Abstract
Alloys have evolved from simple to complex compositions depending on the ability of mankind to develop the materials. The resulting improved functions and performances of alloys enable advancements in civilizations. In the last century, significant evolution and progress have led to the invention of special alloys, such as stainless steels, high-speed steels, and superalloys. Although alloys composed of multiple elements have higher mixing entropy than pure metals, the improved properties are mostly due to mixing enthalpy that allows the addition of suitable alloying elements to increase the strength and improve physical and/or chemical properties. Since the turn of the century, more complex compositions with higher mixing entropies have been introduced. Such complex compositions do not necessarily guarantee a complex structure and microstructure, or the accompanied brittleness. Conversely, significantly higher mixing entropy from complex compositions could simplify the structure and microstructure and impart attractive properties to the alloys. Jien-Wei Yeh and Brian Cantor independently announced the feasibility of high-entropy alloys and equi-atomic multicomponent alloys in reports published in 2004. This breakthrough in alloying concepts has accelerated research on these new materials throughout the world over the last decade.
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References
ASM International (1990) Metals handbook, vols 1 and 2, 10th edn. ASM International, Materials Park, OH
Westbrook JH, Fleischer RL (2000) Intermetallic compounds-structural applications of intermetallic compounds. Wiley, West Sussex
Westbrook JH, Fleischer RL (2000) Intermetallic compounds-magnetic, electrical and optical properties and applications of intermetallic compounds. Wiley, West Sussex
Suryanarayana C, Inoue A (2010) Bulk metallic glasses, 1st edn. CRC Press, West Palm Beach
Smith CS (1963) Four outstanding researchers in metallurgical history. American Society for Testing and Materials, Baltimore
Baker H (ed) (1992) ASM handbook, vol 3, Alloy phase diagrams. ASM International, Materials Park
Reed-Hill RE, Abbaschian R (1994) Physical metallurgy principles, 3rd edn. PWS Publishing Company, Boston, pp 353–358
Yeh JW, Chen SK, Lin SJ, Gan JY, Chin TS, Shun TT, Tsau CH, Chang SY (2004) Nanostructured high-entropy alloys with multiple principal elements: novel alloy design concepts and outcomes. Adv Eng Mater 6:299–303
Cantor B, Chang ITH, Knight P, Vincent AJB (2004) Microstructural development in equiatomic multicomponent alloys. Mater Sci Eng A 375–377:213–218
Ranganathan S (2003) Alloyed pleasures: multimetallic cocktails. Curr Sci 85:1404–1406
Cantor B (2014) Multicomponent and high entropy alloys. Entropy 16:4749–4768
Huang KH, Yeh JW (advisor) (1996) A study on the multicomponent alloy systems containing equal-mole elements. Master’s thesis, National Tsing Hua University, Taiwan
Lai KT, Chen SK, Yeh JW (1998) Properties of the multicomponent alloy system with equal-mole elements. Master’s thesis, National Tsing Hua University, Taiwan
Hsu YH, Chen SK, Yeh JW (2000) A study on the multicomponent alloy systems with equal-mole FCC or BCC elements. Master’s thesis, National Tsing Hua University, Taiwan
Hung YT, Chen SK, Yeh JW (2001) A study on the Cu-Ni-Al-Co-Cr-Fe-Si-Ti multicomponent alloy system. Master’s thesis, National Tsing Hua University, Taiwan
Chen KY, Shun TT, Yeh JW (2002) Development of multi-element high-entropy alloys for spray coating. Master’s thesis, National Tsing Hua University, Taiwan
Tung CC, Shun TT, Chen SK, Yeh JW (2002) Study on the deformation microstructure and high temperature properties of Cu-Co-Ni-Cr-Al-Fe. Master’s thesis, National Tsing Hua University, Taiwan
Chen MJ, Lin SS (2003) The effect of V, S, and Ti additions on the microstructure and wear properties of Al(0.5)CrCuFeCoNi high-entropy alloys. Master’s thesis, National Tsing Hua University, Taiwan
Huang PK, Yeh JW (2003) Research of multi-component high-entropy alloys for thermal spray coating. Master’s thesis, National Tsing Hua University, Taiwan
Hsu CY, Shun TT, Chen SK, Yeh JW (2003) Alloying effect of boron on the microstructure and high-temperature properties of CuCoNiCrAl0.5Fe alloys. Master’s thesis, National Tsing Hua University, Taiwan.
