothem growth. Geochim Cosmochim Acta 107:242–251

    Article  Google Scholar 

  • Kalantari D (2006) Characterization of liquid spray impact onto walls and films. TU Darmstadt, Darmstadt

    Google Scholar 

  • Kaufmann G (2003) Stalagmite growth and palaeo-climate: the numerical perspective. Earth Planet Sci Lett 214:251–266

    Article  Google Scholar 

  • Mühlinghaus C, Scholz D, Mangini A (2007) Modelling stalagmite growth and δ13C as a function of drip interval and temperature. Geochim Cosmochim Acta 71:2780–2790

    Article  Google Scholar 

  • Plummer LN, Wigley TML, Parkhurst DL (1978) The kinetics of calcite dissolution in CO2—water systems at 5° to 60 °C and 0.0 to 1.0 atm CO2. Am J Sci 278:179–216

    Article  Google Scholar 

  • Romanov D, Kaufmann G, Dreybrodt W (2008) δ13C profiles along growth layers of stalagmites: comparing theoretical and experimental results. Geochim Cosmochim Acta 72:438–448

    Article  Google Scholar 

  • van Hinsberg N (2010) Investigation of drop and spray impingement on a thin liquid layer accounting for the wall film topology. TU Darmstadt, Darmstadt

    Google Scholar 

  • Verheyden S, Genty D, Deflandre G, Quinif Y, Keppens E (2008) Monitoring climatological, hydrological and geochemical parameters in the Père Noël cave (Belgium): implication for the interpretation of speleothem isotopic and geochemical time-series. Int J Speleol 37:221–234

    Article  Google Scholar 

  • Wang PK, Pruppacher HR (1977) Acceleration to terminal velocity of cloud and raindrops. J Appl Meteorol 16:275–280

    Article  Google Scholar 

  • White WB (2007) Paleoclimate records from speleothems in limestone caves, studies of cave sediments—physical and chemical records of paleoclimate. Springer, Dordrecht, The Netherlands, pp 135–175

    Google Scholar 

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Correspondence to Simone Milanolo .

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Milanolo, S. (2016). Calcite Deposition. In: Sources and Transport of Inorganic Carbon in the Unsaturated Zone of Karst. Springer Theses. Springer, Cham. https://doi.org/10.1007/978-3-319-29308-0_9

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