Lin PC, Chin TS, Yeh JW (2003) Development on the high frequency soft-magnetic thin films from high-entropy alloys. Master’s thesis, National Tsing Hua University, Taiwan
Tsai CW, Shun TT, Yeh JW (2003) Study on the deformation behavior and microstructure of CuCoNiCrAlxFe high-entropy alloys. Master’s thesis, National Tsing Hua University, Taiwan
Tsai MH, Yeh JW, Gan JY (2003) Study on the evolution of microstructure and electric properties of multi-element high-entropy alloy films. Master’s thesis, National Tsing Hua University, Taiwan
Huang PK, Yeh JW, Shun TT, Chen SK (2004) Multi-principal-element alloys with improved oxidation and wear resistance for thermal spray coating. Adv Eng Mater 6:74–78
Hsu CY, Yeh JW, Chen SK, Shun TT (2004) Wear resistance and high-temperature compression strength of FCC CuCoNiCrAl0.5Fe alloy with boron addition. Metall Mater Trans A 35:1465–1469
Yeh JW, Chen SK, Gan JY, Lin SJ, Chin TS, Shun TT, Tsau CH, Chang SY (2004) Formation of simple crystal structures in Cu-Co-Ni-Cr-Al-Fe-Ti-V alloys with multiprincipal metallic elements. Metall Mater Trans A 35:2533–2536
Chen TK, Shun TT, Yeh JW, Wong MS (2004) Nanostructured nitride films of multi-element high-entropy alloys by reactive DC sputtering. Surf Coat Tech 188–189:193–200
Gaskell DR (1995) Introduction to the thermodynamics of materials, 3rd edn. Taylor & Francis Ltd, Washington, DC, pp 80–84
Swalin RA (1972) Thermodynamics of solids, 2nd edn. Wiley, New York, pp 35–41
Yeh JW (2006) Recent progress in high-entropy alloys. Annales De Chimie – Science des Materiaux (Euro J Control) 31:633–648
Yeh JW (2013) Alloy design strategies and future trends in high-entropy alloys. JOM 65:1759–1771
Takeuchi A, Chen N, Wada T, Yokoyama Y, Kato H, Inoue A, Yeh JW (2011) Pd20Pt20Cu20Ni20P20 high-entropy alloy as a bulk metallic glass in the centimeter. Intermetallics 19:1546–1554
Kao SW, Yeh JW, Chin TS (2008) Rapidly solidified structure of alloys with two to eight equal-molar elements – a simulation by molecular dynamics. J Phys Condens Matter 20:145214
Turnbull D (1977) On the gram-atomic volumes of metal–metalloid glass forming alloys. Scr Metall 11:1131–1136
Turnbull D (1981) Metastable structure in metallurgy. Metall Trans B 12:217–230
Greer AL (1993) Confusion by design. Nature 366:303–304
Gao MC, Alman DE (2013) Searching for next single-phase high-entropy alloy compositions. Entropy 15:4504–4519. doi:10.3390/e15104504
Santodonato LJ, Zhang Y, Feygenson M, Parish CM, Gao MC, Weber RJK, Neuefeind JC, Tang Z, Liaw PK (2015) Deviation from high-entropy configurations in the atomic distributions of a multi-principal-element alloy. Nat Commun 6:5964. doi:10.1038/ncomms69
Miracle DB, Miller JD, Senkov ON, Woodward C, Uchic MD, Tiley J (2014) Exploration and development of high entropy alloys for structural applications. Entropy 16:494–525
Zhang Y, Zuo TT, Tang Z, Gao MC, Dahmen KA, Liaw PK, Lu ZP (2014) Microstructures and properties of high-entropy alloys. Prog Mater Sci 61:1–93
Tsai MH, Yeh JW (2014) High-entropy alloys: a critical review. Mater Res Lett. doi:10.1080/21663831.2014.912690
Samaei AT, Mirsayar MM, Aliha MRM (2015) The microstructure and mechanical behavior of modern high temperature alloys. Eng Solid Mech 3:1–20
Acknowledgment
J.W.Y. sincerely thanks Professors Ranganathan and Cantor for their great contributions from the beginning of high-entropy alloys era and also thanks four colleagues, Professors Su-Jien Lin, Swe-Kai Chen, Tsung-Shune Chin, and Han C. Shih for their continued research and contributions on high-entropy alloys. J.W.Y. would like to acknowledge the Ministry of Science and Technology, Ministry of Economic Affairs, and National Tsing Hua University, R.O.C., for their financial supports through different projects of high-entropy alloys. He also thanks Dr. Chun-Ming Lin for the collections and statistical analyses of papers on high-entropy alloys.
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Yeh, JW. (2016). Overview of High-Entropy Alloys. In: Gao, M., Yeh, JW., Liaw, P., Zhang, Y. (eds) High-Entropy Alloys. Springer, Cham. https://doi.org/10.1007/978-3-319-27013-5_1
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DOI: https://doi.org/10.1007/978-3-319-27013-5_1
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